File name: Pandora2s1_GreenbeltMD_20250422_L2Fit_fwvt1c13d20240823p1-8.txt File generation date: 20250423T051908.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v13d20240823.txt Level 1 file used: Pandora2s1_GreenbeltMD_20250422_L1_smca1c13d20240823p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP starting 20240823 after field enclosure replaced First and last pixel inside fitting window: 1616 1765 Nominal wavelengths inside fitting window [nm]: 492.0728 492.1940 492.3151 492.4363 492.5575 492.6786 492.7997 492.9208 493.0419 493.1629 493.2840 493.4050 493.5260 493.6470 493.7680 493.8890 494.0099 494.1308 494.2518 494.3726 494.4935 494.6144 494.7352 494.8561 494.9769 495.0977 495.2184 495.3392 495.4599 495.5807 495.7014 495.8221 495.9427 496.0634 496.1840 496.3047 496.4253 496.5459 496.6664 496.7870 496.9075 497.0280 497.1485 497.2690 497.3895 497.5100 497.6304 497.7508 497.8712 497.9916 498.1120 498.2323 498.3527 498.4730 498.5933 498.7136 498.8338 498.9541 499.0743 499.1945 499.3147 499.4349 499.5551 499.6752 499.7953 499.9155 500.0356 500.1556 500.2757 500.3957 500.5158 500.6358 500.7558 500.8758 500.9957 501.1157 501.2356 501.3555 501.4754 501.5953 501.7151 501.8349 501.9548 502.0746 502.1944 502.3141 502.4339 502.5536 502.6733 502.7930 502.9127 503.0324 503.1521 503.2717 503.3913 503.5109 503.6305 503.7500 503.8696 503.9891 504.1086 504.2281 504.3476 504.4671 504.5865 504.7059 504.8254 504.9447 505.0641 505.1835 505.3028 505.4221 505.5414 505.6607 505.7800 505.8993 506.0185 506.1377 506.2569 506.3761 506.4953 506.6144 506.7336 506.8527 506.9718 507.0909 507.2099 507.3290 507.4480 507.5670 507.6860 507.8050 507.9239 508.0429 508.1618 508.2807 508.3996 508.5185 508.6373 508.7562 508.8750 508.9938 509.1126 509.2314 509.3501 509.4688 509.5876 509.7063 509.8249 509.9436 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250422T102832.7Z 9243.436490 110 1 50.20 2 89.34 74.57 65.19 146.24 0.00 1 0.00 1 0 22 8.578e-03 8.363e-03 8.273e-04 8.204e-04 2.657145e+04 6.432287e+01 1.688778e+03 -6.000000e+00 4.847445e+02 281.91 -2.00 20.00 -2.00 505.53 0.00e+00 4.219956e-03 2.311704e-05 2.513888e-04 -6.000000e+00 2.420139e-04 281.91 -2.00 20.00 -2.00 501.22 0.00e+00 1.358763e+00 1.594777e-02 1.759708e-01 -6.000000e+00 1.718747e-01 229.31 -2.00 3.47 -2.00 502.70 0.00e+00 19.432 0.129 489.00 513.00 1 4.2535e+00 1.2179e-03 3.6861e-02 -6.0000e+00 1.3189e-02 -6.8706e-02 2.9882e-04 4.7364e-03 -6.0000e+00 3.3954e-03 1.4567e-03 1.1450e-03 7.3088e-05 1.7710e-04 -6.0000e+00 9.3198e-04 -1.8683e-02 2.0353e-04 12 8 8 10 0 0 60.74 23.14 4.65 -0.01868 -0.01074 40 8 1 4 0 1254.760 25.68 20.01 23.14 23.35 26.0 1050.45 -1823 -1500 -533 165 1069 1432 1774 1482 1235 944 564 -73 -752 -871 -1158 -665 -460 132 179 545 622 668 722 756 920 725 330 -307 -642 -1334 -1298 -910 -608 -16 551 247 65 20 -159 -223 -106 253 375 727 791 924 705 219 -400 -843 -1394 -1625 -1513 -1142 -427 172 434 835 774 1016 1072 1022 1147 895 729 260 -101 -414 -607 -1057 -973 -676 -627 -614 -605 -798 -1226 -1110 -1516 -1203 -1064 -630 -681 -758 -793 -804 -683 -210 87 412 725 827 966 875 1070 564 118 -955 -1726 -1893 -1752 -1220 -1019 -434 214 -1 -52 -259 -268 -566 -336 2 613 1237 1623 1838 1504 1083 508 65 -87 260 540 581 841 873 901 719 187 69 -212 -340 -380 -668 -676 -417 89 414 588 496 430 295 545 755 487 6 -567 -966 -1143 -1131 -1497 -1255 -457 146 964 1318 1656 1398 1166 885 524 -67 -692 -796 -1062 -613 -431 126 165 507 581 627 682 719 881 698 318 -293 -602 -1232 -1190 -841 -575 -16 545 247 65 20 -157 -221 -106 255 382 751 825 967 737 227 -411 -850 -1382 -1590 -1479 -1132 -432 169 435 842 784 1029 1091 1049 1181 923 746 265 -102 -413 -601 -1041 -957 -667 -625 -619 -611 -801 -1216 -1082 -1468 -1155 -1023 -607 -663 -749 -793 -809 -684 -208 85 402 711 818 951 844 991 530 107 -852 -1526 -1670 -1569 -1129 -943 -422 216 -1 -54 -269 -280 -569 -341 3 624 1255 1652 1895 1589 1167 551 70 -92 269 552 597 870 911 947 759 198 73 -223 -354 -396 -702 -722 -454 98 465 640 551 484 337 623 860 554 7 -639 -1082 -1280 -1278 SQ 20250422T103142.1Z 9243.438682 114 1 29.41 2 88.74 75.07 64.85 146.95 0.00 1 0.00 1 0 22 6.078e-03 5.968e-03 5.825e-04 5.797e-04 2.440425e+04 4.480574e+01 1.572472e+03 -6.000000e+00 3.435141e+02 281.91 -2.00 20.00 -2.00 505.48 0.00e+00 3.532919e-03 1.630118e-05 2.159429e-04 -6.000000e+00 1.715081e-04 281.91 -2.00 20.00 -2.00 501.05 0.00e+00 1.286846e+00 1.136041e-02 1.576330e-01 -6.000000e+00 1.218430e-01 229.31 -2.00 3.47 -2.00 502.56 0.00e+00 18.047 0.104 489.00 513.00 1 3.5189e+00 8.6879e-04 3.2880e-02 -6.0000e+00 9.3493e-03 -5.9756e-02 2.1461e-04 4.2536e-03 -6.0000e+00 2.4079e-03 3.7592e-03 1.1001e-03 5.2322e-05 1.7125e-04 -6.0000e+00 6.6056e-04 -1.7241e-02 1.6836e-04 12 9 9 12 1 1 18.22 23.14 3.11 -0.01724 -0.00961 47 16 1 4 0 612.590 25.79 20.00 23.14 23.39 25.9 1050.79 -1141 -939 -235 286 805 1147 1242 1148 1060 783 323 88 -487 -643 -523 -270 -215 -44 795 358 537 429 444 445 565 486 162 -124 -421 -906 -560 -464 -357 -191 123 -25 -18 -54 -247 -226 -237 15 230 318 424 474 382 212 -369 -771 -1133 -1205 -985 -870 -615 -147 212 368 609 716 817 789 692 518 470 214 -92 -175 -565 -585 -510 -281 -423 -488 -470 -638 -928 -900 -992 -792 -647 -542 -447 -399 -456 -575 -542 -217 116 330 462 435 612 619 779 492 55 -749 -1186 -1375 -1146 -1049 -850 -543 -214 -188 -4 -204 -321 -274 -277 -7 443 1006 1360 1536 1129 661 286 -19 40 210 384 587 605 524 659 443 213 -107 80 -154 -110 -375 -361 -174 172 287 479 425 374 246 315 461 207 45 -429 -702 -775 -679 -999 -838 -206 258 745 1084 1194 1113 1028 754 309 84 -458 -601 -488 -254 -206 -41 756 346 522 419 436 440 563 486 162 -122 -408 -863 -526 -441 -348 -192 121 -25 -18 -53 -241 -220 -233 15 231 324 438 490 394 216 -372 -763 -1100 -1152 -939 -842 -611 -150 219 370 613 722 827 804 709 531 478 215 -92 -180 -575 -590 -513 -284 -416 -485 -469 -632 -907 -901 -983 -780 -637 -537 -447 -389 -450 -572 -537 -213 113 320 451 428 601 596 751 456 49 -685 -1071 -1239 -1045 -952 -813 -526 -215 -193 -4 -210 -331 -275 -281 -7 452 1023 1387 1586 1194 712 299 -20 42 216 392 601 624 545 689 466 224 -112 83 -159 -113 -388 -380 -180 181 308 522 472 406 271 348 509 228 49 -465 -755 -832 -734 SQ 20250422T103444.9Z 9243.440797 118 1 49.98 2 88.17 75.54 64.53 147.65 0.00 1 0.00 1 0 22 5.115e-03 5.020e-03 8.351e-04 8.296e-04 2.207438e+04 6.378512e+01 1.438174e+03 -6.000000e+00 2.889799e+02 281.91 -2.00 20.00 -2.00 505.50 0.00e+00 3.012837e-03 2.332411e-05 1.839438e-04 -6.000000e+00 1.443337e-04 281.91 -2.00 20.00 -2.00 501.08 0.00e+00 1.239163e+00 1.621053e-02 1.441657e-01 -6.000000e+00 1.026381e-01 229.31 -2.00 3.47 -2.00 502.58 0.00e+00 16.527 0.079 489.00 513.00 1 4.6304e+00 1.2408e-03 2.9128e-02 -6.0000e+00 7.8739e-03 -5.5069e-02 3.0447e-04 3.8948e-03 -6.0000e+00 2.0314e-03 1.5555e-03 2.6171e-03 7.6621e-05 1.6210e-04 -6.0000e+00 5.5615e-04 5.6178e-03 -6.5539e-05 12 8 8 10 0 0 99.63 23.15 2.74 0.00562 0.02377 62 12 1 4 0 805.980 25.79 19.99 23.15 23.44 25.9 1050.99 -858 -745 -222 279 748 1235 1111 897 959 626 380 103 -440 -435 -396 -65 -77 -42 376 108 350 301 457 412 543 224 -11 -283 -267 -678 -511 -342 -309 -170 162 -17 -61 126 -235 -109 -246 25 252 226 346 291 255 154 -285 -700 -1050 -836 -762 -847 -323 -262 86 263 411 446 738 711 563 454 439 263 1 -281 -530 -462 -528 -244 -445 -491 -405 -429 -689 -619 -678 -758 -586 -529 -338 -579 -402 -614 -350 -301 165 278 367 197 549 509 556 453 -7 -825 -983 -1094 -1011 -753 -759 -669 -242 -218 -50 -64 -176 -193 -340 -78 355 851 1232 1348 985 471 303 52 213 240 488 393 399 310 457 273 90 4 48 -97 28 -253 -335 -173 256 375 524 341 233 148 212 388 205 -25 -246 -559 -540 -609 -718 -636 -195 252 693 1166 1070 872 930 603 363 98 -413 -405 -368 -61 -73 -42 353 103 335 290 441 401 532 220 -11 -275 -253 -632 -471 -317 -295 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