File name: Pandora2s1_GreenbeltMD_20231127_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20231128T055140.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20231127_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20231127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231127T123727.3Z 8731.526010 280 1 50.00 2 85.02 122.42 92.51 304.26 0.00 1 0.00 1 0 17 5.694e-01 4.430e-02 4.649e-01 4.210e-02 9.367535e-01 2.354483e-02 1.058174e-02 -6.000000e+00 3.200795e-01 223.41 -2.00 3.47 -2.00 322.19 0.00e+00 -1.554045e-02 9.164903e-03 2.438144e-03 -6.000000e+00 1.438173e-02 280.24 -2.00 20.00 -2.00 321.67 0.00e+00 9.858 0.017 302.00 328.00 3 1.7087e-01 8.1758e-02 1.1214e-01 -6.0000e+00 7.9018e-01 1.8277e+00 9.6807e-02 6.4540e-02 -6.0000e+00 8.6448e-01 -2.1218e+00 5.9857e-02 2.3612e-02 -6.0000e+00 5.1542e-01 7.8950e-01 3.3383e-02 1.4735e-02 -6.0000e+00 2.1970e-01 1.0409e-05 -7.5543e-04 1.1219e-03 1.7131e-04 -6.0000e+00 1.5100e-02 5.2782e-02 -2.1907e-05 12 9 8 11 8 0 2.89 20.78 0.52 0.05278 0.04711 44 8 1 5 0 1136.130 24.56 19.75 20.78 10.94 18.5 916.40 40694 -395 149399 19063 -59875 10612 12743 47226 -22220 14952 39088 -2300 71806 329124 47442 900000 900000 102982 78261 -40162 87501 -20364 75464 -20102 163911 -44677 900000 -44636 30212 5476 11447 -36808 49138 163540 -61067 184257 -52031 60857 -13334 43127 32724 213474 96595 2639 45825 129683 -35455 -11686 40602 61721 78275 34335 74517 8278 116667 -5165 58796 13508 75423 -49835 21613 32369 30978 50970 11602 34101 8341 45031 14354 15924 326 48200 3027 -14924 -35886 9026 -1621 51279 2256 -1972 -15812 18733 4534 12732 -2719 11725 16423 -5424 8209 -22264 4974 -7947 15749 -7230 8158 -9276 6355 -1487 -561 895 -1457 -321 -1165 1898 -8379 1326 -2762 4756 -9145 5130 -3652 7775 -4310 1607 -2784 -1206 -884 3296 2539 -3542 3508 -665 1742 2753 5928 -1602 248 118 1711 -1084 611 -695 -1168 -2088 856 1722 791 500 -976 538 -2716 1128 3200 -43 6129 1108 -6550 580 741 2099 -2051 920 1871 -181 2946 13502 2919 900000 900000 4225 3502 -5392 3590 -1975 3096 -2324 6724 -6332 900000 -4495 1352 347 768 -4393 2566 6709 -7743 7559 -6986 3177 -1740 3538 3051 8757 4323 276 2905 5320 -4760 -1264 2726 3683 4379 3201 5002 1142 5656 -867 5043 1662 4501 -9850 2176 3259 3581 5132 1687 3942 1306 5374 2677 3207 79 7010 632 -3284 -8431 1245 -254 5355 463 -500 -5366 5533 1637 4492 -1183 4569 6198 -2514 3165 -10778 1734 -3130 5233 -3500 4016 -6393 4380 -1232 -465 687 -1022 -197 -712 1215 -6290 957 -2266 4078 -10504 5914 -5063 9983 -6224 2116 -3712 -1603 -1230 4651 3719 -5362 4677 -889 2215 3366 6858 -1952 318 179 2982 -2201 1338 -1660 -3022 -5910 2483 5036 2365 1488 -2779 1391 -6697 2560 SS 20231127T124850.8Z 8731.533922 283 1 50.46 2 83.17 124.34 94.23 306.06 0.00 1 0.00 1 0 17 5.888e-01 1.300e-02 3.450e-01 7.512e-03 8.323929e-01 4.234672e-03 9.325043e-03 -6.000000e+00 3.290846e-01 223.41 -2.00 3.47 -2.00 322.24 0.00e+00 9.887669e-03 2.600062e-03 3.281670e-03 -6.000000e+00 1.490463e-02 280.24 -2.00 20.00 -2.00 321.80 0.00e+00 7.692 0.008 302.00 328.00 3 3.0267e-01 1.7165e-02 8.8472e-02 -6.0000e+00 8.0994e-01 5.5118e-01 2.6554e-02 4.7646e-02 -6.0000e+00 8.8423e-01 -6.7342e-01 2.8601e-02 2.8493e-02 -6.0000e+00 5.2523e-01 2.5813e-01 1.2811e-02 1.3139e-02 -6.0000e+00 2.2598e-01 9.1201e-05 -9.9260e-04 2.1159e-04 2.0298e-04 -6.0000e+00 1.5677e-02 5.2722e-02 -8.1348e-05 12 8 8 10 0 0 28.77 20.67 0.29 0.05272 0.04526 167 32 1 5 0 302.120 24.56 19.01 20.67 11.28 18.5 919.53 -256055 -173607 -207886 900000 -210807 900000 -216647 -87333 -230160 -57925 -212782 50905 -131377 -119205 -114326 -95171 -26538 30432 -14120 -97263 18997 -104674 13977 -95542 -58477 -69645 -39393 -22345 -67200 -6635 -35175 -48622 -27994 6430 9364 25173 -11877 62590 1870 34272 -1024 16334 -8483 23245 -14138 36520 6732 484 16947 5172 22697 16388 30896 10840 29576 7188 18425 8842 15531 -8722 16810 9094 23360 8610 2242 11399 7947 8836 4989 10196 7316 8958 4903 7340 2252 4125 -6892 6250 -4431 1607 309 568 953 -643 2015 325 1495 1661 614 -3501 533 -5584 -1817 -5004 -2443 -1843 766 -804 182 -257 -2151 -1533 -1987 -2309 -3758 -1335 -1513 608 -118 1057 142 -72 -207 -163 -541 -1035 258 40 526 138 1842 1311 1108 654 383 499 676 186 444 -25 -150 -345 -193 35 -20 322 415 269 -350 130 -1017 -401 -4218 -1377 -2491 900000 -2105 900000 -2451 -639 -3370 -424 -2974 373 -1486 -1587 -1826 -1457 -230 223 -122 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8.2643e-01 1.7465e-01 8.2886e-03 4.0177e-02 -6.0000e+00 9.0163e-01 -2.1590e-01 9.0203e-03 2.2705e-02 -6.0000e+00 5.3802e-01 7.7783e-02 4.1442e-03 7.9209e-03 -6.0000e+00 2.3194e-01 3.9521e-04 -7.1498e-04 7.7910e-05 1.0798e-04 -6.0000e+00 1.5773e-02 5.2301e-02 -9.6053e-05 11 8 0 10 0 0 28.34 21.17 0.25 0.05230 0.04693 386 74 1 5 0 130.270 24.56 19.75 21.17 11.88 18.5 923.17 -217878 -168067 -150393 -202546 -238231 -208046 -213905 -152679 -180311 -180502 -174309 -127669 -96615 -79367 -94216 -73872 -70015 -54691 -54455 -65234 -59312 -80240 -9959 -68280 -25000 -58094 -59159 -55073 -40468 -21750 6151 2040 -8879 -17435 -19787 -15544 -12304 1643 1815 3238 -264 503 3337 4580 1967 4473 8360 2349 4021 3780 9063 7364 8784 4470 2922 4459 5601 -1034 2349 1620 4582 6900 6613 4818 5325 1988 2546 3635 3207 3176 2426 3649 1892 1966 -1284 -1977 -3378 -912 -1317 -557 -530 -1311 -1765 -1104 169 -521 707 1260 766 58 -190 -1087 -695 -790 -1040 352 800 94 -278 -737 -1264 -1225 -1236 -1459 -1692 -1024 -1167 -461 350 260 317 337 8 -57 -240 -175 147 319 63 270 351 659 540 776 397 217 647 116 165 -51 -54 -422 -67 -121 -91 72 443 19 -163 72 -345 -341 -1994 -1040 -781 -1604 -2593 -1802 -2223 -982 -1695 -1786 -1811 -1074 -789 -707 -1212 -896 -918 -677 -714 -984 -836 -1449 -99 -1318 -334 -1121 -1127 -981 -671 -366 96 43 -234 -484 -544 -448 -405 58 79 159 -15 29 194 267 121 276 519 164 298 316 816 746 966 551 382 597 742 -142 303 216 652 1104 1224 979 1061 407 539 838 866 958 774 1141 567 537 -323 -466 -822 -244 -428 -212 -234 -648 -929 -618 100 -326 450 801 473 33 -104 -577 -380 -491 -759 296 777 102 -303 -758 -1174 -1022 -1028 -1317 -1619 -1028 -1266 -548 468 391 512 550 13 -85 -348 -256 225 517 107 448 556 1007 798 1100 547 291 903 186 302 -104 -119 -890 -149 -291 -231 185 1160 50 -408 170 -763 -801 SS 20231127T131516.1Z 8731.552269 291 1 50.32 2 79.06 128.98 98.06 310.38 0.00 1 0.00 1 0 25 3.132e-01 5.479e-03 4.615e-02 1.111e-03 6.006847e-01 5.845460e-04 6.802291e-03 -6.000000e+00 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