File name: Pandora2s1_GreenbeltMD_20250808_L2Fit_fout2c13d20240823p1-8.txt File generation date: 20250809T052527.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora2_OF_v2d20210816.txt Instrument calibration file used: Pandora2s1_CF_v13d20240823.txt Level 1 file used: Pandora2s1_GreenbeltMD_20250808_L1_smca1c13d20240823p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP starting 20240823 after field enclosure replaced First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1348 305.2759 305.4170 305.5580 305.6991 305.8401 305.9811 306.1221 306.2631 306.4041 306.5451 306.6860 306.8270 306.9679 307.1088 307.2497 307.3907 307.5315 307.6724 307.8133 307.9542 308.0950 308.2358 308.3767 308.5175 308.6583 308.7991 308.9399 309.0806 309.2214 309.3622 309.5029 309.6436 309.7843 309.9250 310.0657 310.2064 310.3471 310.4877 310.6284 310.7690 310.9097 311.0503 311.1909 311.3315 311.4720 311.6126 311.7532 311.8937 312.0343 312.1748 312.3153 312.4558 312.5963 312.7368 312.8772 313.0177 313.1582 313.2986 313.4390 313.5794 313.7198 313.8602 314.0006 314.1410 314.2813 314.4217 314.5620 314.7023 314.8426 314.9829 315.1232 315.2635 315.4038 315.5440 315.6843 315.8245 315.9647 316.1049 316.2451 316.3853 316.5255 316.6657 316.8058 316.9460 317.0861 317.2262 317.3663 317.5064 317.6465 317.7866 317.9267 318.0667 318.2067 318.3468 318.4868 318.6268 318.7668 318.9068 319.0467 319.1867 319.3267 319.4666 319.6065 319.7464 319.8863 320.0262 320.1661 320.3060 320.4458 320.5857 320.7255 320.8654 321.0052 321.1450 321.2848 321.4245 321.5643 321.7041 321.8438 321.9835 322.1233 322.2630 322.4027 322.5423 322.6820 322.8217 322.9613 323.1010 323.2406 323.3802 323.5198 323.6594 323.7990 323.9386 324.0781 324.2177 324.3572 324.4968 324.6363 324.7758 324.9153 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250808T110900.1Z 9351.464585 192 1 50.43 2 80.78 76.84 111.46 257.33 0.00 1 0.00 1 0 25 7.139e-01 1.703e-02 3.964e-01 1.127e-02 7.573528e-01 6.655090e-03 8.466083e-03 -6.000000e+00 4.216806e-01 231.87 -2.00 3.47 -2.00 321.83 0.00e+00 6.345829e-03 3.906528e-03 6.123633e-04 -6.000000e+00 2.134773e-02 290.76 -2.00 20.00 -2.00 321.27 0.00e+00 5.924 0.004 302.00 328.00 3 2.5504e+00 2.6649e-02 7.2020e-02 -6.0000e+00 1.0611e+00 3.0395e-01 3.9901e-02 4.4212e-02 -6.0000e+00 1.1516e+00 -3.0343e-01 4.0033e-02 2.3097e-02 -6.0000e+00 6.8107e-01 1.0291e-01 1.8076e-02 1.1598e-02 -6.0000e+00 2.9090e-01 5.1339e-05 -9.4306e-04 3.2568e-04 1.2374e-04 -6.0000e+00 1.9437e-02 1.0379e-02 0.0000e+00 12 9 8 11 8 0 -13.11 23.17 0.52 0.01038 0.00329 34 7 1 5 0 1482.980 25.79 20.00 23.17 23.86 26.7 998.63 -208110 -251396 900000 -187800 -248767 900000 -181396 900000 -236388 900000 -282479 900000 -59572 900000 900000 900000 -81923 900000 38224 -4780 41374 900000 900000 218529 900000 227948 226869 -105318 900000 139951 133402 -59490 39593 38481 88807 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-977 -105 -691 1280 -790 586 -1070 839 2501 -2951 2381 -64 1536 -2074 660 -1093 277 -2290 1898 -1509 453 -2484 -1516 -1093 765 -1978 -2180 1670 -555 -1218 -686 1655 712 751 -397 -1139 -289 520 45 2660 684 202 3259 -2070 1711 247 3095 -1201 1205 506 238 -701 863 -1646 299 384 -838 -391 -769 -462 SS 20250808T111913.7Z 9351.471687 197 1 50.08 2 78.84 78.38 113.30 258.75 0.00 1 0.00 1 0 25 3.766e-01 7.751e-03 2.450e-01 4.567e-03 6.507785e-01 2.505792e-03 7.306082e-03 -6.000000e+00 2.179220e-01 231.87 -2.00 3.47 -2.00 321.26 0.00e+00 2.425779e-03 1.266923e-03 4.549729e-04 -6.000000e+00 1.040557e-02 290.76 -2.00 20.00 -2.00 320.64 0.00e+00 4.984 0.002 302.00 328.00 3 2.2618e+00 8.9708e-03 6.0441e-02 -6.0000e+00 5.4557e-01 9.1244e-02 1.2610e-02 3.5580e-02 -6.0000e+00 5.9015e-01 -7.0661e-02 1.2512e-02 1.8135e-02 -6.0000e+00 3.5026e-01 1.3757e-02 5.9218e-03 6.9725e-03 -6.0000e+00 1.5051e-01 1.9563e-04 -7.5396e-04 1.2753e-04 6.9606e-05 -6.0000e+00 1.0144e-02 9.9226e-03 0.0000e+00 11 9 0 11 8 0 4.63 23.18 0.48 0.00992 0.00426 78 15 1 5 0 642.030 25.79 20.00 23.18 24.24 26.8 1001.64 -159847 -106941 -191682 900000 -157785 900000 -171628 -14472 38085 900000 -143430 -59624 58519 -20820 -55458 -33549 -35540 -54826 -21205 -53568 -2572 -65883 -3340 -29416 49136 -19453 57450 -41577 32919 -34985 10630 -10569 -8089 -5268 -15221 -13862 -22609 6500 -12254 17861 -9612 -143 -1398 4749 -9374 5517 846 4977 5086 -2366 -1010 1366 3932 1693 5995 -805 3724 -4518 4592 267 6262 2305 6252 907 2247 62 -218 3208 2813 914 -43 1633 -52 4214 -2307 2787 -2811 2241 -1423 509 -1276 -333 -1928 -1328 158 -383 -301 -1327 1330 107 854 -587 2472 -190 761 -251 237 333 501 -843 -362 194 553 -1365 -2320 -1182 -1063 52 -185 5 -213 -23 -102 294 740 237 527 -297 -197 -347 -141 230 542 627 125 511 1905 124 513 -310 8 1 390 -395 21 68 -158 -134 -254 -131 -253 293 -1164 -519 -2249 900000 -1149 900000 -1736 -64 170 900000 -1625 -362 260 -143 -673 -380 -460 -954 -283 -1040 -30 -1493 -45 -559 457 -378 511 -959 410 -1012 237 -343 -292 -183 -556 -537 -1117 295 -829 1041 -804 -12 -119 387 -901 469 78 459 496 -275 -131 192 590 280 995 -149 668 -859 777 48 1143 497 1480 247 595 16 -59 897 915 343 -17 653 -20 1448 -757 794 -833 685 -535 222 -653 -188 -1178 -861 109 -279 -227 -1023 973 74 545 -360 1474 -128 587 -226 246 385 589 -954 -370 177 491 -1332 -2433 -1286 -1235 64 -257 8 -357 -40 -167 455 1080 345 798 -481 -336 -594 -233 364 827 913 177 690 2576 191 893 -599 15 2 810 -888 49 166 -393 -336 -614 -297 -544 599 SS 20250808T112503.0Z 9351.475729 200 1 50.53 2 77.74 79.25 114.36 259.56 0.00 1 0.00 1 0 25 2.544e-01 5.604e-03 1.622e-01 2.867e-03 6.034590e-01 1.547078e-03 6.764972e-03 -6.000000e+00 1.460968e-01 231.87 -2.00 3.47 -2.00 321.01 0.00e+00 1.889579e-03 7.079644e-04 4.345693e-04 -6.000000e+00 6.567570e-03 290.76 -2.00 20.00 -2.00 320.31 0.00e+00 4.568 0.002 302.00 328.00 3 2.0186e+00 5.2117e-03 5.5475e-02 -6.0000e+00 3.6578e-01 8.0400e-02 7.0382e-03 3.2589e-02 -6.0000e+00 3.9532e-01 -5.8041e-02 6.7503e-03 1.6518e-02 -6.0000e+00 2.3573e-01 8.5892e-03 3.2749e-03 5.9695e-03 -6.0000e+00 1.0120e-01 3.8803e-04 -7.0798e-04 8.0621e-05 5.6053e-05 -6.0000e+00 6.6427e-03 9.7793e-03 0.0000e+00 10 0 0 10 0 0 -13.75 23.20 0.31 0.00978 0.00446 123 24 1 5 0 410.740 25.79 20.01 23.20 24.45 26.8 1003.08 -111319 -99796 -45854 -79017 49337 -95067 -47353 -114678 -40367 -74242 -24523 -106742 -26324 -49974 -4941 -33088 -1143 -24433 -21597 -14078 -34828 -22514 -39018 6961 -22226 12185 -19016 2533 -17498 96 -7022 10909 1448 -3014 -7600 763 -6538 -1716 -5540 -2819 2261 -310 398 -1275 6679 -691 3137 -1663 -29 -1062 1159 2867 836 1756 199 329 -1315 2359 -1260 1682 1819 5009 2065 2564 -36 1273 701 1510 1065 1230 1046 -768 647 132 587 -938 -12 -1406 170 -979 -727 -2224 -976 -1214 -520 -609 -204 551 387 436 689 975 413 1224 465 809 352 371 -557 -427 -159 321 -337 -768 -1132 -1138 -782 -428 153 -501 139 -79 302 298 612 499 611 -62 -188 -648 -118 258 -11 389 29 554 1021 684 65 157 -124 147 -74 -160 -159 -59 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