File name: Pandora32s1_GreenbeltMD_20240121_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20240223T215254.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20240121_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240121T170409.2Z 8786.711217 346 1 48.36 2 58.99 176.04 101.98 41.70 0.00 1 0.00 1 0 25 1.549e-02 5.741e-03 5.776e-03 1.611e-03 3.237363e-01 8.025200e-04 3.879524e-03 -6.000000e+00 8.720129e-03 224.12 -2.00 3.47 -2.00 317.41 0.00e+00 6.222985e-04 1.186626e-04 8.961052e-05 -6.000000e+00 3.795577e-04 276.45 -2.00 20.00 -2.00 316.81 0.00e+00 1.934 0.000 302.00 328.00 3 4.6836e+00 2.1051e-03 2.5094e-02 -6.0000e+00 2.1539e-02 2.6026e-02 2.3718e-03 1.6177e-02 -6.0000e+00 2.3445e-02 -1.4578e-02 1.4644e-03 8.0949e-03 -6.0000e+00 1.3956e-02 1.3871e-03 7.4195e-04 2.3699e-03 -6.0000e+00 5.9660e-03 4.7098e-04 -4.9217e-04 4.5183e-05 2.5980e-05 -6.0000e+00 4.1203e-04 6.6070e-03 -1.2082e-04 10 0 0 10 0 0 46.67 20.40 0.39 0.00661 0.00291 24 6 1 5 0 2014.960 25.17 20.00 20.40 5.13 3.8 885.69 -4730 -4758 -2681 -4282 -7368 -6340 323 -2492 -903 -3178 -4564 -4752 -1301 -2125 1223 -56 -190 2087 -38 2474 1020 -474 2525 -974 1438 207 -409 -379 -2320 79 1408 737 1681 -748 -2387 -3304 -1728 -1225 58 389 -140 -149 -120 -371 -167 465 -205 -145 238 -582 553 693 1053 1341 472 940 960 81 83 -18 1123 1072 1553 1337 312 -235 38 -133 433 1142 -15 -177 -229 433 -100 -829 -309 -968 -943 -577 -1544 -936 -2006 -1679 -749 -888 170 -190 128 549 212 804 -117 454 416 363 482 677 726 -154 -292 -846 -367 40 -510 -1058 -790 -546 -149 352 335 269 297 148 360 288 337 96 156 -94 -459 198 367 200 310 340 252 722 526 301 237 -268 -308 -62 -67 -26 -409 73 220 -316 -50 -143 -351 -415 -473 -275 -435 -700 -554 27 -240 -96 -371 -546 -576 -169 -322 207 -11 -39 436 -8 558 239 -113 587 -245 375 57 -115 -103 -604 20 363 208 512 -245 -768 -1026 -552 -440 24 183 -72 -81 -67 -210 -95 262 -116 -81 131 -324 316 421 670 888 325 657 682 58 59 -12 788 787 1212 1106 265 -194 29 -101 339 967 -14 -168 -220 406 -90 -702 -243 -732 -725 -480 -1412 -915 -2083 -1795 -827 -1025 202 -232 157 662 246 881 -122 458 431 402 573 858 967 -208 -382 -1047 -433 47 -632 -1371 -1051 -746 -210 515 510 417 457 221 510 392 452 132 222 -139 -695 298 541 289 436 464 334 947 718 432 353 -410 -477 -97 -110 -44 -704 128 384 -549 -84 -236 -570 SS 20240121T170930.0Z 8786.714930 349 1 48.92 2 58.93 177.50 101.31 42.64 0.00 1 0.00 1 0 25 1.223e-02 5.428e-03 4.296e-03 1.233e-03 3.233436e-01 6.144693e-04 3.871337e-03 -6.000000e+00 6.885609e-03 224.12 -2.00 3.47 -2.00 317.34 0.00e+00 6.802273e-04 8.920062e-05 8.206241e-05 -6.000000e+00 2.996895e-04 276.45 -2.00 20.00 -2.00 316.74 0.00e+00 1.930 0.000 302.00 328.00 3 4.2023e+00 1.6096e-03 2.5047e-02 -6.0000e+00 1.7007e-02 1.9434e-02 1.8126e-03 1.6144e-02 -6.0000e+00 1.8512e-02 -1.1317e-02 1.1138e-03 8.0769e-03 -6.0000e+00 1.1020e-02 -5.4976e-04 5.6260e-04 2.3774e-03 -6.0000e+00 4.7113e-03 7.6677e-04 -4.0173e-04 3.4539e-05 2.5997e-05 -6.0000e+00 3.2528e-04 6.0420e-03 -1.0376e-04 10 0 0 10 0 0 31.80 20.41 0.25 0.00604 0.00302 41 10 1 5 0 1192.950 25.17 19.99 20.41 5.16 3.7 884.38 -1539 -2503 -2494 -3351 -4200 -3342 -2443 -2671 -3310 -2367 -4693 -4399 -1596 -1761 803 -1012 -629 121 474 1661 700 861 1770 374 1619 410 -372 -978 -1135 -620 1304 802 1690 37 -2371 -2342 -1671 -718 -216 -43 -697 -633 -613 -408 411 -24 -229 -302 -127 -376 695 754 800 1140 349 1154 1083 312 224 484 755 1265 1529 1455 347 15 -40 -134 435 970 34 11 -244 159 -37 -340 -449 -850 -638 -951 -1233 -917 -1778 -1870 -764 -671 -207 -227 256 459 199 430 362 426 766 483 398 625 240 -461 -321 -779 -454 243 -477 -1061 -531 -599 -105 389 122 188 242 270 182 378 448 248 112 -103 -387 34 356 59 424 474 291 835 499 16 240 -192 -196 121 161 -183 -128 36 -6 -196 -6 -270 -557 -136 -252 -265 -350 -402 -296 -220 -267 -375 -285 -582 -552 -215 -275 141 -202 -133 27 108 388 170 208 428 96 433 116 -107 -274 -301 -160 347 233 530 12 -784 -742 -549 -263 -91 -21 -367 -349 -347 -234 235 -14 -131 -171 -71 -212 404 464 517 765 243 813 776 225 160 341 537 937 1205 1211 297 13 -31 -103 344 829 31 11 -235 150 -33 -289 -356 -648 -494 -798 -1129 -900 -1848 -2007 -845 -775 -247 -278 314 554 231 473 376 431 795 535 472 791 321 -622 -419 -964 -536 286 -591 -1374 -704 -816 -148 567 185 291 371 400 257 512 601 339 160 -152 -583 51 524 85 595 647 385 1094 681 23 357 -293 -302 190 262 -308 -219 62 -10 -338 -10 -444 -901 SS 20240121T171505.7Z 8786.718816 352 1 48.29 2 58.90 179.04 100.59 43.62 0.00 1 0.00 1 0 17 1.513e-02 5.316e-03 4.106e-03 1.187e-03 3.237994e-01 5.934182e-04 3.876127e-03 -6.000000e+00 8.517835e-03 224.12 -2.00 3.47 -2.00 317.31 0.00e+00 6.333879e-04 8.523553e-05 7.483470e-05 -6.000000e+00 3.707439e-04 276.45 -2.00 20.00 -2.00 316.71 0.00e+00 1.928 0.000 302.00 328.00 3 4.1123e+00 1.5545e-03 2.5046e-02 -6.0000e+00 2.1039e-02 2.1587e-02 1.7493e-03 1.6154e-02 -6.0000e+00 2.2901e-02 -1.3388e-02 1.0739e-03 8.0879e-03 -6.0000e+00 1.3632e-02 1.3029e-03 5.4148e-04 2.3819e-03 -6.0000e+00 5.8278e-03 8.3918e-04 -4.2734e-04 3.3255e-05 2.5707e-05 -6.0000e+00 4.0245e-04 6.1114e-03 -1.2807e-04 10 0 0 10 0 0 46.16 20.41 0.31 0.00611 0.00290 45 11 1 5 0 1073.020 25.17 20.00 20.41 5.05 3.7 883.48 -2065 -5691 -3429 -7010 -4722 -6202 -2960 -3229 -2741 -78 -5751 -2933 -2211 -2054 847 -1022 131 -72 1173 2593 265 1046 1993 939 295 225 -176 -394 -302 -607 1946 233 2430 32 -2550 -1738 -2164 -742 -447 131 308 -662 -344 -670 -82 63 -370 225 -441 136 349 945 645 1216 784 566 1099 -84 235 407 983 1417 1358 1182 287 -249 -96 -113 866 926 -142 -308 -203 241 -184 -313 -507 -560 -995 -616 -1061 -1229 -1645 -1759 -838 -776 50 -52 247 332 273 448 88 232 849 267 323 628 311 -339 -55 -554 -552 157 -424 -932 -713 -415 -9 297 200 124 121 325 37 422 324 238 247 -226 -218 15 419 72 342 427 194 965 321 151 168 -148 -155 32 48 -154 -177 47 48 -178 -76 -183 -540 -183 -596 -370 -762 -450 -555 -263 -322 -309 -9 -726 -364 -304 -330 155 -201 27 -16 266 603 65 254 481 241 82 66 -52 -112 -80 -157 517 70 784 10 -825 -567 -745 -272 -197 64 158 -365 -196 -389 -47 37 -213 127 -247 76 204 594 411 816 551 409 808 -63 172 291 709 1027 1080 971 245 -203 -76 -86 682 783 -129 -295 -196 224 -169 -274 -399 -437 -758 -525 -984 -1214 -1686 -1896 -950 -902 59 -63 302 395 317 497 94 236 898 300 388 803 415 -460 -70 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