File name: Pandora2s1_GreenbeltMD_20240209_L2Fit_fout2c16d20230922p1-8.txt File generation date: 20250301T104602.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v16d20230922.txt Level 1 file used: Pandora2s1_GreenbeltMD_20240209_L1_smca1c16d20230922p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP starting 20230922, based on session 14 after set temperature returned to 20C First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0155 305.1566 305.2976 305.4387 305.5797 305.7207 305.8617 306.0027 306.1437 306.2847 306.4256 306.5666 306.7075 306.8485 306.9894 307.1303 307.2712 307.4121 307.5529 307.6938 307.8347 307.9755 308.1163 308.2571 308.3979 308.5387 308.6795 308.8203 308.9611 309.1018 309.2426 309.3833 309.5240 309.6647 309.8054 309.9461 310.0868 310.2274 310.3681 310.5087 310.6493 310.7900 310.9306 311.0712 311.2117 311.3523 311.4929 311.6334 311.7740 311.9145 312.0550 312.1955 312.3360 312.4765 312.6170 312.7574 312.8979 313.0383 313.1787 313.3192 313.4596 313.5999 313.7403 313.8807 314.0211 314.1614 314.3017 314.4421 314.5824 314.7227 314.8630 315.0033 315.1435 315.2838 315.4240 315.5643 315.7045 315.8447 315.9849 316.1251 316.2653 316.4054 316.5456 316.6857 316.8259 316.9660 317.1061 317.2462 317.3863 317.5264 317.6664 317.8065 317.9465 318.0865 318.2266 318.3666 318.5066 318.6466 318.7865 318.9265 319.0664 319.2064 319.3463 319.4862 319.6261 319.7660 319.9059 320.0458 320.1856 320.3255 320.4653 320.6052 320.7450 320.8848 321.0246 321.1643 321.3041 321.4439 321.5836 321.7233 321.8631 322.0028 322.1425 322.2822 322.4218 322.5615 322.7012 322.8408 322.9804 323.1201 323.2597 323.3993 323.5388 323.6784 323.8180 323.9575 324.0971 324.2366 324.3761 324.5156 324.6551 324.7946 324.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240209T132712.0Z 8805.560556 76 1 49.86 2 76.59 121.95 79.46 129.07 0.00 1 0.00 1 0 17 4.721e-01 1.264e-02 3.201e-01 8.475e-03 6.055107e-01 4.472248e-03 6.811663e-03 -6.000000e+00 2.645108e-01 224.77 -2.00 3.47 -2.00 321.12 0.00e+00 3.091311e-03 1.951639e-03 1.680687e-03 -6.000000e+00 1.146296e-02 276.36 -2.00 20.00 -2.00 320.61 0.00e+00 4.209 0.001 302.00 328.00 3 4.4573e+00 1.4341e-02 5.2136e-02 -6.0000e+00 6.5526e-01 9.7013e-02 1.9348e-02 3.2256e-02 -6.0000e+00 7.1528e-01 -1.0415e-01 2.0083e-02 1.8266e-02 -6.0000e+00 4.2345e-01 3.4580e-02 9.7969e-03 6.7208e-03 -6.0000e+00 1.8067e-01 4.7873e-05 -5.9158e-04 2.4237e-04 8.2855e-05 -6.0000e+00 1.2496e-02 2.0702e-02 -5.8631e-07 12 8 8 10 0 0 99.92 21.74 0.25 0.02070 0.01626 37 7 1 5 0 1347.450 24.65 19.41 21.74 12.17 20.1 957.32 900000 -167163 -68359 -143733 -209470 -58629 -183147 900000 -27158 -136709 41638 -30625 -8042 -40424 -53305 85275 84222 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-195 1412 384 -1 -1364 140 -781 506 -1327 -749 -2179 -2075 -483 -1807 107 134 1369 -477 665 -217 300 -549 693 -1249 373 261 324 -349 -1700 70 -1399 21 -975 -1470 -2276 1021 -719 1754 -383 1152 -39 -258 -1957 231 629 2096 676 57 -184 -61 2225 -976 2948 -750 1185 954 -263 -1343 319 -555 90 -566 -208 760 -60 1467 -1266 1076 -892 1400 -2821 SS 20240209T133756.5Z 8805.568016 79 1 26.88 2 74.84 123.92 77.89 130.95 0.00 1 0.00 1 0 17 1.678e-01 5.568e-03 6.227e-02 2.089e-03 5.544464e-01 1.061384e-03 6.312895e-03 -6.000000e+00 9.341417e-02 224.77 -2.00 3.47 -2.00 320.34 0.00e+00 1.799673e-03 3.782410e-04 8.521084e-04 -6.000000e+00 4.057311e-03 276.36 -2.00 20.00 -2.00 319.79 0.00e+00 3.752 0.001 302.00 328.00 3 2.7619e+00 3.1476e-03 4.6594e-02 -6.0000e+00 2.3109e-01 5.4773e-02 3.9418e-03 2.8536e-02 -6.0000e+00 2.5197e-01 -4.4581e-02 3.7945e-03 1.5050e-02 -6.0000e+00 1.4990e-01 5.9045e-03 1.9372e-03 4.9996e-03 -6.0000e+00 6.3739e-02 4.2776e-04 -4.2033e-04 5.7096e-05 5.5106e-05 -6.0000e+00 4.3379e-03 2.0208e-02 -1.3949e-06 12 1 1 12 1 1 97.46 20.92 0.26 0.02021 0.01705 73 27 1 5 0 363.170 24.65 19.30 20.92 12.51 20.1 959.44 -60632 -63327 -59655 -35700 -62283 -73370 -74343 -27978 -61431 -22910 -41223 -22366 -35176 -20919 -20419 -15855 -8274 -12091 -9058 -5821 -9844 -9300 -10730 -11757 -4939 -7033 -4343 -6398 -9036 -7217 -119 2096 -432 -3046 -4978 -6154 -9883 -6120 -3362 -484 -1684 -2480 14 -591 -1292 1877 -375 1821 -661 -1080 979 956 2028 1845 2075 1259 1048 187 566 -142 1783 1480 2150 2962 1677 295 432 584 345 1243 1136 1216 301 1077 -565 -232 -1431 -1376 -1852 -903 -764 -952 -1753 -1594 -834 -365 360 199 804 682 537 208 -494 -54 277 -184 518 712 356 -16 -506 -728 -1490 -338 -806 -1206 -1077 -563 -330 226 536 294 -56 89 -198 213 -64 256 290 147 51 313 530 263 709 -92 197 553 366 106 -169 -232 -291 -195 -235 -82 87 363 141 -30 9 -201 -407 -517 -657 -652 -304 -623 -867 -954 -256 -901 -252 -563 -273 -602 -392 -474 -423 -229 -382 -301 -198 -361 -337 -409 -496 -210 -325 -202 -293 -407 -332 -6 120 -29 -232 -369 -446 -815 -571 -375 -64 -254 -404 2 -102 -226 325 -67 326 -125 -215 210 229 524 518 617 391 337 61 177 -44 555 505 821 1260 759 130 184 252 161 667 616 690 171 636 -311 -113 -653 -620 -918 -522 -466 -662 -1343 -1283 -713 -332 342 195 785 643 469 169 -383 -42 237 -181 580 833 454 -20 -606 -861 -1617 -366 -952 -1383 -1296 -719 -455 343 889 473 -89 148 -307 312 -94 392 474 252 87 515 844 404 1034 -130 266 768 569 184 -295 -428 -559 -393 -508 -174 187 793 308 -69 18 -407 -801 SS 20240209T134753.3Z 8805.574922 82 1 50.36 2 73.25 125.80 76.47 132.74 0.00 1 0.00 1 0 17 1.165e-01 4.919e-03 2.957e-02 1.158e-03 5.076636e-01 5.828361e-04 5.744703e-03 -6.000000e+00 6.486360e-02 224.77 -2.00 3.47 -2.00 320.23 0.00e+00 1.784206e-03 1.989034e-04 5.357892e-04 -6.000000e+00 2.817178e-03 276.36 -2.00 20.00 -2.00 319.68 0.00e+00 3.417 0.001 302.00 328.00 3 2.3809e+00 1.7117e-03 4.2395e-02 -6.0000e+00 1.6046e-01 3.4275e-02 2.1151e-03 2.5824e-02 -6.0000e+00 1.7495e-01 -2.4677e-02 1.9804e-03 1.3488e-02 -6.0000e+00 1.0408e-01 -8.2860e-04 1.0193e-03 4.5759e-03 -6.0000e+00 4.4262e-02 9.0915e-04 -3.3161e-04 3.2452e-05 4.8267e-05 -6.0000e+00 3.0117e-03 1.9799e-02 1.3832e-05 11 1 0 11 8 0 99.76 21.08 0.22 0.01980 0.01731 287 55 1 5 0 175.430 24.65 19.30 21.08 12.68 20.2 961.29 -32457 -52897 -26511 -41059 -39640 -52084 -39896 -37010 -31661 -24561 -29153 -24563 -28104 -12796 -18047 -10889 -10457 -2925 -5210 -903 -3227 -6235 -4654 -2257 -3633 -5374 -4868 -6076 -5125 -4850 -135 -3308 -206 -933 -3052 -4464 -4086 -4252 -706 -538 -1524 -867 -666 -224 604 764 -549 297 -374 -295 774 1627 1202 1874 597 890 623 119 102 -47 1047 1379 2251 2449 1199 276 419 -721 885 1170 1121 779 354 553 -243 -131 -764 -1739 -1206 -821 -917 -924 -2129 -1571 -1061 -263 118 348 905 726 527 271 175 -121 229 166 545 755 257 -325 -215 -803 -966 -319 -909 -1120 -862 -610 -282 248 338 335 122 32 -262 173 -4 319 164 65 -108 342 372 252 542 81 119 508 280 114 -43 -242 -305 -123 -136 -89 2 387 56 31 -70 -236 -330 -293 -690 -289 -510 -436 -620 -451 -506 -468 -372 -474 -408 -587 -286 -524 -351 -372 -105 -207 -36 -137 -271 -206 -106 -186 -297 -276 -336 -267 -260 -8 -232 -16 -80 -254 -363 -363 -443 -87 -80 -258 -156 -125 -43 116 149 -110 60 -77 -63 180 416 334 560 191 293 212 41 34 -15 348 497 902 1094 566 126 183 -320 416 634 674 492 224 332 -135 -65 -351 -791 -592 -470 -607 -693 -1604 -1237 -889 -234 110 334 867 671 452 237 144 -100 206 155 579 910 337 -426 -263 -897 -988 -329 -1023 -1333 -1074 -806 -400 385 525 543 196 54 -408 254 -6 488 268 103 -186 569 600 391 799 116 162 707 434 196 -73 -435 -568 -241 -284 -195 4 881 128 68 -146 -469 -636 SS 20240209T135442.4Z 8805.579657 86 1 50.34 2 72.19 127.12 75.52 133.98 0.00 1 0.00 1 0 17 8.152e-02 5.135e-03 3.638e-02 1.548e-03 4.833205e-01 7.793502e-04 5.515780e-03 -6.000000e+00 4.539738e-02 224.77 -2.00 3.47 -2.00 320.07 0.00e+00 1.273781e-03 2.521127e-04 5.009223e-04 -6.000000e+00 1.971639e-03 276.36 -2.00 20.00 -2.00 319.51 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