File name: Pandora2s1_GreenbeltMD_20231105_L2Fit_fwvt1c9d20220412p1-8.txt File generation date: 20231106T054030.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20231105_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20231105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.0848 492.2060 492.3273 492.4485 492.5697 492.6909 492.8121 492.9332 493.0543 493.1755 493.2966 493.4177 493.5387 493.6598 493.7808 493.9018 494.0228 494.1438 494.2648 494.3857 494.5067 494.6276 494.7485 494.8694 494.9902 495.1111 495.2319 495.3527 495.4735 495.5943 495.7151 495.8358 495.9566 496.0773 496.1980 496.3187 496.4393 496.5600 496.6806 496.8012 496.9218 497.0424 497.1630 497.2835 497.4040 497.5245 497.6450 497.7655 497.8860 498.0064 498.1269 498.2473 498.3677 498.4880 498.6084 498.7287 498.8491 498.9694 499.0897 499.2099 499.3302 499.4504 499.5707 499.6909 499.8111 499.9312 500.0514 500.1715 500.2917 500.4118 500.5318 500.6519 500.7720 500.8920 501.0120 501.1320 501.2520 501.3720 501.4919 501.6119 501.7318 501.8517 501.9716 502.0914 502.2113 502.3311 502.4509 502.5707 502.6905 502.8103 502.9300 503.0498 503.1695 503.2892 503.4089 503.5285 503.6482 503.7678 503.8874 504.0070 504.1266 504.2461 504.3657 504.4852 504.6047 504.7242 504.8437 504.9631 505.0826 505.2020 505.3214 505.4408 505.5601 505.6795 505.7988 505.9182 506.0375 506.1567 506.2760 506.3953 506.5145 506.6337 506.7529 506.8721 506.9913 507.1104 507.2295 507.3486 507.4677 507.5868 507.7059 507.8249 507.9439 508.0630 508.1819 508.3009 508.4199 508.5388 508.6577 508.7766 508.8955 509.0144 509.1333 509.2521 509.3709 509.4897 509.6085 509.7273 509.8460 509.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20231105T114647.6Z 8709.490829 247 1 33.47 2 89.40 110.87 18.75 198.08 0.00 1 0.00 1 0 43 1.584e-02 1.561e-02 7.925e-04 7.848e-04 1.287030e+04 5.521536e+01 8.325211e+02 -6.000000e+00 8.971258e+02 282.73 -2.00 20.00 -2.00 505.54 0.00e+00 4.411062e-03 2.214249e-05 2.405391e-04 -6.000000e+00 4.480225e-04 282.73 -2.00 20.00 -2.00 501.42 0.00e+00 9.067943e-01 1.495560e-02 1.057314e-01 -6.000000e+00 3.144934e-01 224.44 -2.00 3.47 -2.00 502.87 0.00e+00 19.554 0.132 489.00 513.00 1 4.2526e+00 1.1459e-03 3.5100e-02 -6.0000e+00 2.4168e-02 -6.3869e-02 2.8006e-04 3.0071e-03 -6.0000e+00 6.1923e-03 1.5303e-03 6.4182e-03 7.9312e-05 1.2622e-04 -6.0000e+00 1.7196e-03 2.1858e-03 1.1851e-04 12 9 9 12 1 1 59.83 21.83 8.24 0.00219 0.04670 39 8 1 4 0 836.550 24.86 19.81 21.83 13.87 19.1 931.16 -3878 -2334 -775 676 1793 2551 2712 2434 1996 923 111 -698 -1470 -2129 -1783 -1274 -370 494 1016 1164 1142 1095 1252 1660 1526 1331 544 -298 -1818 -2561 -2539 -1738 -447 763 1136 870 370 -54 -235 -257 134 809 1258 1789 2092 1736 1442 460 -485 -1890 -2754 -3130 -2667 -1661 -100 953 1393 1629 1468 1737 1880 2062 1819 1427 879 332 -480 -982 -1611 -1815 -1725 -1243 -840 -627 -800 -1570 -2147 -2614 -2661 -2623 -2077 -1945 -1556 -1195 -1004 -1101 -1047 -974 -471 7 920 1519 1902 1737 1103 173 -859 -2142 -3003 -3141 -2585 -1593 -318 442 376 -405 -934 -1292 -820 -282 516 1096 2015 2472 2983 3246 2906 2009 1462 543 424 343 766 1270 1058 1178 1149 988 724 276 -559 -999 -1525 -1455 -1061 -409 282 770 1039 1039 1125 1102 1125 1010 562 -466 -1531 -2336 -2377 -1994 -3338 -2037 -652 579 1562 2252 2422 2187 1789 826 99 -619 -1302 -1890 -1585 -1143 -336 457 950 1096 1082 1042 1198 1596 1478 1292 500 -286 -1731 -2416 -2401 -1662 -412 717 1081 830 353 -51 -223 -246 129 785 1236 1773 2084 1736 1436 456 -476 -1838 -2651 -3000 -2568 -1623 -99 962 1422 1671 1438 1704 1854 2043 1811 1420 871 327 -471 -957 -1566 -1759 -1675 -1214 -827 -622 -793 -1549 -2100 -2544 -2579 -2547 -2020 -1907 -1536 -1190 -1007 -1108 -1052 -975 -470 7 926 1536 1915 1724 1074 165 -806 -1992 -2782 -2917 -2437 -1543 -318 454 394 -428 -941 -1305 -832 -289 534 1143 2102 2589 3141 3454 3135 2190 1588 587 452 364 813 1352 1137 1272 1246 1074 790 301 -607 -1079 -1652 -1585 -1172 -437 305 845 1155 1169 1277 1260 1291 1159 644 -532 -1740 -2649 -2702 -2289 SO 20231105T114941.3Z 8709.492840 251 1 33.89 2 88.88 111.33 18.94 200.05 0.00 1 0.00 1 0 36 1.219e-02 1.206e-02 9.260e-04 9.172e-04 1.451538e+04 6.498065e+01 9.570012e+02 -6.000000e+00 6.906048e+02 282.73 -2.00 20.00 -2.00 505.51 0.00e+00 3.973487e-03 2.581405e-05 2.187748e-04 -6.000000e+00 3.448837e-04 282.73 -2.00 20.00 -2.00 501.39 0.00e+00 1.026219e+00 1.750043e-02 1.093270e-01 -6.000000e+00 2.420976e-01 224.44 -2.00 3.47 -2.00 502.83 0.00e+00 18.378 0.109 489.00 513.00 1 4.6586e+00 1.3456e-03 3.2147e-02 -6.0000e+00 1.8604e-02 -6.5303e-02 3.2734e-04 3.0728e-03 -6.0000e+00 4.7668e-03 1.1950e-03 5.4402e-03 9.1061e-05 1.3817e-04 -6.0000e+00 1.3237e-03 -3.9827e-03 1.5555e-04 12 8 8 10 0 0 39.11 21.77 5.90 -0.00398 0.03375 38 7 1 4 0 891.630 24.86 19.83 21.77 14.03 19.0 931.75 -2841 -1582 -228 566 1503 2116 2119 1927 1514 810 20 -504 -880 -1366 -1300 -903 -322 433 352 723 910 942 958 1246 1289 1087 509 -325 -1199 -2147 -2005 -1253 -367 291 936 530 206 -111 -380 -372 168 543 980 1199 1488 1298 944 416 -558 -1266 -2224 -2460 -2184 -1380 -197 628 892 1082 1126 1178 1537 1470 1454 1105 915 10 -412 -871 -1075 -1666 -1260 -1074 -588 -406 -610 -1008 -1616 -1856 -1881 -2046 -1569 -1428 -1176 -944 -930 -801 -698 -504 -382 228 630 1353 1491 1282 1055 250 -537 -1600 -2333 -2747 -2148 -1171 -335 199 314 -357 -649 -989 -653 -362 167 815 1350 1978 2331 2435 2128 1680 1065 581 247 368 622 1035 846 1022 973 675 548 336 -354 -909 -1121 -1282 -666 -323 200 386 909 859 976 848 1053 978 507 -251 -1197 -1785 -1976 -1619 -2421 -1369 -202 484 1308 1870 1898 1736 1361 725 18 -446 -773 -1200 -1147 -804 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0.00e+00 1.234338e+00 2.471788e-02 9.712046e-02 -6.000000e+00 1.488417e-01 224.44 -2.00 3.47 -2.00 502.59 0.00e+00 16.053 0.073 489.00 513.00 1 5.2264e+00 1.8967e-03 2.6583e-02 -6.0000e+00 1.1438e-02 -4.4235e-02 4.6723e-04 2.6929e-03 -6.0000e+00 2.9296e-03 9.4133e-04 3.5054e-03 1.2662e-04 1.0788e-04 -6.0000e+00 8.1401e-04 2.4081e-02 1.1856e-05 12 9 9 12 1 1 -4.29 21.98 2.72 0.02408 0.04840 9 3 1 4 0 1939.730 24.86 19.86 21.98 14.10 19.1 932.13 -1458 -1114 75 334 932 1328 1361 1171 794 283 35 -299 -590 -944 -929 -777 -47 55 91 497 484 373 842 1034 1032 680 228 -175 -756 -1195 -1232 -865 -264 154 696 341 18 90 -136 -293 -67 136 613 735 654 718 342 374 -107 -841 -1285 -1676 -1484 -865 -21 36 499 717 658 865 1092 1162 916 471 833 211 -242 -585 -693 -775 -1056 -515 -604 -280 -268 -532 -1147 -1070 -1327 -1247 -1206 -1143 -703 -763 -544 -359 -321 -81 -143 142 557 579 927 525 687 -103 -213 -798 -1548 -1247 -1366 -798 -226 226 201 -285 -463 -730 -428 -407 209 457 658 1184 1342 1562 1333 917 958 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