File name: Pandora2s1_GreenbeltMD_20221210_L2Fit_fwvt1c14d20221101p1-8.txt File generation date: 20250301T104420.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v14d20221101.txt Level 1 file used: Pandora2s1_GreenbeltMD_20221210_L1_smca1c14d20221101p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20221210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP starting 20221101 with March 2023 ref period First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.1136 492.2348 492.3561 492.4773 492.5985 492.7197 492.8408 492.9620 493.0831 493.2042 493.3253 493.4464 493.5675 493.6885 493.8095 493.9306 494.0516 494.1725 494.2935 494.4145 494.5354 494.6563 494.7772 494.8981 495.0189 495.1398 495.2606 495.3814 495.5022 495.6230 495.7438 495.8645 495.9852 496.1060 496.2267 496.3473 496.4680 496.5886 496.7093 496.8299 496.9505 497.0710 497.1916 497.3121 497.4327 497.5532 497.6737 497.7941 497.9146 498.0350 498.1555 498.2759 498.3963 498.5166 498.6370 498.7573 498.8777 498.9980 499.1183 499.2385 499.3588 499.4790 499.5992 499.7194 499.8396 499.9598 500.0799 500.2001 500.3202 500.4403 500.5604 500.6805 500.8005 500.9205 501.0406 501.1606 501.2805 501.4005 501.5205 501.6404 501.7603 501.8802 502.0001 502.1199 502.2398 502.3596 502.4794 502.5992 502.7190 502.8388 502.9585 503.0782 503.1979 503.3176 503.4373 503.5570 503.6766 503.7962 503.9158 504.0354 504.1550 504.2745 504.3941 504.5136 504.6331 504.7526 504.8721 504.9915 505.1109 505.2304 505.3498 505.4691 505.5885 505.7079 505.8272 505.9465 506.0658 506.1851 506.3043 506.4236 506.5428 506.6620 506.7812 506.9004 507.0195 507.1387 507.2578 507.3769 507.4960 507.6151 507.7341 507.8532 507.9722 508.0912 508.2102 508.3292 508.4481 508.5670 508.6860 508.8049 508.9237 509.0426 509.1614 509.2803 509.3991 509.5179 509.6367 509.7554 509.8742 509.9929 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221210T121800.2Z 8379.512502 252 1 5.91 2 90.39 119.73 67.44 286.87 0.00 1 0.00 1 0 36 1.656e-02 1.640e-02 4.423e-03 4.380e-03 7.752751e+03 2.809571e+02 4.937422e+02 -6.000000e+00 9.241684e+02 278.86 -2.00 20.00 -2.00 505.44 0.00e+00 9.821467e-03 1.224513e-04 5.263797e-04 -6.000000e+00 4.649800e-04 278.86 -2.00 20.00 -2.00 501.39 0.00e+00 4.339266e-01 8.449623e-02 1.090878e-01 -6.000000e+00 3.325433e-01 223.20 -2.00 3.47 -2.00 502.80 0.00e+00 20.879 0.160 489.00 513.00 1 5.3188e+00 6.4523e-03 4.0497e-02 -6.0000e+00 2.5463e-02 -4.9693e-02 1.6326e-03 2.7306e-03 -6.0000e+00 6.6328e-03 4.2349e-04 -2.9504e-04 4.6143e-04 2.1303e-04 -6.0000e+00 1.8043e-03 -5.4202e-03 9.3909e-05 12 9 9 12 1 1 999.00 20.65 7.51 -0.00542 -0.00747 1 3 1 4 0 2872.740 24.25 18.85 20.65 4.30 14.5 875.72 -3763 -3137 -1462 -496 441 1896 3452 2289 1729 1254 78 -328 -766 -1909 -2294 -1355 -1114 337 1151 1027 900 1125 1238 2209 2248 1565 613 -600 -1679 -2181 -2462 -2232 -690 519 834 1308 307 -6 405 223 -239 50 2149 1383 2059 2298 2187 529 -462 -942 -1788 -2565 -3202 -2395 -855 495 1401 2634 1018 1275 1505 2195 1912 2105 1487 0 -98 -557 -1271 -1491 -1477 -1830 -1049 -1013 -257 -1682 -1834 -2028 -2504 -2158 -2478 -2477 -1490 -1058 -1620 -692 -917 -566 -415 554 1008 1113 2401 2145 1768 1141 -163 -775 -3035 -3203 -3233 -2924 -305 -421 652 -554 -31 -1900 -737 -423 532 904 2395 2201 3104 3938 3059 2387 1564 974 292 327 426 1294 961 899 556 1158 471 752 -152 -767 -1442 -2023 -1481 -1634 107 413 230 -48 1434 824 788 1359 449 -935 -2036 -1740 -2583 900000 -3220 -2740 -1247 -434 393 1701 3090 2079 1567 1127 69 -291 -673 -1686 -2035 -1203 -1005 306 1055 950 803 1006 1115 1992 2046 1439 567 -552 -1525 -1950 -2201 -2021 -634 487 794 1246 294 -6 385 214 -225 48 2051 1355 2030 2271 2157 525 -455 -913 -1716 -2458 -3110 -2362 -858 485 1388 2606 1029 1292 1534 2241 1967 2156 1519 0 -99 -561 -1276 -1490 -1475 -1849 -1064 -1037 -261 -1717 -1849 -2029 -2505 -2152 -2491 -2507 -1504 -1072 -1661 -704 -933 -572 -419 559 1029 1114 2398 2143 1747 1154 -163 -762 -2993 -3135 -3188 -2943 -297 -423 657 -565 -31 -1954 -757 -443 545 942 2502 2337 3304 4205 3322 2612 1712 1060 316 352 461 1402 1018 960 599 1243 509 808 -163 -817 -1536 -2168 -1596 -1796 118 460 260 -53 1575 916 880 1509 500 -1041 -2248 -1953 -2820 900000 SQ 20221210T122050.3Z 8379.514471 256 1 40.19 2 89.91 120.18 67.95 287.23 0.00 1 0.00 1 0 15 1.216e-02 1.199e-02 3.415e-04 3.382e-04 7.037756e+03 2.169060e+01 4.487048e+02 -6.000000e+00 6.783329e+02 278.86 -2.00 20.00 -2.00 505.48 0.00e+00 8.490077e-03 9.471371e-06 4.602003e-04 -6.000000e+00 3.406513e-04 278.86 -2.00 20.00 -2.00 501.46 0.00e+00 7.400790e-01 6.480551e-03 9.751125e-02 -6.000000e+00 2.415139e-01 223.20 -2.00 3.47 -2.00 502.88 0.00e+00 20.454 0.151 489.00 513.00 1 2.8130e+00 4.9587e-04 3.8582e-02 -6.0000e+00 1.8535e-02 -5.6099e-02 1.2273e-04 2.5686e-03 -6.0000e+00 4.7520e-03 5.5036e-03 1.5852e-03 3.5622e-05 1.8359e-04 -6.0000e+00 1.3193e-03 9.6911e-03 -7.1427e-05 12 9 9 12 1 1 95.47 21.52 5.45 0.00969 0.02069 167 40 1 4 0 238.190 24.25 18.61 21.52 4.37 14.5 876.01 -2995 -2194 -939 179 1085 1704 1998 1916 1606 964 262 -456 -1033 -1453 -1452 -1180 -494 187 804 871 906 962 1047 1242 1352 1191 719 74 -910 -1855 -2001 -1505 -624 358 866 798 551 59 -211 -187 -2 476 875 1370 1559 1449 1174 678 -177 -1102 -1957 -2395 -2288 -1588 -525 331 776 1023 1109 1125 1370 1425 1442 1236 874 393 -145 -564 -970 -1225 -1281 -1017 -695 -452 -496 -945 -1422 -1897 -1975 -2042 -1808 -1580 -1289 -1063 -883 -796 -767 -659 -485 -92 372 858 1305 1368 1079 431 -278 -1239 -2034 -2436 -2277 -1629 -669 -23 116 -241 -734 -895 -790 -266 405 1023 1686 2060 2297 2317 2230 1893 1381 895 520 403 545 706 752 853 836 734 620 430 -71 -642 -1087 -1291 -1059 -521 -76 279 611 667 720 732 798 710 408 -234 -982 -1681 -1894 -1617 -2566 -1916 -800 156 965 1538 1823 1755 1465 873 236 -408 -917 -1287 -1289 -1056 -448 172 748 780 815 869 952 1139 1250 1106 667 68 -824 -1662 -1791 -1362 -577 338 830 768 529 56 -203 -181 -2 452 843 1337 1536 1436 1161 667 -173 -1061 -1864 -2270 -2181 -1539 -520 335 796 1013 1103 1124 1376 1441 1464 1254 883 394 -145 -558 -954 -1199 -1255 -1002 -691 -453 -497 -941 -1404 -1863 -1932 -2001 -1778 -1561 -1280 -1062 -887 -801 -770 -659 -485 -92 378 884 1353 1412 1102 434 -275 -1209 -1964 -2343 -2205 -1607 -676 -24 116 -243 -739 -900 -803 -275 424 1088 1812 2235 2514 2465 2393 2039 1482 954 550 425 577 754 809 923 910 801 679 470 -77 -693 -1169 -1393 -1153 -575 -85 305 674 743 807 826 904 806 462 -263 -1090 -1852 -2087 -1798 SQ 20221210T122343.4Z 8379.516474 260 1 31.34 2 89.43 120.63 68.47 287.60 0.00 1 0.00 1 0 15 9.221e-03 9.118e-03 2.365e-04 2.349e-04 6.756144e+03 1.508780e+01 4.437380e+02 -6.000000e+00 5.143654e+02 278.86 -2.00 20.00 -2.00 505.47 0.00e+00 6.869135e-03 6.544221e-06 3.739379e-04 -6.000000e+00 2.583118e-04 278.86 -2.00 20.00 -2.00 501.32 0.00e+00 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