File name: Pandora2s1_GreenbeltMD_20220925_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104512.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20220925_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20220925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220925T121956.3Z 8303.513846 75 1 12.23 2 75.05 103.81 70.25 101.54 0.00 1 0.00 1 0 17 1.654e-01 1.126e-02 1.621e-01 7.440e-03 4.719055e-01 3.801742e-03 5.466540e-03 -6.000000e+00 9.381617e-02 228.25 -2.00 3.47 -2.00 319.94 0.00e+00 1.916961e-04 1.230568e-03 1.032814e-03 -6.000000e+00 4.211875e-03 287.58 -2.00 20.00 -2.00 319.20 0.00e+00 3.799 0.001 302.00 328.00 3 4.2011e+00 1.1280e-02 4.4979e-02 -6.0000e+00 2.3309e-01 2.4247e-02 1.3725e-02 2.5253e-02 -6.0000e+00 2.5268e-01 -3.3102e-02 1.1400e-02 1.2245e-02 -6.0000e+00 1.5084e-01 9.6139e-03 5.8888e-03 3.3858e-03 -6.0000e+00 6.5127e-02 1.0902e-04 -2.1777e-04 2.1085e-04 3.7874e-05 -6.0000e+00 4.3145e-03 2.1088e-02 -4.1738e-06 12 9 9 12 1 1 4.69 22.83 0.42 0.02109 0.01945 5 5 1 5 0 2009.760 25.58 19.97 22.83 21.87 14.8 972.28 -63991 -51519 29764 -7099 12306 -102322 -8501 -68833 2053 -70072 13542 -7070 69989 -8077 -5042 -8473 -17778 6584 4133 1034 -33441 1306 -10732 2362 -4762 12824 -24047 22340 5321 -4630 -3114 6989 9164 -832 -707 -6761 -94 -9251 -2172 -5543 4273 -4993 255 253 5715 -1870 6017 -1720 1835 1446 1594 -3147 -1941 4001 2271 5369 -1770 2599 894 2852 2728 2443 1970 2215 990 3008 884 1448 1214 1551 2079 -780 3316 -4321 2440 -1684 664 -5263 881 -3204 -1992 -3174 -2073 -163 -23 101 298 1126 -1084 1903 -193 461 -873 1014 -1590 -24 -42 689 -567 38 -815 -1206 -285 -1207 -200 -1760 175 -1115 1354 404 243 -213 160 -345 295 -538 415 300 547 -14 -85 1058 -435 1240 220 704 -12 1026 -314 -231 323 -617 -704 703 198 -401 843 570 0 -1184 344 -980 -1266 -985 281 -88 116 -3192 -117 -1997 33 -2389 206 -154 863 -264 -190 -369 -916 287 195 53 -2402 67 -677 142 -328 772 -2041 1118 313 -332 -253 583 831 -81 -65 -706 -11 -1396 -373 -1134 852 -1148 57 57 1235 -439 1309 -410 434 369 451 -1014 -667 1382 827 1963 -704 967 331 1047 1075 1074 970 1157 505 1423 423 725 635 913 1293 -505 1988 -2608 1361 -886 326 -2879 523 -2087 -1457 -2592 -1766 -146 -22 103 313 1189 -1142 1816 -174 384 -717 874 -1590 -27 -49 879 -742 47 -929 -1369 -317 -1345 -235 -2204 228 -1571 2032 618 392 -344 267 -540 430 -780 619 476 923 -23 -143 1717 -692 1848 319 966 -16 1532 -526 -387 569 -1133 -1352 1420 427 -829 1759 1207 0 -2537 691 -1922 SS 20220925T123341.1Z 8303.523392 82 1 50.91 2 72.47 106.17 67.74 103.91 0.00 1 0.00 1 0 25 3.076e-01 1.396e-02 1.847e-01 9.459e-03 4.103371e-01 4.886933e-03 4.738938e-03 -6.000000e+00 1.757529e-01 228.25 -2.00 3.47 -2.00 319.91 0.00e+00 8.130111e-04 1.525726e-03 1.051533e-03 -6.000000e+00 7.971610e-03 287.58 -2.00 20.00 -2.00 319.15 0.00e+00 3.273 0.001 302.00 328.00 3 5.6496e+00 1.4371e-02 3.8821e-02 -6.0000e+00 4.3638e-01 4.6760e-02 1.7335e-02 2.1829e-02 -6.0000e+00 4.7328e-01 -1.1660e-02 1.4159e-02 1.0860e-02 -6.0000e+00 2.8164e-01 -3.8287e-03 7.3675e-03 3.0955e-03 -6.0000e+00 1.2211e-01 4.4386e-05 6.4058e-04 2.7893e-04 3.5073e-05 -6.0000e+00 8.0962e-03 1.9861e-02 4.9267e-05 12 9 8 11 8 0 99.72 22.87 0.81 0.01986 0.02467 14 3 1 5 0 3635.800 25.58 20.00 22.87 22.13 14.9 974.42 900000 33413 -17486 293714 -43748 900000 -72293 25788 68517 18559 -59722 6423 -11798 66371 55961 79826 29200 -35568 -15624 -2583 23406 19306 21728 10274 37899 -13833 -7960 -3915 4038 -22146 5463 -17140 7536 6108 -8556 323 -3491 -6634 5292 -2316 2633 8406 -2030 9293 -5467 8171 -13149 -2525 -3086 12804 6696 -1360 5421 1409 -1833 5090 2815 -1573 2745 -4287 6572 266 134 -2173 3444 1437 -1070 -3058 1361 1970 -676 -13 1163 -1307 -2653 1014 -5281 -4303 -515 1667 -1951 1608 -3745 519 -399 815 1825 1680 -38 -45 1438 -45 -1659 -2547 -1273 -799 1059 2143 193 -734 -806 -2017 -258 -466 674 -1771 -1863 394 -63 1382 865 586 1 -140 -1306 -400 -1395 1502 -315 -96 349 1341 1671 20 -183 -996 -432 463 634 -971 447 -719 -77 -854 46 -13 1059 224 198 81 -365 -701 900000 420 -366 2708 -990 900000 -2545 389 747 342 -2453 156 -415 1279 1407 1740 1126 -2802 -1061 -160 1118 971 1147 654 1938 -1229 -647 -285 267 -2079 440 -1939 733 642 -978 36 -467 -1107 951 -512 592 1868 -515 2108 -1452 1898 -3758 -652 -814 3069 1877 -445 1779 509 -705 1882 1074 -614 1005 -1707 2515 120 67 -1166 1667 665 -498 -1517 738 1193 -446 -8 734 -791 -1463 486 -2561 -2146 -283 1031 -1412 1230 -3177 449 -375 802 1845 1722 -39 -43 1233 -36 -1311 -2151 -1191 -841 1237 2709 250 -909 -916 -2121 -265 -521 795 -2236 -2490 546 -95 2230 1465 983 2 -209 -1838 -550 -2011 2241 -511 -158 563 2086 2498 28 -254 -1324 -569 656 982 -1645 784 -1311 -145 -1728 99 -28 2340 505 434 171 -734 -1366 SS 20220925T123924.5Z 8303.527367 85 1 50.27 2 71.41 107.18 66.70 104.92 0.00 1 0.00 1 0 25 7.936e-02 8.642e-03 1.018e-01 6.232e-03 3.954219e-01 3.206126e-03 4.631352e-03 -6.000000e+00 4.532476e-02 228.25 -2.00 3.47 -2.00 319.78 0.00e+00 2.171676e-03 9.501552e-04 7.336429e-04 -6.000000e+00 2.037280e-03 287.58 -2.00 20.00 -2.00 319.01 0.00e+00 3.097 0.000 302.00 328.00 3 5.1858e+00 9.3071e-03 3.6844e-02 -6.0000e+00 1.1255e-01 4.5866e-02 1.1120e-02 2.0576e-02 -6.0000e+00 1.2204e-01 -1.1630e-02 8.7945e-03 1.0627e-02 -6.0000e+00 7.2619e-02 -4.2605e-03 4.5956e-03 3.5774e-03 -6.0000e+00 3.1252e-02 8.4667e-05 2.8611e-05 1.8408e-04 3.8420e-05 -6.0000e+00 2.0813e-03 2.0191e-02 4.1911e-06 11 8 0 10 0 0 99.89 22.89 0.41 0.02019 0.02041 23 4 1 5 0 2185.360 25.58 19.99 22.89 22.27 14.9 975.97 -15500 8963 36117 29338 6075 900000 -19616 25643 7264 22462 23809 4505 -29474 -20322 -11319 28388 -20881 5372 -6922 9686 6782 5545 2126 -3183 1202 -10744 8922 -4745 -666 -7584 6414 -9928 1 -9224 2165 -5110 -4652 -5800 6262 -496 -4269 -2530 454 2960 -1612 3115 -1648 2246 84 4947 -551 1879 -827 841 1568 1978 -939 15 140 1257 3315 1863 2140 142 437 -1949 242 -464 1871 981 2387 899 288 1583 -2718 -690 -42 -44 -1515 563 -3011 -2051 -2227 194 -1763 708 -53 1140 -223 4 1356 -728 -301 358 195 897 994 256 534 -757 -889 -2011 -844 -1595 -978 -744 179 -728 1041 758 88 718 167 402 -397 500 -807 459 -613 -209 430 -59 272 1229 -98 -325 1229 320 -264 -135 20 -134 -190 -382 310 -670 370 310 450 270 -497 -667 -342 168 519 405 97 900000 -466 439 164 447 473 124 -1384 -1044 -625 1160 -1488 315 -482 594 427 355 150 -253 96 -1103 732 -418 -55 -737 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