File name: Pandora200s1_GrandForksND_20240807_L2Fit_fwvt1c3d20230515p1-8.txt File generation date: 20241123T135106.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Mafany Ndiva Mongoh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 200 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora200_OF_v3d20210115.txt Instrument calibration file used: Pandora200s1_CF_v3d20230515.txt Level 1 file used: Pandora200s1_GrandForksND_20240807_L1_smca1c3d20230515p1-8.txt Full location name: University of North Dakota Grand Forks ND Short location name: GrandForksND Country of location: United States Location latitude [deg]: 47.9219 Location longitude [deg]: -97.0865 Location altitude [m]: 256 Local noon date: 20240807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Anafld, based on Oob session 2." First and last pixel inside fitting window: 1612 1760 Nominal wavelengths inside fitting window [nm]: 492.0856 492.2071 492.3287 492.4502 492.5717 492.6932 492.8147 492.9361 493.0576 493.1790 493.3004 493.4218 493.5432 493.6646 493.7859 493.9072 494.0285 494.1498 494.2711 494.3924 494.5136 494.6348 494.7561 494.8772 494.9984 495.1196 495.2407 495.3619 495.4830 495.6041 495.7251 495.8462 495.9672 496.0883 496.2093 496.3303 496.4513 496.5722 496.6932 496.8141 496.9350 497.0559 497.1768 497.2976 497.4185 497.5393 497.6601 497.7809 497.9017 498.0225 498.1432 498.2639 498.3847 498.5054 498.6260 498.7467 498.8673 498.9880 499.1086 499.2292 499.3498 499.4703 499.5909 499.7114 499.8319 499.9524 500.0729 500.1933 500.3138 500.4342 500.5546 500.6750 500.7954 500.9157 501.0361 501.1564 501.2767 501.3970 501.5173 501.6376 501.7578 501.8780 501.9982 502.1184 502.2386 502.3588 502.4789 502.5990 502.7191 502.8392 502.9593 503.0794 503.1994 503.3194 503.4394 503.5594 503.6794 503.7994 503.9193 504.0392 504.1591 504.2790 504.3989 504.5188 504.6386 504.7584 504.8782 504.9980 505.1178 505.2375 505.3573 505.4770 505.5967 505.7164 505.8361 505.9557 506.0754 506.1950 506.3146 506.4342 506.5537 506.6733 506.7928 506.9123 507.0318 507.1513 507.2708 507.3902 507.5097 507.6291 507.7485 507.8679 507.9872 508.1066 508.2259 508.3452 508.4645 508.5838 508.7031 508.8223 508.9415 509.0607 509.1799 509.2991 509.4183 509.5374 509.6566 509.7757 509.8948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240807T165800.5Z 8985.706950 250 1 49.36 2 37.41 139.95 67.06 111.09 0.00 1 0.00 1 0 15 3.393e-03 3.365e-03 1.330e-03 1.324e-03 4.193483e+03 8.362360e+01 2.951463e+02 -6.000000e+00 1.891357e+02 284.32 -2.00 20.00 -2.00 505.19 0.00e+00 3.187596e-04 3.633989e-05 2.453244e-05 -6.000000e+00 9.553642e-05 284.32 -2.00 20.00 -2.00 500.24 0.00e+00 4.209964e-02 2.660723e-02 2.746304e-02 -6.000000e+00 6.784968e-02 232.42 -2.00 3.69 -2.00 501.84 0.00e+00 1.258 0.000 489.00 513.00 1 8.2970e+00 2.0356e-03 2.9791e-03 -6.0000e+00 5.1937e-03 8.8734e-03 5.3223e-04 6.7270e-04 -6.0000e+00 1.3608e-03 4.0498e-04 2.4914e-04 1.2621e-04 3.5252e-05 -6.0000e+00 3.3618e-04 -1.4091e-04 1.3493e-05 10 0 0 10 0 0 99.28 18.69 0.75 -0.00014 0.00159 13 3 1 4 0 3796.810 22.09 15.00 18.69 999.00 -9.0 -9.00 -574 -679 -394 -255 190 283 857 170 243 243 -59 -96 7 -93 -490 56 -24 83 6 99 272 -4 313 640 334 337 152 -172 -300 0 -147 -389 171 -77 88 -190 300 -129 -266 -124 135 -222 25 432 210 146 92 177 -100 -238 -664 -897 -524 -310 -157 -377 -194 258 417 88 332 173 387 427 399 518 99 -101 -478 -328 -210 -292 -2 55 -168 -283 -54 -233 -237 -151 -209 -282 -50 -267 -55 -479 -88 -131 160 179 149 297 26 584 297 427 -332 -193 -597 -650 -488 -550 363 -328 -135 -267 9 -115 -356 -398 -221 -220 518 671 866 532 875 123 277 -15 127 106 319 -123 19 195 76 155 134 -102 -294 -76 -82 -462 -296 188 -113 395 197 -165 315 329 728 192 -134 -549 -615 -204 -438 -572 -691 -386 -258 197 298 912 183 261 257 -61 -99 7 -94 -491 56 -25 87 7 107 294 -5 338 692 363 366 164 -183 -310 0 -146 -391 175 -82 96 -207 322 -137 -279 -129 141 -235 26 464 228 158 99 186 -104 -239 -650 -864 -501 -302 -157 -389 -203 270 435 92 346 182 406 446 412 525 100 -100 -469 -318 -203 -285 -2 54 -168 -279 -52 -222 -225 -143 -199 -272 -48 -262 -54 -479 -88 -131 159 179 151 304 27 594 298 417 -318 -180 -548 -593 -449 -523 355 -312 -130 -255 9 -114 -354 -377 -211 -213 503 654 847 525 863 121 270 -14 119 99 298 -116 18 184 71 145 125 -95 -270 -69 -78 -441 -268 172 -106 374 189 -160 306 321 710 189 -131 -528 -578 -187 -402 SQ 20240807T183650.6Z 8985.775585 318 1 50.16 2 31.81 181.26 53.74 134.44 0.00 1 0.00 1 0 15 4.202e-03 4.175e-03 1.490e-03 1.483e-03 4.481777e+03 9.627408e+01 3.166141e+02 -6.000000e+00 2.342469e+02 284.32 -2.00 20.00 -2.00 505.30 0.00e+00 2.657938e-04 4.110963e-05 2.314454e-05 -6.000000e+00 1.183125e-04 284.32 -2.00 20.00 -2.00 500.30 0.00e+00 9.166737e-02 2.982490e-02 3.065201e-02 -6.000000e+00 8.400782e-02 232.41 -2.00 3.69 -2.00 501.93 0.00e+00 1.176 0.000 489.00 513.00 1 8.4601e+00 2.2804e-03 3.1207e-03 -6.0000e+00 6.4310e-03 8.0018e-03 5.8886e-04 7.4884e-04 -6.0000e+00 1.6843e-03 3.4673e-04 -1.4262e-04 1.4034e-04 3.3073e-05 -6.0000e+00 4.1634e-04 7.1823e-05 3.3921e-05 11 8 0 10 0 0 98.62 18.69 0.87 0.00007 -0.00092 13 3 1 4 0 3858.120 22.09 15.00 18.69 999.00 -9.0 -9.00 -854 -224 -566 -234 231 236 579 336 268 221 254 -175 -33 -201 -392 -115 -79 161 -183 -26 666 32 209 458 523 238 402 -504 -56 -70 -592 -108 291 24 52 58 250 -26 -336 205 4 -47 -20 354 178 353 44 -152 -38 -610 -900 -656 -980 -411 -112 -319 66 -212 294 58 492 154 261 2306 399 90 451 -409 -401 -438 -251 -355 295 71 -305 -368 -258 -792 -658 -386 -90 102 -403 339 -242 -121 -260 46 283 257 32 341 392 474 369 190 -46 -327 -607 -556 -456 -439 19 -464 -401 -241 219 -269 -154 -464 -629 -217 259 611 856 683 568 146 341 245 411 79 138 70 -129 296 266 313 201 -294 -144 -392 -246 -483 -185 -146 99 -20 117 -132 442 449 740 420 25 -235 -780 -344 -622 -831 -221 -579 -247 249 259 644 377 299 244 276 -188 -35 -210 -409 -121 -84 176 -192 -28 698 33 220 483 552 251 421 -523 -60 -73 -615 -113 311 24 55 61 261 -26 -344 208 4 -48 -21 370 187 370 46 -156 -38 -597 -920 -656 -981 -416 -109 -320 67 -216 298 59 498 157 266 2294 400 89 438 -395 -383 -413 -236 -337 282 69 -297 -352 -242 -738 -608 -356 -84 95 -381 322 -233 -117 -252 44 273 249 32 339 391 468 358 180 -42 -295 -540 -490 -407 -404 18 -458 -400 -238 213 -260 -148 -454 -626 -218 261 617 866 696 581 149 343 243 400 77 134 68 -126 288 258 303 195 -283 -137 -367 -227 -446 -173 -139 96 -20 116 -132 444 453 747 426 25 -233 -761 -328 -592 SQ 20240807T192153.5Z 8985.806869 349 1 48.32 2 33.30 201.25 49.21 147.34 0.00 1 0.00 1 0 15 3.332e-03 3.323e-03 9.713e-04 9.683e-04 3.080422e+03 6.024701e+01 2.113071e+02 -6.000000e+00 1.857053e+02 284.32 -2.00 20.00 -2.00 505.29 0.00e+00 3.955386e-04 2.675904e-05 2.637443e-05 -6.000000e+00 9.380737e-05 284.32 -2.00 20.00 -2.00 500.39 0.00e+00 2.511252e-02 1.934823e-02 2.367641e-02 -6.000000e+00 6.662774e-02 232.41 -2.00 3.69 -2.00 502.00 0.00e+00 1.196 0.000 489.00 513.00 1 7.7280e+00 1.4775e-03 2.6585e-03 -6.0000e+00 5.1001e-03 3.9668e-03 3.8503e-04 5.5084e-04 -6.0000e+00 1.3365e-03 7.2323e-04 6.9990e-04 9.2602e-05 2.4325e-05 -6.0000e+00 3.3011e-04 4.3107e-04 -4.4815e-07 10 0 0 10 0 0 99.92 18.70 0.93 0.00043 0.00529 31 8 1 4 0 1558.520 22.09 15.00 18.70 999.00 -9.0 -9.00 -847 -362 -363 -164 366 505 682 423 373 334 222 -83 -248 -194 -211 -148 -27 90 -19 31 387 212 309 367 310 426 369 -333 -420 -134 -428 -380 47 -90 -46 99 146 -23 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