File name: Pandora238s1_Granada_20250503_L2Fit_fwvt1c14d20240721p1-8.txt File generation date: 20250504T001629.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20250503_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20250503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 1624 1774 Nominal wavelengths inside fitting window [nm]: 492.0557 492.1763 492.2970 492.4177 492.5383 492.6590 492.7796 492.9002 493.0207 493.1413 493.2618 493.3824 493.5029 493.6234 493.7438 493.8643 493.9847 494.1051 494.2255 494.3459 494.4663 494.5866 494.7070 494.8273 494.9476 495.0679 495.1881 495.3084 495.4286 495.5488 495.6690 495.7892 495.9093 496.0295 496.1496 496.2697 496.3898 496.5099 496.6299 496.7500 496.8700 496.9900 497.1100 497.2299 497.3499 497.4698 497.5897 497.7096 497.8295 497.9494 498.0692 498.1890 498.3088 498.4286 498.5484 498.6682 498.7879 498.9076 499.0273 499.1470 499.2667 499.3863 499.5060 499.6256 499.7452 499.8647 499.9843 500.1039 500.2234 500.3429 500.4624 500.5819 500.7013 500.8207 500.9402 501.0596 501.1789 501.2983 501.4177 501.5370 501.6563 501.7756 501.8949 502.0141 502.1334 502.2526 502.3718 502.4910 502.6102 502.7293 502.8485 502.9676 503.0867 503.2058 503.3248 503.4439 503.5629 503.6819 503.8009 503.9199 504.0388 504.1578 504.2767 504.3956 504.5145 504.6333 504.7522 504.8710 504.9898 505.1086 505.2274 505.3461 505.4649 505.5836 505.7023 505.8210 505.9397 506.0583 506.1769 506.2956 506.4141 506.5327 506.6513 506.7698 506.8883 507.0069 507.1253 507.2438 507.3623 507.4807 507.5991 507.7175 507.8359 507.9542 508.0726 508.1909 508.3092 508.4275 508.5458 508.6640 508.7822 508.9004 509.0186 509.1368 509.2550 509.3731 509.4912 509.6093 509.7274 509.8455 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250503T054821.7Z 9254.241917 88 1 54.14 2 84.99 74.00 118.35 5.14 0.00 1 0.00 1 0 15 3.524e-03 3.499e-03 6.000e-04 5.985e-04 7.287568e+03 3.721198e+01 4.983396e+02 -6.000000e+00 1.832209e+02 281.02 -2.00 20.00 -2.00 505.29 0.00e+00 2.024281e-03 1.599848e-05 1.221118e-04 -6.000000e+00 9.607270e-05 281.02 -2.00 20.00 -2.00 500.43 0.00e+00 9.289468e-01 1.154856e-02 5.407222e-02 -6.000000e+00 6.774218e-02 229.88 -2.00 3.42 -2.00 502.02 0.00e+00 9.827 0.015 489.00 513.00 1 5.0678e+00 8.8173e-04 1.4227e-02 -6.0000e+00 5.1749e-03 7.1529e-03 2.2906e-04 1.4436e-03 -6.0000e+00 1.3618e-03 3.0271e-03 -1.8821e-06 4.2471e-05 5.6548e-05 -6.0000e+00 2.6243e-04 -1.8528e-03 7.0867e-05 10 0 0 10 0 0 99.86 20.85 1.67 -0.00185 -0.00187 53 6 1 4 0 1020.986 24.75 14.99 20.85 17.52 5.4 888.96 -585 -376 -15 309 265 314 647 976 957 411 297 119 104 48 40 10 -102 -12 131 155 -28 27 10 41 283 260 236 -184 292 -369 -338 -370 -706 -475 31 3 -438 -96 -260 84 -98 -102 -134 239 220 298 281 500 457 257 -226 -790 -682 -666 -383 -143 11 48 276 282 68 289 248 109 45 49 18 -481 -385 -405 -554 -263 -284 -227 -297 -40 -192 -468 -455 -348 -533 -487 -431 -510 -333 -164 -374 -431 -151 -90 -18 250 360 487 149 174 13 -392 -721 -561 -662 -108 -403 -249 -58 -298 -279 -213 -235 58 46 228 601 488 419 293 398 628 754 224 92 70 -77 350 404 263 363 240 529 681 0 -116 23 496 -109 -318 -10 238 103 106 249 169 287 167 -158 54 34 -208 -352 -309 -256 -576 -361 -15 312 273 329 669 1019 995 422 311 124 106 48 40 10 -104 -12 137 163 -30 28 10 43 303 279 252 -197 302 -375 -342 -365 -704 -493 32 4 -456 -99 -274 87 -102 -104 -138 249 232 316 297 520 469 259 -226 -776 -660 -647 -384 -144 12 49 287 291 70 301 252 110 47 50 18 -482 -382 -394 -549 -254 -278 -224 -298 -40 -188 -450 -432 -338 -518 -467 -415 -491 -327 -163 -372 -426 -148 -89 -18 249 356 485 145 172 12 -367 -679 -515 -606 -99 -372 -241 -57 -296 -275 -207 -224 55 45 226 599 477 413 289 396 634 761 223 91 69 -75 342 389 253 350 234 507 654 0 -113 22 472 -104 -303 -10 233 101 106 245 167 285 167 -159 54 34 -207 -341 -297 -248 SQ 20250503T055657.3Z 9254.247885 91 1 54.15 2 83.34 75.25 118.19 7.24 0.00 1 0.00 1 0 15 3.060e-03 3.050e-03 3.094e-04 3.086e-04 5.592374e+03 1.869247e+01 3.864599e+02 -6.000000e+00 1.590788e+02 281.02 -2.00 20.00 -2.00 505.27 0.00e+00 1.955458e-03 8.248723e-06 1.171941e-04 -6.000000e+00 8.341046e-05 281.02 -2.00 20.00 -2.00 500.39 0.00e+00 7.568992e-01 5.963726e-03 4.346927e-02 -6.000000e+00 5.881887e-02 229.88 -2.00 3.42 -2.00 501.99 0.00e+00 7.857 0.008 489.00 513.00 1 4.0494e+00 4.5546e-04 1.1406e-02 -6.0000e+00 4.4932e-03 1.0319e-02 1.1865e-04 1.1333e-03 -6.0000e+00 1.1825e-03 1.1050e-02 9.2635e-05 2.2121e-05 4.6985e-05 -6.0000e+00 2.2789e-04 4.2857e-03 2.5791e-05 10 0 0 10 0 0 8.78 20.85 1.73 0.00429 0.00493 206 23 1 4 0 262.508 24.75 15.00 20.85 17.53 5.5 889.64 -535 -242 39 411 184 247 663 976 805 341 161 84 52 125 133 -39 -48 -6 39 177 -18 -80 -21 51 216 228 16 -151 192 -293 -246 -309 -594 -463 -13 3 -394 -136 -175 54 -10 -62 -127 212 313 318 210 448 555 277 -157 -621 -576 -658 -369 -156 -40 -65 189 190 70 193 242 -10 32 -67 -52 -467 -377 -376 -369 -208 -213 -290 -182 -5 -190 -371 -370 -242 -520 -497 -429 -451 -284 -126 -347 -268 -175 -9 92 64 249 388 78 113 -32 -346 -585 -498 -473 -125 -391 -200 -142 -202 -219 -105 -262 149 58 193 500 438 305 226 362 443 628 220 111 -10 -3 287 338 256 330 203 479 490 10 -20 152 394 41 -155 79 172 235 173 211 190 211 72 -99 -34 -54 -136 -325 -298 -303 -528 -242 39 418 191 261 694 1030 848 354 170 88 54 125 134 -40 -49 -7 41 189 -19 -85 -22 54 227 238 17 -158 199 -298 -248 -316 -594 -481 -14 3 -413 -141 -179 56 -10 -64 -131 222 331 339 223 468 570 279 -157 -608 -556 -638 -368 -156 -41 -68 197 196 72 201 246 -11 32 -69 -52 -466 -374 -364 -363 -206 -208 -286 -182 -5 -185 -356 -361 -234 -504 -476 -413 -433 -278 -125 -345 -263 -172 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184.706 24.75 15.00 20.85 18.16 5.5 895.19 -502 -220 19 333 172 222 534 924 797 320 92 124 65 82 124 6 -82 -87 2 163 -52 -85 -27 9 169 176 21 -268 216 -201 -252 -229 -549 -391 11 -55 -352 -58 -115 184 -3 -44 -134 194 256 328 258 457 516 287 -161 -557 -474 -603 -332 -129 -53 -84 192 207 54 158 213 12 -9 -59 -30 -454 -393 -369 -421 -125 -163 -259 -219 14 -204 -398 -343 -188 -452 -476 -414 -419 -229 -197 -337 -385 -145 -21 59 -2 299 289 25 45 -90 -358 -592 -383 -421 -54 -326 -154 -158 -187 -182 -129 -138 159 102 254 495 392 312 237 369 430 580 227 71 37 -35 255 346 280 299 212 422 484 7 -22 177 489 -18 -136 78 195 199 143 200 143 183 65 -97 -127 -103 -165 -324 -245 -295 -490 -217 19 345 182 231 568 991 853 337 96 128 68 84 127 6 -85 -90 2 171 -55 -89 -28 10 180 187 23 -283 228 -201 -258 -229 -555 -411 12 -59 -373 -61 -119 187 -3 -46 -139 205 273 352 275 479 533 290 -162 -548 -460 -587 -332 -130 -54 -88 201 214 56 164 217 12 -9 -61 -30 -455 -390 -358 -415 -121 -159 -255 -219 14 -200 -382 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