File name: Pandora238s1_Granada_20250404_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250405T002416.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20250404_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20250404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250404T075722.2Z 9225.331506 147 1 0.90 2 66.65 100.85 108.41 29.81 0.00 1 0.00 1 0 17 3.418e-02 7.726e-03 1.741e-02 3.870e-03 3.967331e-01 1.853728e-03 4.552872e-03 -6.000000e+00 1.827234e-02 227.73 -2.00 3.42 -2.00 317.70 0.00e+00 1.456667e-04 2.970974e-04 1.129621e-04 -6.000000e+00 7.983738e-04 278.01 -2.00 20.00 -2.00 317.05 0.00e+00 2.504 0.000 302.00 328.00 3 1.0930e+00 4.9180e-03 3.0505e-02 -6.0000e+00 4.5545e-02 2.5081e-02 5.5732e-03 1.9635e-02 -6.0000e+00 4.9730e-02 -1.0829e-02 3.5660e-03 9.6752e-03 -6.0000e+00 2.9523e-02 -6.7546e-03 1.8607e-03 2.7075e-03 -6.0000e+00 1.2621e-02 1.0485e-02 -2.5386e-04 8.7792e-05 2.0651e-05 -6.0000e+00 7.2047e-04 1.0327e-03 0.0000e+00 12 9 1 12 1 1 69.58 20.77 1.00 0.00103 -0.00087 12 86 1 5 0 68.582 24.75 15.00 20.77 21.27 5.3 914.93 -17835 -845 -11643 -8223 -15867 -7364 -15400 -1223 -10927 -9646 -9141 -3636 -5012 -1830 -1290 -1101 474 -702 2828 2464 1952 2959 4541 2407 -124 857 -496 1894 1785 2259 -1028 1918 3585 -2750 -1738 -1562 -1524 -1938 362 -1134 -1185 -1633 -904 -780 1568 574 -238 -862 -2371 2388 1338 443 1106 1352 494 1612 1181 793 714 165 1617 1393 579 1709 -750 680 -605 -127 1014 786 382 -735 -1135 -219 -163 -193 -597 364 9 -1390 -999 -1091 -1598 -1964 -947 -1207 -1041 345 1194 -277 1375 922 276 753 945 -347 804 373 -643 -479 80 30 -643 393 -863 -787 -994 -1048 -6 233 76 62 276 987 948 487 -128 330 283 42 -394 410 175 -337 986 513 1149 325 146 -190 -360 -148 26 437 278 -410 -205 -251 -214 -801 -158 198 90 -1218 -57 -936 -559 -1012 -456 -1133 -91 -1006 -928 -831 -349 -600 -247 -189 -181 79 -129 522 479 388 556 925 542 -30 218 -127 430 380 511 -279 539 1065 -875 -512 -448 -496 -690 157 -549 -612 -822 -473 -402 797 297 -122 -445 -1244 1317 783 262 692 916 325 1072 816 534 497 114 1093 1041 455 1390 -606 510 -459 -98 833 683 355 -685 -1073 -196 -138 -152 -469 274 7 -1263 -961 -1140 -1665 -2145 -1070 -1392 -1255 419 1439 -317 1525 962 278 767 1032 -412 974 501 -871 -636 103 35 -750 474 -1120 -1036 -1342 -1442 -9 345 116 96 418 1437 1306 668 -176 471 423 64 -591 595 258 -472 1338 706 1503 444 206 -277 -551 -229 41 703 468 -709 -351 -439 -368 -1347 -263 322 143 SS 20250404T080036.4Z 9225.333755 150 1 1.08 2 66.02 101.40 108.10 30.44 0.00 1 0.00 1 0 25 3.506e-02 8.060e-03 2.156e-02 5.051e-03 3.919612e-01 2.420426e-03 4.517510e-03 -6.000000e+00 1.874687e-02 227.73 -2.00 3.42 -2.00 317.60 0.00e+00 5.158162e-04 3.776773e-04 1.116053e-04 -6.000000e+00 8.190287e-04 278.01 -2.00 20.00 -2.00 316.94 0.00e+00 2.443 0.000 302.00 328.00 3 1.8043e+00 6.4135e-03 2.9950e-02 -6.0000e+00 4.6728e-02 3.8418e-02 7.2629e-03 1.9436e-02 -6.0000e+00 5.1020e-02 -1.9114e-02 4.6035e-03 9.5791e-03 -6.0000e+00 3.0288e-02 -1.8305e-03 2.3873e-03 2.7115e-03 -6.0000e+00 1.2950e-02 5.4297e-03 -1.9155e-04 1.1445e-04 2.0349e-05 -6.0000e+00 7.3864e-04 2.5402e-04 0.0000e+00 12 9 1 12 1 1 94.33 20.77 0.96 0.00025 -0.00119 7 44 1 5 0 134.766 24.75 14.99 20.77 21.31 5.3 916.23 188 -5872 -6724 -21418 -21055 2755 -9698 -17804 -5923 2746 -984 -4842 -4449 522 1875 -415 1424 -2428 2277 2116 2729 1812 -1144 476 -64 4620 -761 -1803 1592 2339 1590 4180 1705 -1963 -1878 -694 -1024 -2387 809 -2299 -66 -44 -558 552 -1713 -1752 -384 394 -602 999 1660 2421 1300 -443 -23 2625 280 -392 135 -834 1969 735 1165 1591 161 -154 -167 -59 1299 572 533 -132 -921 -647 -280 304 722 -43 300 -1419 -2161 -1181 -2091 -954 -471 -1050 -814 -223 1134 329 780 859 476 351 829 -3 608 -919 430 -294 -471 576 -856 -3 -1321 -904 -747 -541 136 465 389 705 -37 202 526 527 164 -92 489 192 -666 198 119 -247 354 687 1802 634 -80 -450 -127 273 -598 342 -35 -396 515 190 -26 -1216 -259 427 -319 13 -454 -556 -1793 -1524 166 -721 -1657 -551 247 -87 -496 -559 72 281 -71 247 -477 443 433 563 360 -257 113 -16 1171 -202 -439 351 546 433 1183 531 -637 -569 -203 -340 -873 355 -1147 -34 -24 -296 285 -914 -943 -200 219 -337 527 978 1513 818 -308 -16 1845 196 -268 95 -587 1415 555 914 1297 136 -117 -134 -46 1060 523 493 -128 -864 -580 -237 237 557 -32 241 -1280 -2085 -1224 -2167 -1020 -524 -1248 -969 -270 1352 387 861 928 473 354 892 -4 756 -1230 589 -383 -599 704 -984 -4 -1692 -1171 -989 -756 191 697 599 1095 -56 290 739 705 227 -129 712 287 -1014 292 172 -349 490 922 2285 840 -114 -663 -195 423 -932 551 -60 -685 874 330 -45 -2054 -433 695 -509 SS 20250404T081904.9Z 9225.346585 167 1 0.67 2 62.43 104.58 106.23 34.00 0.00 1 0.00 1 0 17 1.659e-02 6.960e-03 1.146e-02 3.819e-03 3.444789e-01 1.832120e-03 3.980850e-03 -6.000000e+00 8.869219e-03 227.73 -2.00 3.42 -2.00 317.03 0.00e+00 3.049356e-04 2.450350e-04 9.919337e-05 -6.000000e+00 3.875357e-04 278.01 -2.00 20.00 -2.00 316.38 0.00e+00 2.149 0.000 302.00 328.00 3 1.1570e+00 4.8057e-03 2.6295e-02 -6.0000e+00 2.2107e-02 2.9162e-02 5.4187e-03 1.7000e-02 -6.0000e+00 2.4139e-02 -1.7368e-02 3.2773e-03 8.3791e-03 -6.0000e+00 1.4330e-02 -1.8539e-03 1.6429e-03 2.3480e-03 -6.0000e+00 6.1259e-03 1.4528e-02 -3.1558e-04 8.6615e-05 1.8435e-05 -6.0000e+00 3.4980e-04 1.3081e-03 0.0000e+00 12 9 1 12 1 1 -55.90 20.78 0.92 0.00131 -0.00106 10 98 1 5 0 60.240 24.75 15.00 20.78 21.79 5.4 918.92 -118 -2474 -2967 -449 -6208 -3364 -8197 -5272 -660 -4249 -6551 742 822 -48 3754 -1821 -558 -365 -1843 1149 1723 3374 346 178 1234 -855 407 -868 -2476 4167 1615 603 2784 814 -4055 -1262 -819 -1385 428 -324 -1478 -328 -1188 -375 -950 -954 944 -508 -200 -337 1254 327 1041 883 1221 1902 1217 659 744 -289 1417 2069 864 1245 -1411 54 -360 -652 686 635 8 -300 -204 -743 -34 309 493 -752 611 97 -1083 -1034 -1951 -1786 -588 -541 -441 324 -156 -670 311 740 517 866 773 -387 36 275 154 -327 161 -162 -439 1 -782 -729 -949 -847 35 470 290 140 23 782 737 470 373 483 -256 179 -301 250 598 -178 801 809 1186 441 -269 -480 -92 -106 -57 108 23 -539 252 -602 -20 -679 -123 379 1 -13 -275 -349 -49 -622 -343 -956 -687 -92 -646 -956 110 134 -9 812 -423 -130 -92 -486 308 465 931 99 54 388 -291 135 -264 -710 1177 534 212 1027 306 -1479 -476 -321 -595 208 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