File name: Pandora32s1_GreenbeltMD_20230731_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20230803T005346.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20230731_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20230731 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230731T111239.4Z 8612.467123 171 1 45.17 2 78.85 75.45 121.04 258.26 0.00 1 0.00 1 0 25 3.564e-01 9.008e-03 4.607e-02 1.896e-03 6.203851e-01 1.001439e-03 7.087781e-03 -6.000000e+00 2.064140e-01 232.15 -2.00 3.47 -2.00 320.67 0.00e+00 2.877346e-03 4.177219e-04 1.761324e-03 -6.000000e+00 9.258655e-03 290.58 -2.00 20.00 -2.00 319.96 0.00e+00 4.987 0.002 302.00 328.00 3 1.3911e+00 3.2159e-03 5.9538e-02 -6.0000e+00 5.1705e-01 8.1350e-02 4.1545e-03 3.3737e-02 -6.0000e+00 5.5866e-01 -1.6100e-01 3.7237e-03 1.7136e-02 -6.0000e+00 3.3326e-01 6.3254e-02 1.8423e-03 5.1215e-03 -6.0000e+00 1.4151e-01 5.0027e-04 -6.7581e-04 5.1694e-05 6.6316e-05 -6.0000e+00 9.5107e-03 2.9551e-02 3.7907e-05 12 9 1 12 1 1 97.13 26.54 0.45 0.02955 0.02447 121 31 1 5 0 368.880 30.99 25.01 26.54 24.91 3.2 998.09 -115376 -149484 -84999 -114726 -129217 -137229 -119911 -76861 -118722 -88817 -94525 -114873 -37411 -68077 -14778 -31974 -34461 -9781 -22674 23889 -43135 -21036 -22516 -28894 -17840 -25838 8095 -26790 -18406 -22397 -12877 -6834 2572 -5431 -5350 -908 -9848 -201 -3145 3509 5565 4801 -2279 3910 4634 8840 1239 8320 3438 -1558 4694 3892 5622 5544 5077 3529 2019 1143 907 2780 2081 3352 3613 3304 2095 1503 2644 1013 2696 2273 706 858 -22 1431 -637 -971 -1392 -2598 -1603 -1733 -1037 -1279 -2330 -1326 -176 -548 -437 41 695 591 622 -388 -16 -620 59 -323 -238 146 -446 -413 -808 -1036 -691 -369 -1155 -1487 -832 -710 226 389 240 421 342 635 335 363 102 207 155 -348 -62 357 703 408 394 51 227 1131 349 206 285 -124 -153 20 -33 -256 -73 19 -58 19 -98 -298 -325 -1365 -2714 -974 -1761 -2103 -2309 -1796 -853 -2283 -1380 -1626 -2655 -491 -1561 -251 -780 -981 -241 -692 486 -1617 -696 -779 -1049 -633 -1055 265 -1103 -749 -904 -550 -331 132 -330 -317 -50 -639 -14 -279 351 621 585 -315 523 625 1168 180 1161 524 -265 828 777 1216 1197 1173 866 521 298 232 684 528 916 1118 1158 793 562 949 376 1077 1054 343 439 -11 694 -314 -432 -573 -1075 -722 -923 -596 -843 -1715 -1029 -134 -448 -378 37 617 510 503 -318 -13 -489 47 -302 -257 168 -568 -533 -989 -1146 -745 -396 -1256 -1730 -1013 -920 296 569 366 683 558 999 529 547 154 327 245 -581 -103 574 1085 650 604 76 323 1633 567 357 511 -237 -307 41 -70 -585 -163 44 -132 41 -214 -615 -684 SS 20230731T111845.1Z 8612.471355 174 1 48.57 2 77.70 76.35 122.13 259.05 0.00 1 0.00 1 0 25 2.407e-01 6.386e-03 3.011e-02 1.282e-03 5.730119e-01 6.749081e-04 6.543972e-03 -6.000000e+00 1.393772e-01 232.15 -2.00 3.47 -2.00 320.36 0.00e+00 2.941446e-03 2.540757e-04 1.046385e-03 -6.000000e+00 6.251768e-03 290.58 -2.00 20.00 -2.00 319.60 0.00e+00 4.556 0.002 302.00 328.00 3 1.2048e+00 2.0931e-03 5.4368e-02 -6.0000e+00 3.4913e-01 3.1813e-02 2.6367e-03 3.0403e-02 -6.0000e+00 3.7723e-01 -7.4234e-02 2.3093e-03 1.5601e-02 -6.0000e+00 2.2503e-01 2.4215e-02 1.1641e-03 5.1430e-03 -6.0000e+00 9.5551e-02 9.4717e-04 -6.6509e-04 3.5380e-05 5.8408e-05 -6.0000e+00 6.4223e-03 2.9345e-02 1.9569e-05 10 0 0 10 0 0 40.80 26.56 0.36 0.02934 0.02435 223 52 1 5 0 217.780 30.99 25.00 26.56 25.74 3.3 1003.72 -99192 -94130 -60325 -80491 -78040 -102260 -66580 -53296 -73536 -59475 -79068 -67194 -43077 -39231 -13024 -20803 -17828 -14226 -10338 580 -15580 -12694 -5592 -16843 -9547 -12207 1432 -10164 -11669 -17475 -6145 -4196 781 -3083 -3768 -2835 -6708 -1890 -108 2174 1662 832 -3474 1962 1857 3359 1674 5165 -478 5 637 3054 4030 2532 2714 1601 791 90 731 623 1577 2587 2559 2339 1427 585 1171 522 1639 1336 363 568 -137 493 -714 -573 -1233 -1396 -1434 -1010 -1072 -1214 -1961 -1473 -602 -422 -58 143 397 640 820 423 220 237 -37 44 -2 529 -269 -427 -621 -869 -527 -238 -1205 -1317 -516 -647 273 387 195 286 330 393 253 425 190 296 141 -178 -248 124 373 101 417 30 178 865 172 227 74 -247 -140 84 -106 -172 26 15 -30 -121 18 -166 -195 -1339 -1448 -724 -1178 -1025 -1637 -791 -633 -1223 -937 -1582 -1302 -803 -898 -288 -544 -513 -435 -331 18 -583 -463 -196 -714 -410 -573 60 -468 -532 -880 -319 -255 52 -234 -281 -204 -540 -172 -12 281 225 123 -566 313 301 548 283 864 -88 1 134 700 1005 695 790 492 253 29 231 193 498 881 910 936 611 247 474 215 727 686 210 346 -84 287 -389 -280 -557 -624 -700 -576 -665 -860 -1540 -1223 -494 -370 -54 137 381 594 712 367 180 195 -31 43 -2 630 -334 -537 -783 -993 -587 -265 -1366 -1594 -652 -819 371 583 306 474 547 626 379 642 287 441 223 -299 -418 203 585 153 644 44 253 1251 262 389 131 -467 -262 166 -224 -368 57 33 -68 -262 39 -338 -385 SS 20230731T112405.2Z 8612.475060 177 1 48.63 2 76.69 77.13 123.09 259.75 0.00 1 0.00 1 0 25 1.777e-01 6.032e-03 1.962e-02 1.022e-03 5.375416e-01 5.339036e-04 6.141817e-03 -6.000000e+00 1.029320e-01 232.15 -2.00 3.47 -2.00 320.07 0.00e+00 1.930910e-03 1.817443e-04 8.110927e-04 -6.000000e+00 4.616921e-03 290.58 -2.00 20.00 -2.00 319.30 0.00e+00 4.235 0.001 302.00 328.00 3 1.1522e+00 1.5954e-03 5.0642e-02 -6.0000e+00 2.5784e-01 1.5122e-02 1.9566e-03 2.8374e-02 -6.0000e+00 2.7858e-01 -5.6825e-02 1.6477e-03 1.4130e-02 -6.0000e+00 1.6619e-01 1.8251e-02 8.4741e-04 4.2353e-03 -6.0000e+00 7.0570e-02 1.4098e-03 -5.7793e-04 2.8374e-05 4.6582e-05 -6.0000e+00 4.7425e-03 2.9187e-02 3.3908e-05 10 0 0 10 0 0 84.49 26.58 0.35 0.02919 0.02484 280 66 1 5 0 173.640 31.10 25.03 26.58 26.66 3.2 1007.83 -74747 -66065 -55294 -60786 -53347 -75663 -53234 -57227 -52582 -38123 -43885 -45900 -38851 -23487 -17045 -12833 -6549 -10013 -6379 31 -6109 -6253 -3687 -7662 -5039 -6252 -5683 -6409 -7958 -7401 -2320 -4560 2770 -3303 -6028 -3788 -5210 -40 -1397 1893 -404 1305 -1515 1150 1895 2434 1263 2544 447 -273 1645 2280 2398 2271 1743 1657 1306 -175 -111 41 1242 1653 2139 2342 1144 764 770 827 1374 1078 346 6 192 11 -464 -781 -1190 -1413 -1065 -1201 -1392 -1165 -1795 -1482 -446 -493 45 325 223 883 850 548 -65 298 327 31 234 411 -188 -486 -520 -957 -689 -95 -997 -1285 -626 -657 32 419 272 171 300 285 447 456 477 287 93 -162 -282 -29 265 244 366 137 252 1097 243 109 29 -267 -264 130 -89 -119 0 16 -82 -138 26 -208 -119 -1170 -1126 -920 -1060 -792 -1343 -801 -1027 -1033 -707 -897 -1034 -984 -583 -493 -423 -228 -395 -263 1 -277 -286 -169 -396 -277 -370 -342 -378 -462 -440 -149 -354 230 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