File name: Pandora2s1_GreenbeltMD_20240213_L2Fit_fwvt1c9d20220412p1-8.txt File generation date: 20240214T052904.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20240213_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.0848 492.2060 492.3273 492.4485 492.5697 492.6909 492.8121 492.9332 493.0543 493.1755 493.2966 493.4177 493.5387 493.6598 493.7808 493.9018 494.0228 494.1438 494.2648 494.3857 494.5067 494.6276 494.7485 494.8694 494.9902 495.1111 495.2319 495.3527 495.4735 495.5943 495.7151 495.8358 495.9566 496.0773 496.1980 496.3187 496.4393 496.5600 496.6806 496.8012 496.9218 497.0424 497.1630 497.2835 497.4040 497.5245 497.6450 497.7655 497.8860 498.0064 498.1269 498.2473 498.3677 498.4880 498.6084 498.7287 498.8491 498.9694 499.0897 499.2099 499.3302 499.4504 499.5707 499.6909 499.8111 499.9312 500.0514 500.1715 500.2917 500.4118 500.5318 500.6519 500.7720 500.8920 501.0120 501.1320 501.2520 501.3720 501.4919 501.6119 501.7318 501.8517 501.9716 502.0914 502.2113 502.3311 502.4509 502.5707 502.6905 502.8103 502.9300 503.0498 503.1695 503.2892 503.4089 503.5285 503.6482 503.7678 503.8874 504.0070 504.1266 504.2461 504.3657 504.4852 504.6047 504.7242 504.8437 504.9631 505.0826 505.2020 505.3214 505.4408 505.5601 505.6795 505.7988 505.9182 506.0375 506.1567 506.2760 506.3953 506.5145 506.6337 506.7529 506.8721 506.9913 507.1104 507.2295 507.3486 507.4677 507.5868 507.7059 507.8249 507.9439 508.0630 508.1819 508.3009 508.4199 508.5388 508.6577 508.7766 508.8955 509.0144 509.1333 509.2521 509.3709 509.4897 509.6085 509.7273 509.8460 509.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240213T154945.3Z 8809.659552 165 1 11.53 2 56.58 152.97 72.39 97.13 0.00 1 0.00 1 0 15 2.306e-03 2.293e-03 2.889e-04 2.879e-04 1.067192e+03 1.661875e+01 8.129639e+01 -6.000000e+00 1.274240e+02 276.34 -2.00 20.00 -2.00 505.25 0.00e+00 4.728764e-04 7.861276e-06 2.768505e-05 -6.000000e+00 6.429606e-05 276.34 -2.00 20.00 -2.00 500.33 0.00e+00 9.928364e-02 5.808876e-03 9.229432e-03 -6.000000e+00 4.643642e-02 224.91 -2.00 3.47 -2.00 501.94 0.00e+00 1.810 0.000 489.00 513.00 1 3.8577e+00 4.4535e-04 2.7562e-03 -6.0000e+00 3.5520e-03 1.1820e-02 1.1543e-04 2.4910e-04 -6.0000e+00 9.2569e-04 3.1632e-02 1.4882e-04 3.0628e-05 1.4599e-05 -6.0000e+00 2.5103e-04 5.1935e-02 -4.3318e-05 10 0 0 10 0 0 99.95 20.67 1.30 0.05194 0.05297 532 102 1 4 0 21.670 24.35 19.07 20.67 8.59 19.9 932.25 -460 -334 -92 126 297 448 430 412 366 208 3 -93 -175 -247 -261 -191 -79 54 54 95 153 193 180 226 323 192 10 -5 -172 -346 -307 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410 375 312 197 156 118 84 149 192 129 241 226 130 159 93 -33 -92 -95 -172 -98 16 37 56 234 153 242 238 189 85 47 -110 -320 -415 -466 900000 SQ 20240213T154956.9Z 8809.659686 165 2 11.53 2 56.57 153.02 72.35 97.16 0.00 1 0.00 1 0 15 2.580e-03 2.574e-03 1.805e-03 1.793e-03 1.068904e+03 1.030279e+02 7.780168e+01 -6.000000e+00 1.425963e+02 276.34 -2.00 20.00 -2.00 505.15 0.00e+00 5.308724e-04 4.875734e-05 3.046387e-05 -6.000000e+00 7.195036e-05 276.34 -2.00 20.00 -2.00 500.15 0.00e+00 8.272068e-02 3.631874e-02 9.638621e-03 -6.000000e+00 5.195910e-02 224.91 -2.00 3.47 -2.00 501.76 0.00e+00 1.809 0.000 489.00 513.00 1 6.0821e+00 2.7752e-03 2.7799e-03 -6.0000e+00 3.9745e-03 1.7739e-02 7.2677e-04 2.4711e-04 -6.0000e+00 1.0356e-03 3.4221e-03 -7.4725e-05 1.8978e-04 1.6009e-05 -6.0000e+00 2.8092e-04 5.2877e-02 -3.9261e-05 10 0 0 10 0 0 97.83 20.67 1.29 0.05288 0.05236 532 102 1 4 0 21.670 24.35 19.07 20.67 8.59 19.9 932.25 -365 -536 -160 109 294 579 261 504 454 186 -42 -167 -107 -364 -240 -315 -163 91 79 6 163 104 113 195 572 145 220 6 -74 -312 -47 -259 -106 129 181 -92 16 -168 -308 87 -236 118 147 14 170 138 59 12 25 -484 -451 -277 -612 -484 -74 -1 50 38 258 300 194 427 93 259 55 -121 -102 -107 -219 -254 -202 65 -100 75 17 38 -168 -199 -150 -523 -412 -379 -249 -375 -253 -246 -135 3 63 41 159 228 292 321 104 12 -247 -168 -276 -421 -293 -361 121 -337 -52 13 -271 -20 -336 226 -223 375 171 417 251 430 299 452 262 120 11 -95 351 114 8 404 466 -201 172 92 -95 -157 -203 -207 -36 25 212 14 311 174 230 255 200 -41 110 -30 -340 -488 -482 900000 -367 -552 -169 118 327 654 299 578 517 209 -47 -183 -116 -391 -239 -317 -167 95 84 7 174 111 121 211 614 156 234 7 -75 -310 -46 -260 -109 136 194 -98 17 -176 -321 90 -246 123 156 15 181 148 62 12 26 -480 -436 -263 -585 -471 -73 -1 52 39 267 310 201 443 97 267 56 -122 -101 -104 -212 -244 -194 63 -97 73 16 37 -161 -188 -142 -495 -392 -364 -241 -367 -249 -244 -133 3 62 41 160 233 300 329 105 12 -240 -160 -257 -391 -274 -347 119 -342 -53 13 -271 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