File name: Pandora238s1_Granada_20250531_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250601T002301.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20250531_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20250531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250531T054541.3Z 9282.240062 78 1 54.84 2 81.91 68.52 117.26 23.83 0.00 1 0.00 1 0 25 5.123e-01 2.652e-02 4.080e-01 1.839e-02 8.693878e-01 1.052513e-02 9.886799e-03 -6.000000e+00 2.893123e-01 231.56 -2.00 3.42 -2.00 322.00 0.00e+00 8.063388e-03 6.124378e-03 6.337421e-03 -6.000000e+00 1.542980e-02 283.89 -2.00 20.00 -2.00 321.51 0.00e+00 6.659 0.005 302.00 328.00 3 2.3019e+00 4.1002e-02 8.0264e-02 -6.0000e+00 7.3372e-01 6.9907e-01 6.0737e-02 5.3541e-02 -6.0000e+00 8.0863e-01 -7.8142e-01 6.1471e-02 3.1131e-02 -6.0000e+00 4.7281e-01 2.7107e-01 2.7755e-02 1.1950e-02 -6.0000e+00 1.9979e-01 4.1691e-05 -3.7532e-04 4.3838e-04 1.5502e-04 -6.0000e+00 1.1781e-02 2.6621e-03 0.0000e+00 12 8 8 10 0 0 -69.55 21.32 1.36 0.00266 -0.00016 32 4 1 5 0 1713.194 25.00 15.00 21.32 27.68 5.5 957.60 900000 -218572 -72634 900000 900000 -101326 900000 -49715 -82897 900000 900000 -257886 900000 900000 -68920 900000 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1725 1214 155 1739 1325 1426 369 1967 2088 2022 3704 652 -645 3346 3055 1033 2700 5120 3100 3323 1975 2631 4720 3128 776 3069 2094 1711 -1082 -3491 5541 -3639 -1652 -1385 1499 929 3380 -791 743 1886 -3701 2261 596 2625 1417 701 1313 -3769 -1050 -77 1094 -5069 -16 -3910 1481 -769 -5484 -591 -2226 1757 -3227 -2494 -3391 -3067 1409 -3479 4292 -1088 -616 -4928 73 1990 -186 5743 1636 3389 4731 845 287 1144 -1881 2210 626 1370 423 -557 -1761 3444 -1120 -78 1156 3006 -3233 -876 301 -913 -3350 SS 20250531T060204.1Z 9282.251436 83 1 54.17 2 78.85 70.80 115.94 27.60 0.00 1 0.00 1 0 25 2.969e-01 6.404e-03 2.890e-01 4.731e-03 6.893584e-01 2.515213e-03 7.530633e-03 -6.000000e+00 1.624742e-01 231.56 -2.00 3.42 -2.00 321.28 0.00e+00 4.721437e-03 1.231621e-03 1.638675e-03 -6.000000e+00 7.545647e-03 283.89 -2.00 20.00 -2.00 320.70 0.00e+00 4.993 0.002 302.00 328.00 3 1.9308e+00 8.6533e-03 5.8707e-02 -6.0000e+00 4.0936e-01 8.0335e-02 1.2526e-02 3.6750e-02 -6.0000e+00 4.4600e-01 -8.8553e-02 1.3621e-02 2.0981e-02 -6.0000e+00 2.6265e-01 2.2015e-02 6.4247e-03 8.5665e-03 -6.0000e+00 1.1270e-01 3.5668e-04 -3.8279e-04 1.1136e-04 6.8369e-05 -6.0000e+00 6.6053e-03 2.5749e-03 0.0000e+00 11 8 0 10 0 0 -1.39 21.30 1.15 0.00257 -0.00030 121 13 1 5 0 447.300 25.00 14.99 21.30 28.65 5.6 965.14 -77427 900000 -104887 900000 -104310 41579 900000 900000 -178378 -52504 -121728 900000 -109011 -49157 -43446 -37958 -28119 -724 15933 7752 29630 10585 -2721 87230 -2346 1969 -48991 -13925 -60648 23589 -22924 -4481 9659 -23866 4256 -10314 7724 -8075 -11319 3221 -12661 2214 9111 -1464 -6693 4508 7774 -7562 777 1416 11076 -3144 1141 -131 -1506 1533 273 -363 -1038 2133 2343 369 3961 6018 879 1380 1158 -108 263 886 1761 1015 870 -314 -1973 141 535 -24 -1673 -583 206 -1635 -2000 -796 68 679 -1046 548 1409 1061 108 -996 546 -1281 165 188 114 6 16 -246 -37 -1006 -295 485 -1413 -1430 -652 -1058 -257 201 449 554 268 489 155 851 561 464 -437 -478 -78 -27 533 -347 805 -59 360 382 344 140 -231 -268 -679 271 13 -876 257 26 276 -72 263 44 -61 -357 900000 -483 900000 -481 192 900000 900000 -1781 -242 -748 900000 -1005 -321 -350 -350 -259 -6 116 66 205 93 -31 439 -30 26 -1109 -210 -1449 287 -576 -107 247 -880 103 -311 223 -328 -598 178 -897 144 592 -106 -527 362 620 -742 74 145 1205 -435 165 -21 -259 265 50 -64 -179 354 413 75 900 1551 240 350 310 -30 83 330 696 420 342 -118 -668 41 152 -7 -601 -250 101 -953 -1237 -510 47 495 -812 426 1085 771 72 -642 332 -848 126 167 106 6 19 -273 -38 -1008 -266 467 -1388 -1573 -695 -1225 -323 289 712 914 434 758 225 1181 812 706 -720 -815 -127 -42 802 -500 1100 -80 451 534 561 251 -464 -516 -1384 580 31 -2157 619 66 679 -165 572 90 -121 SS 20250531T060722.9Z 9282.255126 86 1 54.04 2 77.85 71.54 115.48 28.79 0.00 1 0.00 1 0 17 3.275e-01 6.418e-03 2.369e-01 3.423e-03 6.410302e-01 1.754506e-03 7.014335e-03 -6.000000e+00 1.783916e-01 231.56 -2.00 3.42 -2.00 321.01 0.00e+00 3.814352e-03 8.001450e-04 1.412745e-03 -6.000000e+00 7.927490e-03 283.89 -2.00 20.00 -2.00 320.40 0.00e+00 4.612 0.002 302.00 328.00 3 1.8191e+00 5.7853e-03 5.4195e-02 -6.0000e+00 4.4817e-01 6.0911e-02 7.9963e-03 3.3610e-02 -6.0000e+00 4.8774e-01 -5.3732e-02 8.3887e-03 1.8348e-02 -6.0000e+00 2.8883e-01 3.9616e-03 4.0420e-03 6.9601e-03 -6.0000e+00 1.2351e-01 5.8682e-04 -3.8132e-04 7.9872e-05 5.5208e-05 -6.0000e+00 6.9799e-03 3.0949e-03 0.0000e+00 11 8 0 10 0 0 -1.57 21.31 0.94 0.00309 0.00023 161 18 1 5 0 335.294 25.00 15.00 21.31 29.09 5.5 968.58 -91318 900000 -131416 191069 -129447 -165660 900000 -88179 85800 -45031 -32206 -5033 -7334 -3638 -56012 -67072 -42993 -9620 44218 -5328 14420 -14795 4771 -35346 -15113 -7669 -26241 -29915 -32790 -39252 -20533 388 -8630 -9594 -16633 -10968 1991 -12833 -3117 -3126 3812 1957 -332 -5598 -1849 -3378 430 6293 993 -318 1242 361 3339 5289 -1581 489 1312 658 1916 240 771 2602 3843 2324 1971 953 110 1050 648 1595 1393 1924 -543 -336 -1316 1137 -1370 -1035 431 68 385 -353 -2707 -2028 -474 -417 -543 -188 1013 438 258 376 474 -621 263 428 351 128 552 -653 116 -421 -1224 730 -1717 -1449 -804 -321 -410 110 344 502 186 811 72 53 40 219 -236 -47 -220 587 393 173 282 340 427 579 -161 -347 -481 -297 -574 523 190 -465 491 -176 -34 -457 251 416 -260 -352 900000 -944 638 -731 -1566 900000 -490 286 -200 -125 -18 -37 -22 -748 -1194 -657 -120 344 -79 179 -238 71 -858 -316 -161 -669 -744 -825 -1226 -679 12 -351 -405 -656 -439 80 -720 -200 -242 300 166 -31 -603 -197 -378 47 682 119 -41 185 60 583 1004 -333 105 289 142 394 50 169 634 1059 747 636 288 35 332 238 686 642 918 -253 -147 -519 385 -463 -354 173 33 213 -229 -1894 -1479 -371 -346 -429 -151 801 360 193 267 321 -450 220 376 354 152 687 -783 129 -411 -1095 693 -1837 -1574 -932 -398 -554 170 532 876 289 1309 108 77 60 348 -404 -76 -373 952 623 261 407 480 561 843 -272 -591 -911 -584 -1187 1132 413 -1066 1105 -418 -78 -994 559 867 -529 SS 20250531T061235.5Z 9282.258744 89 1 53.97 2 76.87 72.25 115.01 29.95 0.00 1 0.00 1 0 25 2.137e-01 5.462e-03 1.431e-01 2.622e-03 5.988140e-01 1.336668e-03 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