File name: Pandora2s1_GreenbeltMD_20230916_L2Fit_fwvt1c15d20230712p1-8.txt File generation date: 20250301T104432.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v15d20230712.txt Level 1 file used: Pandora2s1_GreenbeltMD_20230916_L1_smca1c15d20230712p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20230916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP for July-Sept 2023 when set temperature was increased, based on session 9 lab cal First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.0840 492.2052 492.3265 492.4478 492.5690 492.6902 492.8114 492.9326 493.0537 493.1749 493.2960 493.4171 493.5382 493.6593 493.7803 493.9014 494.0224 494.1434 494.2644 494.3854 494.5063 494.6273 494.7482 494.8691 494.9900 495.1109 495.2317 495.3526 495.4734 495.5942 495.7150 495.8357 495.9565 496.0772 496.1980 496.3187 496.4394 496.5600 496.6807 496.8013 496.9219 497.0425 497.1631 497.2837 497.4042 497.5248 497.6453 497.7658 497.8863 498.0067 498.1272 498.2476 498.3680 498.4884 498.6088 498.7292 498.8495 498.9699 499.0902 499.2105 499.3307 499.4510 499.5713 499.6915 499.8117 499.9319 500.0521 500.1722 500.2924 500.4125 500.5326 500.6527 500.7728 500.8928 501.0129 501.1329 501.2529 501.3729 501.4929 501.6128 501.7328 501.8527 501.9726 502.0925 502.2123 502.3322 502.4520 502.5718 502.6916 502.8114 502.9312 503.0509 503.1707 503.2904 503.4101 503.5298 503.6494 503.7691 503.8887 504.0083 504.1279 504.2475 504.3671 504.4866 504.6061 504.7256 504.8451 504.9646 505.0841 505.2035 505.3229 505.4423 505.5617 505.6811 505.8004 505.9198 506.0391 506.1584 506.2777 506.3970 506.5162 506.6354 506.7547 506.8739 506.9930 507.1122 507.2314 507.3505 507.4696 507.5887 507.7078 507.8268 507.9459 508.0649 508.1839 508.3029 508.4219 508.5408 508.6598 508.7787 508.8976 509.0165 509.1354 509.2542 509.3731 509.4919 509.6107 509.7295 509.8482 509.9670 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20230916T105542.1Z 8659.455348 25 1 31.91 2 89.63 86.90 104.80 81.20 0.00 1 0.00 1 0 29 1.086e-02 1.069e-02 3.975e-04 3.947e-04 1.820682e+04 2.965642e+01 1.157264e+03 -6.000000e+00 6.299247e+02 288.64 -2.00 20.00 -2.00 505.49 0.00e+00 3.321716e-03 1.128352e-05 1.950007e-04 -6.000000e+00 3.117694e-04 288.64 -2.00 20.00 -2.00 501.26 0.00e+00 1.144490e+00 7.572707e-03 1.219233e-01 -6.000000e+00 2.163030e-01 229.17 -2.00 3.47 -2.00 502.72 0.00e+00 19.786 0.136 489.00 513.00 1 2.8359e+00 5.8167e-04 3.5959e-02 -6.0000e+00 1.6651e-02 -5.6381e-02 1.4265e-04 3.4627e-03 -6.0000e+00 4.2640e-03 6.0113e-03 2.6280e-03 3.7960e-05 1.2808e-04 -6.0000e+00 1.1802e-03 1.0148e-02 3.4499e-05 12 9 9 12 1 1 42.21 26.96 5.16 0.01015 0.02838 116 24 1 4 0 272.680 29.80 24.97 26.96 18.62 18.9 954.53 -2291 -1563 -380 507 1362 1824 2103 1966 1687 965 362 -290 -727 -1139 -1180 -747 -212 226 499 725 814 785 913 938 1146 939 527 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-1085 -850 -765 -799 -733 -543 -184 180 601 947 1334 1215 888 264 -417 -1248 -1823 -2154 -1910 -1316 -593 23 185 -236 -631 -793 -754 -446 80 625 1256 1727 2134 2246 2129 1673 1049 407 294 300 568 879 1060 994 963 733 564 252 -99 -569 -881 -1030 -798 -205 229 596 827 945 855 919 890 825 501 -176 -1024 -1684 -1928 -1581 SO 20230916T105832.6Z 8659.457322 29 1 33.57 2 89.08 87.35 104.27 81.66 0.00 1 0.00 1 0 22 7.834e-03 7.728e-03 2.241e-04 2.231e-04 1.647056e+04 1.648690e+01 1.061629e+03 -6.000000e+00 4.542003e+02 288.64 -2.00 20.00 -2.00 505.45 0.00e+00 2.779800e-03 6.362504e-06 1.652991e-04 -6.000000e+00 2.247973e-04 288.64 -2.00 20.00 -2.00 501.11 0.00e+00 1.226795e+00 4.304519e-03 1.074408e-01 -6.000000e+00 1.560146e-01 229.17 -2.00 3.47 -2.00 502.60 0.00e+00 18.707 0.115 489.00 513.00 1 1.9652e+00 3.3069e-04 3.2749e-02 -6.0000e+00 1.2009e-02 -4.2958e-02 8.1568e-05 3.1078e-03 -6.0000e+00 3.0766e-03 1.6766e-02 2.4692e-03 2.1718e-05 1.1354e-04 -6.0000e+00 8.5096e-04 1.8821e-03 6.1646e-05 12 8 8 10 0 0 15.23 26.89 3.28 0.00188 0.01901 304 58 1 4 0 110.420 29.80 24.94 26.89 18.67 18.9 954.77 -1546 -1051 -325 385 977 1364 1521 1354 1297 805 281 -202 -516 -793 -799 -545 -173 168 447 550 547 571 676 728 841 721 281 -158 -642 -1179 -1287 -938 -419 109 339 315 124 -190 -263 -303 -152 125 454 699 842 841 657 214 -350 -892 -1371 -1631 -1449 -1046 -399 140 480 633 662 815 822 963 884 786 512 219 -170 -449 -673 -825 -878 -680 -501 -330 -420 -641 -967 -1246 -1285 -1251 -1119 -1007 -785 -629 -554 -615 -516 -330 -147 106 349 721 950 966 702 346 -284 -943 -1450 -1670 -1516 -1031 -441 -59 -4 -258 -455 -568 -520 -289 -62 384 820 1202 1496 1531 1473 1124 807 383 262 260 448 591 700 662 651 483 411 229 -77 -412 -644 -650 -500 -162 158 379 613 577 592 552 637 522 336 -74 -643 -1051 -1237 -1050 -1339 -928 -295 359 891 1268 1434 1287 1229 758 263 -187 -475 -728 -735 -506 -163 162 439 523 523 548 652 706 820 704 274 -152 -607 -1146 -1247 -881 -402 108 341 318 124 -190 -261 -302 -152 126 465 695 842 843 656 211 -355 -890 -1343 -1580 -1406 -1031 -386 139 483 641 672 828 839 988 910 807 523 221 -170 -445 -663 -808 -860 -671 -499 -332 -422 -640 -953 -1216 -1245 -1210 -1087 -985 -775 -628 -559 -623 -522 -332 -148 107 353 735 966 964 683 327 -261 -889 -1354 -1560 -1381 -971 -433 -58 -5 -263 -463 -576 -530 -297 -65 402 862 1266 1525 1581 1543 1189 851 400 270 264 454 601 717 682 674 501 426 237 -79 -421 -656 -666 -519 -171 170 399 656 627 650 611 708 581 373 -82 -702 -1138 -1339 -1146 SO 20230916T110119.6Z 8659.459255 33 1 33.68 2 88.54 87.79 103.76 82.12 0.00 1 0.00 1 0 29 6.235e-03 6.164e-03 1.525e-04 1.520e-04 1.422688e+04 1.102324e+01 9.238932e+02 -6.000000e+00 3.615190e+02 288.64 -2.00 20.00 -2.00 505.42 0.00e+00 2.331918e-03 4.327952e-06 1.400649e-04 -6.000000e+00 1.789273e-04 288.64 -2.00 20.00 -2.00 501.01 0.00e+00 1.238955e+00 2.949262e-03 9.363068e-02 -6.000000e+00 1.241885e-01 229.17 -2.00 3.47 -2.00 502.52 0.00e+00 17.379 0.092 489.00 513.00 1 1.4260e+00 2.2662e-04 2.9248e-02 -6.0000e+00 9.5592e-03 -3.1711e-02 5.6189e-05 2.7229e-03 -6.0000e+00 2.4492e-03 3.4955e-02 2.2618e-03 1.4999e-05 1.0150e-04 -6.0000e+00 6.7733e-04 6.9174e-03 2.5677e-05 12 8 8 10 0 0 35.73 26.95 2.38 0.00692 0.02261 570 109 1 4 0 58.770 29.80 24.98 26.95 18.69 18.9 955.15 -1222 -838 -270 305 765 1083 1198 1103 987 641 232 -181 -378 -593 -596 -431 -170 120 408 437 423 485 512 605 650 539 203 -132 -490 -908 -974 -703 -322 82 238 236 113 -128 -227 -257 -142 86 376 566 652 623 488 150 -288 -755 -1115 -1308 -1189 -831 -354 50 327 484 548 644 683 755 668 622 407 200 -137 -380 -523 -625 -679 -574 -415 -274 -321 -497 -766 -974 -1017 -1036 -905 -832 -613 -515 -448 -474 -379 -255 -100 93 298 512 706 767 565 252 -245 -698 -1121 -1304 -1165 -831 -431 -105 -90 -246 -381 -469 -423 -309 -30 338 678 938 1233 1263 1216 912 644 333 293 218 361 472 515 484 520 390 302 214 -41 -341 -516 -533 -378 -114 120 350 481 495 475 504 503 411 241 -91 -514 -883 -991 -869 -1070 -748 -248 288 710 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