File name: Pandora32s1_GreenbeltMD_20200818_L2Fit_fout2c2d20190306p1-8.txt File generation date: 20250509T143214.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora32_OF_v3d20181024.txt Instrument calibration file used: Pandora32s1_CF_v2d20190306.txt Level 1 file used: Pandora32s1_GreenbeltMD_20200818_L1_smca1c2d20190306p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20200818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB ICF based on field calibration session 1 First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0066 305.1477 305.2887 305.4297 305.5707 305.7117 305.8527 305.9936 306.1346 306.2755 306.4165 306.5574 306.6983 306.8392 306.9801 307.1209 307.2618 307.4026 307.5435 307.6843 307.8251 307.9659 308.1067 308.2475 308.3882 308.5290 308.6697 308.8105 308.9512 309.0919 309.2326 309.3733 309.5140 309.6546 309.7953 309.9359 310.0765 310.2172 310.3578 310.4984 310.6389 310.7795 310.9201 311.0606 311.2011 311.3417 311.4822 311.6227 311.7632 311.9036 312.0441 312.1846 312.3250 312.4654 312.6059 312.7463 312.8867 313.0270 313.1674 313.3078 313.4481 313.5885 313.7288 313.8691 314.0094 314.1497 314.2900 314.4302 314.5705 314.7107 314.8510 314.9912 315.1314 315.2716 315.4118 315.5519 315.6921 315.8322 315.9724 316.1125 316.2526 316.3927 316.5328 316.6729 316.8130 316.9530 317.0931 317.2331 317.3731 317.5131 317.6531 317.7931 317.9331 318.0730 318.2130 318.3529 318.4928 318.6327 318.7726 318.9125 319.0524 319.1923 319.3321 319.4720 319.6118 319.7516 319.8914 320.0312 320.1710 320.3108 320.4505 320.5903 320.7300 320.8697 321.0094 321.1491 321.2888 321.4285 321.5682 321.7078 321.8475 321.9871 322.1267 322.2663 322.4059 322.5455 322.6851 322.8246 322.9642 323.1037 323.2432 323.3827 323.5222 323.6617 323.8012 323.9406 324.0801 324.2195 324.3589 324.4984 324.6378 324.7771 324.9165 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200818T105611.3Z 7535.455686 75 1 48.52 2 84.80 77.65 76.17 76.81 0.00 1 0.00 1 0 17 2.706e-01 4.764e-02 1.231e-01 2.288e-02 8.635514e-01 1.252134e-02 9.446614e-03 -6.000000e+00 1.557002e-01 231.35 -2.00 3.47 -2.00 320.92 0.00e+00 -1.106619e-02 3.307496e-03 7.917305e-04 -6.000000e+00 6.994470e-03 290.68 -2.00 20.00 -2.00 320.02 0.00e+00 9.514 0.015 302.00 328.00 3 3.8381e-01 3.7588e-02 1.0482e-01 -6.0000e+00 3.8936e-01 1.9248e+00 4.4135e-02 4.8108e-02 -6.0000e+00 4.2071e-01 -1.8651e+00 2.4717e-02 2.0646e-02 -6.0000e+00 2.5094e-01 6.5704e-01 1.2847e-02 1.0614e-02 -6.0000e+00 1.0804e-01 1.0228e-05 3.4701e-03 5.8538e-04 1.2683e-04 -6.0000e+00 7.1011e-03 -4.5320e-03 8.4031e-05 12 8 8 10 0 0 14.52 21.96 1.45 -0.00453 0.02154 14 3 1 5 0 3465.080 26.32 20.00 21.96 900000 110700 25866 -4886 -28127 -8347 -5078 31826 -29067 -43810 40234 29645 -23411 -25110 37690 38423 -9217 53685 50050 13696 46742 50887 8198 -26182 61824 24993 -4718 43101 -47251 -29632 -36954 4273 -12005 32657 28967 -33800 14530 12908 16974 20790 27635 107377 58746 30482 2295 107480 71868 -37076 49750 16392 21718 -176 45063 32133 6890 18110 -7814 21547 19484 6147 20148 -8458 23020 -26910 5179 10294 -32342 16054 8333 9259 879 3925 13945 -4584 -5448 -20782 15812 -14414 -47 -789 -3928 -5777 904 -5474 -9551 4357 20354 -5570 9697 -4213 7753 -9839 1381 -2154 -2243 4590 -6102 2422 5067 2267 -3307 4691 434 -10553 433 -253 -1423 7956 -4000 -2151 -1098 3107 2595 -2675 -3354 -5384 4517 -1186 -2681 89 -3346 5133 2451 5279 3243 -787 4386 -2049 6038 -4955 1067 1238 -684 1624 -3053 1084 1646 1521 2117 -1501 91 -2582 -954 900000 6735 3462 -763 -4392 -914 -536 2517 -4539 -8086 3101 2525 -3704 -4532 4051 4442 -1757 5989 5695 1944 4901 4655 1116 -4885 5655 3346 -727 3942 -8337 -4562 -6678 581 -2116 3789 3167 -6259 1686 1728 2613 3618 4932 8864 7733 5032 466 7194 6574 -9926 5660 2706 3682 -41 7138 6165 1783 4323 -2458 4903 4173 1371 3731 -2170 4776 -10266 1514 2779 -12988 4083 2510 3161 357 1594 4978 -1810 -1920 -7418 3563 -4406 -14 -278 -1683 -2900 470 -2920 -5598 2576 10671 -3502 5668 -2452 4082 -5773 703 -1187 -1406 2867 -4950 2083 4697 2193 -3172 3692 319 -8518 336 -209 -1253 6841 -4308 -2614 -1503 4443 3837 -4113 -4979 -7862 6000 -1746 -4242 142 -5415 7245 3395 6916 4203 -1028 5266 -2760 8670 -9236 2102 2640 -1585 3960 -8408 2775 4278 4001 5501 -4216 233 -6258 -2174 SU 20200818T105807.0Z 7535.457026 77 1 48.10 2 84.43 77.95 75.82 77.08 0.00 1 0.00 1 0 25 2.093e-01 3.182e-02 1.168e-01 1.781e-02 8.723600e-01 9.698180e-03 9.584243e-03 -6.000000e+00 1.203293e-01 231.35 -2.00 3.47 -2.00 321.37 0.00e+00 -9.770397e-03 3.155136e-03 3.692574e-03 -6.000000e+00 5.396158e-03 290.68 -2.00 20.00 -2.00 320.62 0.00e+00 9.037 0.013 302.00 328.00 3 5.8609e-01 3.1137e-02 1.0418e-01 -6.0000e+00 3.0090e-01 1.6831e+00 3.6867e-02 6.1537e-02 -6.0000e+00 3.2501e-01 -1.8319e+00 2.0596e-02 2.1412e-02 -6.0000e+00 1.9402e-01 6.8485e-01 1.0891e-02 1.2577e-02 -6.0000e+00 8.3014e-02 1.4386e-05 1.8122e-03 4.5548e-04 1.0784e-04 -6.0000e+00 5.4417e-03 -1.8525e-03 3.4482e-05 12 8 8 10 0 0 -16.67 21.96 1.22 -0.00185 0.01177 20 4 1 5 0 2404.320 26.32 20.00 21.96 7176 25876 -4765 -32690 -14298 -51181 19565 30134 -50087 -6036 -50793 19342 19164 -26383 -7581 36051 80039 54747 65884 29145 32606 9979 -27920 -15108 21816 6701 4576 42258 -22736 -51926 6308 -117 -6483 4815 16223 4212 -28296 21438 20702 25496 15538 32232 82578 12959 24787 37491 25911 -7308 -1075 20678 19794 4479 50735 11285 24879 8794 14993 34030 36387 -2060 -4824 -3312 1632 -4279 11356 23594 6752 4545 2460 7348 14239 6913 16258 1909 -1638 -5254 -8221 -10571 -11070 -1293 2048 -18105 691 270 -9148 1501 8343 -72 2032 -182 -3452 -4333 -1200 -14957 1453 -3415 -1703 -1726 2167 -2979 -2893 4901 -5695 -4036 -4337 -5059 103 -2071 -1929 724 807 829 235 -1587 -2436 -1751 1797 2067 -1411 1516 -2180 3122 4094 3328 4053 -345 3890 1236 4147 -1581 171 42 457 -748 -651 28 988 772 356 -196 -634 -1131 -2149 759 2370 -564 -4439 -1287 -5656 1155 1727 -6247 -545 -6335 1310 1431 -3207 -948 3193 4726 4184 4462 2733 2775 970 -3831 -1942 2084 756 501 2789 -2488 -7214 537 -12 -799 552 1521 402 -3784 1973 2301 3188 2375 4310 6597 1980 3143 3972 2970 -1155 -162 2622 2750 801 6168 2176 4407 1894 3099 5674 5498 -419 -963 -679 354 -1107 2682 4835 1595 1129 684 2233 4451 2413 5054 633 -501 -1451 -2127 -2809 -3288 -415 754 -8575 333 139 -4969 775 4202 -40 1104 -97 -1942 -2303 -600 -8962 840 -2222 -1277 -1501 2022 -2997 -2746 3838 -4424 -3020 -3485 -4361 89 -1962 -2029 854 1088 1224 361 -2462 -3670 -2527 2511 3015 -2260 2450 -3600 4648 5766 4597 5394 -466 4864 1661 6246 -2943 352 95 1000 -1782 -1672 77 2702 2139 986 -524 -1573 -2594 -5168 SU 20200818T110000.0Z 7535.458333 79 1 49.92 2 84.08 78.23 75.48 77.35 0.00 1 0.00 1 0 25 2.051e-01 2.525e-02 1.200e-01 1.319e-02 8.766173e-01 7.235207e-03 9.641468e-03 -6.000000e+00 1.178602e-01 231.35 -2.00 3.47 -2.00 321.70 0.00e+00 -4.131181e-03 2.903857e-03 3.056044e-03 -6.000000e+00 5.285601e-03 290.68 -2.00 20.00 -2.00 321.04 0.00e+00 8.609 0.011 302.00 328.00 3 6.7186e-01 2.4784e-02 9.8543e-02 -6.0000e+00 2.9473e-01 1.5182e+00 2.9693e-02 5.2542e-02 -6.0000e+00 3.1835e-01 -1.7489e+00 1.8052e-02 2.2182e-02 -6.0000e+00 1.9004e-01 6.6386e-01 9.5159e-03 7.9327e-03 -6.0000e+00 8.1310e-02 2.0552e-05 1.2045e-03 3.4151e-04 7.3191e-05 -6.0000e+00 5.3302e-03 -2.1271e-03 2.0195e-05 12 8 8 10 0 0 17.17 21.96 0.81 -0.00213 0.00692 29 6 1 5 0 1720.990 26.32 20.00 21.96 -10519 19237 87755 -12110 -32035 -56974 -37730 10970 -54545 -20058 -38758 -34656 58971 -28654 95046 10833 11493 -6434 27630 28044 -10937 878 -23231 -21611 -22774 -8673 5418 22015 35876 -49956 10102 -14581 -27237 2386 11096 -6973 1631 -3207 44858 13766 6633 47181 15604 6392 16996 47059 7442 8513 15616 6013 23044 5362 19372 17577 20182 22416 35920 13410 18094 5448 -331 15960 9477 1904 15334 15995 14266 10254 15697 6191 11776 5392 13261 12339 -518 1750 -2030 -16119 -10754 -5054 1632 -7708 1369 -2673 -4829 1329 1284 4548 527 -490 -1660 -4833 -5559 -9172 -515 -2916 -2761 -1236 -1772 -481 -4433 6538 -5587 -4450 -3399 -4319 -1050 -4069 -2297 -660 -501 2075 -910 478 -2222 -1420 1360 -850 -1006 392 611 2789 1163 2336 3234 1751 1297 2966 3550 -1107 2215 -754 443 282 -1467 -349 826 1007 505 279 -1009 -1361 -2301 -787 1147 2822 -850 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