File name: Pandora2s1_GreenbeltMD_20220807_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104757.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20220807_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20220807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220807T121416.7Z 8254.509915 102 1 49.91 2 68.07 86.32 164.29 335.97 0.00 1 0.00 1 0 17 2.130e-02 5.287e-03 8.992e-03 1.090e-03 3.494061e-01 5.568648e-04 4.090002e-03 -6.000000e+00 1.226046e-02 231.91 -2.00 3.47 -2.00 319.03 0.00e+00 4.285393e-04 1.310863e-04 3.526302e-04 -6.000000e+00 5.497123e-04 290.73 -2.00 20.00 -2.00 318.16 0.00e+00 2.654 0.000 302.00 328.00 3 2.9138e+00 1.5564e-03 3.2145e-02 -6.0000e+00 3.0701e-02 5.7952e-03 1.8041e-03 1.8408e-02 -6.0000e+00 3.3158e-02 -2.9937e-03 1.2718e-03 8.9305e-03 -6.0000e+00 1.9771e-02 -4.9540e-03 6.6857e-04 2.4499e-03 -6.0000e+00 8.5065e-03 1.3544e-03 -1.0952e-04 3.1342e-05 2.6174e-05 -6.0000e+00 5.5595e-04 1.2892e-02 9.7842e-06 11 1 0 11 8 0 98.55 23.23 0.23 0.01289 0.01207 301 58 1 5 0 165.780 25.39 20.00 23.23 31.12 14.5 1047.02 -2214 -4991 -2364 -11173 -7733 -7220 -2816 -6609 -5043 -8437 -7013 -3932 -4607 -1113 -1441 -208 -2991 745 -911 369 -479 30 -280 -1298 -1230 -71 -1388 -1309 -1348 54 611 986 5 -2664 -2808 -2927 -2048 -1700 163 -967 -761 -983 -395 -426 -144 -767 -483 -641 -375 254 889 652 1144 1383 731 1339 281 787 -71 1126 1231 2048 1957 1292 10 -22 -626 145 1403 447 938 45 697 83 64 -448 -1050 -1033 -655 -1074 -1070 -1787 -1884 -1068 -710 -266 65 620 476 454 377 -6 52 415 215 275 753 366 -208 -351 -770 -1013 -257 -641 -1148 -863 -607 -496 280 246 425 156 197 67 74 128 131 272 -55 -23 -53 378 188 640 346 290 675 662 201 181 -197 -209 -180 -36 -1 -208 399 65 -55 -154 -279 -524 -73 -200 -92 -429 -261 -250 -104 -289 -240 -426 -349 -211 -294 -81 -122 -19 -294 75 -98 41 -53 3 -33 -167 -166 -10 -189 -165 -164 7 86 153 1 -457 -449 -494 -393 -391 45 -305 -256 -345 -142 -153 -52 -278 -172 -227 -133 94 356 281 523 665 363 681 146 399 -36 565 656 1189 1247 869 7 -13 -366 87 938 340 757 34 557 63 44 -277 -610 -610 -435 -819 -918 -1535 -1701 -1017 -727 -288 73 704 530 473 359 -6 47 395 207 297 912 487 -282 -452 -919 -1111 -277 -753 -1453 -1137 -841 -724 435 412 679 246 321 101 103 175 186 410 -89 -39 -87 610 293 943 489 389 887 933 310 298 -342 -370 -330 -63 -2 -408 795 133 -109 -293 -511 -930 SS 20220807T125035.2Z 8254.535129 126 1 50.95 2 61.02 92.00 165.44 5.91 0.00 1 0.00 1 0 17 1.724e-02 6.055e-03 9.483e-03 2.300e-03 2.724548e-01 1.168272e-03 3.226827e-03 -6.000000e+00 9.921599e-03 231.91 -2.00 3.47 -2.00 317.97 0.00e+00 3.380620e-04 2.001585e-04 1.964731e-04 -6.000000e+00 4.447590e-04 290.73 -2.00 20.00 -2.00 317.06 0.00e+00 2.054 0.000 302.00 328.00 3 5.0728e+00 3.1597e-03 2.4924e-02 -6.0000e+00 2.4845e-02 3.1405e-02 3.5791e-03 1.4253e-02 -6.0000e+00 2.6830e-02 2.3190e-03 2.2219e-03 6.8940e-03 -6.0000e+00 1.5998e-02 -6.5138e-03 1.1270e-03 1.8892e-03 -6.0000e+00 6.8855e-03 3.0754e-04 -1.2372e-04 6.5745e-05 2.0584e-05 -6.0000e+00 4.4972e-04 1.1158e-02 2.3854e-05 10 0 0 10 0 0 99.26 23.32 0.44 0.01116 0.01023 28 5 1 5 0 1819.470 25.47 20.01 23.32 32.03 14.6 1054.20 1174 -7524 2717 -7231 3015 -9401 -1994 -7334 1414 -1696 1142 -1951 -1764 -985 -361 1569 -1236 2300 -375 2472 -1585 2241 -1038 266 -867 -57 -2277 1006 -501 387 1845 1619 1260 -2980 -1323 -2900 -831 -1645 667 -767 -134 -546 -396 364 354 -893 179 -1615 -653 582 60 661 148 1667 364 1230 -95 276 -77 1095 1221 1590 1657 1304 212 43 -496 80 925 298 804 -93 950 -286 -69 -1361 -808 -859 -852 -1945 -1134 -2091 -1368 -1184 -708 36 -29 991 431 847 133 154 -383 1164 -215 269 403 586 -218 -449 -653 -986 29 -493 -1050 -946 -155 -690 423 272 680 25 369 -82 1 -265 15 353 188 102 -169 487 -61 749 131 319 161 572 158 79 -120 -102 -247 47 130 -15 482 -28 -63 -242 -232 -553 95 -709 229 -600 204 -732 -159 -698 135 -170 109 -208 -217 -138 -57 262 -219 412 -72 476 -317 430 -217 58 -201 -13 -532 209 -100 80 406 387 327 -781 -315 -735 -235 -559 267 -353 -65 -275 -203 185 180 -457 88 -794 -314 286 32 372 89 1031 233 797 -63 179 -49 699 824 1164 1315 980 167 31 -343 56 721 239 682 -81 799 -230 -55 -986 -538 -572 -631 -1653 -1065 -1963 -1333 -1221 -785 42 -35 1214 521 952 138 145 -374 1146 -214 297 496 785 -296 -581 -783 -1093 32 -587 -1348 -1266 -217 -1013 652 448 1151 42 577 -118 1 -345 20 502 289 162 -269 753 -91 1055 178 408 201 753 225 120 -188 -162 -406 82 240 -27 857 -51 -112 -455 -420 -972 SS 20220807T125537.7Z 8254.538630 129 1 9.94 2 60.05 92.81 165.32 10.19 0.00 1 0.00 1 0 25 1.311e-02 6.468e-03 6.388e-03 2.349e-03 2.654012e-01 1.198965e-03 3.123876e-03 -6.000000e+00 7.550071e-03 231.91 -2.00 3.47 -2.00 316.95 0.00e+00 4.014784e-04 1.598404e-04 1.587725e-04 -6.000000e+00 3.384122e-04 290.73 -2.00 20.00 -2.00 316.09 0.00e+00 1.994 0.000 302.00 328.00 3 4.2279e+00 3.1733e-03 2.4140e-02 -6.0000e+00 1.8906e-02 3.0746e-02 3.5538e-03 1.3720e-02 -6.0000e+00 2.0416e-02 -3.2337e-03 2.1019e-03 6.6336e-03 -6.0000e+00 1.2174e-02 -2.1688e-03 1.0263e-03 1.8182e-03 -6.0000e+00 5.2403e-03 7.6848e-04 1.0702e-04 6.5314e-05 1.9770e-05 -6.0000e+00 3.4217e-04 1.0078e-02 2.2353e-05 12 9 1 12 1 1 36.16 23.34 0.15 0.01008 0.01088 10 11 1 5 0 888.760 25.47 20.00 23.34 32.26 14.6 1055.99 -3027 1921 -2831 -4076 -6338 1034 -1234 959 340 -2027 -5047 -3635 611 -136 237 1466 610 -2077 2769 951 457 1679 2344 646 1892 -189 -529 -227 -488 2483 1314 1582 468 -2086 -2344 -1705 -1995 -316 -436 -575 -1442 -1086 -804 157 -372 -861 -542 -1359 -330 -161 156 896 1370 666 931 1178 777 759 553 377 1088 1664 2117 1380 -112 -170 -743 67 878 312 354 571 367 475 -365 -553 -1141 -638 -964 -878 -738 -1974 -1864 -1192 -730 -421 25 683 502 604 265 -184 83 135 278 456 639 628 -382 -543 -852 -897 -500 -536 -937 -827 -501 -334 283 448 611 171 348 316 -1 49 141 354 177 53 236 189 516 562 403 -107 503 417 86 130 -33 -328 -212 84 -216 -165 489 180 34 19 -557 -759 -418 268 -410 -531 -761 117 -157 135 53 -327 -822 -631 117 -30 54 352 153 -557 735 266 128 463 676 201 606 -64 -173 -68 -138 708 410 533 172 -761 -792 -599 -800 -148 -226 -338 -905 -649 -490 102 -225 -562 -343 -848 -201 -101 98 589 948 485 690 890 595 571 409 282 857 1318 1808 1230 -95 -143 -597 54 735 296 333 545 366 448 -315 -460 -881 -489 -825 -790 -739 -2030 -2002 -1349 -833 -508 31 863 623 700 300 -190 86 134 302 515 804 809 -502 -719 -1047 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