File name: Pandora32s1_GreenbeltMD_20240201_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20240223T215238.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20240201_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240201T170913.1Z 8797.714735 434 1 48.35 2 56.16 176.64 110.53 270.74 0.00 1 0.00 1 0 17 1.168e-02 5.464e-03 4.796e-03 1.613e-03 2.936639e-01 8.062017e-04 3.517842e-03 -6.000000e+00 6.591152e-03 224.50 -2.00 3.47 -2.00 317.04 0.00e+00 3.943552e-04 1.078330e-04 6.398688e-05 -6.000000e+00 2.863191e-04 276.39 -2.00 20.00 -2.00 316.45 0.00e+00 1.790 0.000 302.00 328.00 3 4.8738e+00 2.1039e-03 2.3033e-02 -6.0000e+00 1.6294e-02 1.8649e-02 2.3638e-03 1.4657e-02 -6.0000e+00 1.7728e-02 -8.5897e-03 1.4227e-03 7.3186e-03 -6.0000e+00 1.0550e-02 -1.0226e-03 7.0453e-04 2.1184e-03 -6.0000e+00 4.5088e-03 4.7027e-04 -3.7438e-04 4.5327e-05 2.3678e-05 -6.0000e+00 3.1076e-04 3.8080e-03 -6.4686e-05 10 0 0 10 0 0 77.28 21.37 0.26 0.00381 0.00099 22 5 1 5 0 2197.420 25.90 20.00 21.37 16.88 3.8 953.22 1228 -2126 -2641 -1242 -4695 -5076 -1316 -1441 307 -3144 -2792 -4588 -989 573 181 1631 -1378 709 78 1959 1252 -332 2533 330 840 -37 -846 186 -1450 -380 741 738 2029 -258 -2837 -1975 -2013 -1191 -519 89 -751 -95 -225 -114 64 293 98 -423 -18 -550 750 136 539 1556 925 862 504 -261 333 247 1505 966 1568 875 247 121 -807 -118 386 938 -5 49 72 147 38 -630 -263 -792 -1109 -268 -1501 -1152 -1739 -1764 -809 -599 109 -116 177 287 348 768 18 362 528 432 404 726 505 -352 38 -772 -387 -27 -638 -812 -406 -449 -13 210 397 133 141 182 334 235 186 238 -51 -55 -354 147 216 195 321 244 41 742 452 178 198 -480 -401 225 -111 170 -205 52 373 -79 -79 -283 -600 131 -264 -344 -156 -552 -555 -142 -172 41 -460 -411 -690 -157 102 37 366 -336 176 20 518 343 -92 686 95 254 -12 -274 58 -431 -109 217 234 688 -93 -1018 -674 -713 -469 -236 46 -424 -56 -136 -70 39 179 60 -254 -11 -327 456 88 363 1084 667 632 377 -196 247 181 1105 743 1276 756 218 104 -656 -93 310 814 -5 48 70 141 35 -548 -213 -614 -870 -226 -1387 -1140 -1819 -1904 -902 -696 131 -144 219 350 407 851 19 367 549 477 477 915 669 -472 49 -953 -454 -32 -790 -1049 -538 -611 -18 305 599 204 214 267 467 315 245 321 -72 -80 -530 218 315 279 446 330 53 960 607 252 290 -718 -607 346 -177 279 -344 88 636 -134 -131 -459 -957 SS 20240201T171447.4Z 8797.718604 437 1 48.72 2 56.11 178.24 111.58 271.58 0.00 1 0.00 1 0 25 1.088e-02 5.554e-03 3.912e-03 1.350e-03 2.939760e-01 6.749179e-04 3.533324e-03 -6.000000e+00 6.139228e-03 224.50 -2.00 3.47 -2.00 316.99 0.00e+00 5.145287e-04 8.907653e-05 6.575916e-05 -6.000000e+00 2.666741e-04 276.39 -2.00 20.00 -2.00 316.39 0.00e+00 1.788 0.000 302.00 328.00 3 4.5544e+00 1.7599e-03 2.3040e-02 -6.0000e+00 1.5177e-02 1.5604e-02 1.9767e-03 1.4698e-02 -6.0000e+00 1.6512e-02 -8.8265e-03 1.1858e-03 7.3390e-03 -6.0000e+00 9.8265e-03 -6.4840e-05 5.8548e-04 2.1372e-03 -6.0000e+00 4.1998e-03 6.4866e-04 -2.8169e-04 3.7856e-05 2.3930e-05 -6.0000e+00 2.8942e-04 3.5063e-03 -6.0919e-05 10 0 0 10 0 0 92.18 21.38 0.30 0.00351 0.00139 31 7 1 5 0 1571.510 25.90 20.00 21.38 17.09 3.7 953.49 -247 -1989 -969 -2157 -4654 -5029 -929 -1614 -1521 -2372 -2978 -2681 1263 -2029 634 1850 -789 933 639 2114 1046 351 1066 498 894 -215 430 -316 -720 -478 425 1005 1379 -419 -2131 -1860 -2290 -1115 -471 -167 -868 -869 -529 59 -101 259 -135 -776 -580 -463 361 1117 1282 1067 664 861 897 118 336 175 811 1333 1412 1185 523 -356 -194 -201 556 1243 -9 24 -251 223 -197 -348 -168 -464 -767 -770 -1364 -1164 -1706 -1718 -882 -776 168 -50 322 321 357 829 -102 481 739 408 324 563 423 -289 -324 -773 -597 -7 -525 -1051 -682 -421 -63 395 222 243 134 322 124 459 312 137 211 7 -259 -183 98 129 371 529 122 930 449 333 110 -272 -310 149 -77 -99 -86 126 13 -59 -64 -212 -599 -27 -254 -128 -282 -566 -568 -103 -199 -211 -355 -451 -407 202 -381 132 425 -196 237 169 572 293 99 299 146 276 -70 141 -101 -217 -140 128 324 479 -154 -775 -647 -829 -447 -217 -87 -495 -519 -323 36 -63 160 -83 -472 -349 -278 222 722 866 752 482 636 673 89 251 129 603 1031 1157 1025 463 -307 -158 -159 449 1081 -8 24 -248 215 -183 -305 -136 -361 -605 -654 -1265 -1155 -1786 -1854 -984 -903 202 -62 398 391 419 919 -107 488 768 452 383 709 560 -387 -421 -954 -703 -8 -649 -1360 -903 -571 -87 572 334 372 203 471 173 614 413 184 295 10 -386 -272 143 185 514 713 160 1202 603 469 161 -406 -468 228 -122 -163 -144 213 22 -99 -105 -341 -952 SS 20240201T172519.1Z 8797.725915 440 1 48.11 2 56.10 181.27 113.58 273.19 0.00 1 0.00 1 0 17 1.110e-02 5.553e-03 3.651e-03 1.272e-03 2.932870e-01 6.355966e-04 3.509751e-03 -6.000000e+00 6.266870e-03 224.50 -2.00 3.47 -2.00 316.96 0.00e+00 4.707038e-04 8.343787e-05 6.439378e-05 -6.000000e+00 2.721525e-04 276.39 -2.00 20.00 -2.00 316.37 0.00e+00 1.787 0.000 302.00 328.00 3 4.4288e+00 1.6565e-03 2.2990e-02 -6.0000e+00 1.5493e-02 1.6387e-02 1.8602e-03 1.4623e-02 -6.0000e+00 1.6854e-02 -7.2958e-03 1.1148e-03 7.2999e-03 -6.0000e+00 1.0030e-02 -1.0781e-03 5.5000e-04 2.1276e-03 -6.0000e+00 4.2877e-03 7.3635e-04 6.9177e-06 3.5655e-05 2.3667e-05 -6.0000e+00 2.9534e-04 3.1251e-03 -1.1879e-05 10 0 0 10 0 0 99.89 21.40 0.29 0.00313 0.00318 36 8 1 5 0 1336.330 26.00 20.00 21.40 17.25 3.7 953.24 -2425 -60 -2160 -1839 -5203 -3783 -1292 -1925 552 -2113 -1968 -4648 -1300 144 1094 614 -512 1091 636 1525 1209 139 2752 720 732 291 -566 -259 -578 -78 896 358 1439 -574 -2237 -2437 -1529 -1429 -699 33 -1281 -286 -797 -443 -132 15 -215 -187 -475 -399 858 723 571 1483 835 1142 998 40 425 300 1402 975 1293 1214 119 -312 -171 63 369 1165 -66 -73 171 245 -19 -485 -197 -941 -1047 -393 -1380 -1072 -1939 -1801 -761 -771 -8 154 330 408 307 575 9 527 787 222 400 438 284 -310 -287 -831 -387 121 -526 -902 -697 -422 -138 320 315 302 273 203 157 161 439 423 169 -181 -376 82 384 21 254 407 84 800 510 41 31 -37 -260 135 74 -49 -109 3 133 -303 -43 -326 -370 -279 -8 -292 -242 -643 -427 -146 -241 76 -319 -299 -726 -215 27 230 144 -128 279 170 418 341 39 768 213 228 95 -188 -83 -176 -23 271 117 503 -214 -821 -857 -554 -578 -324 17 -737 -171 -490 -275 -82 9 -133 -114 -286 -240 529 470 390 1045 608 844 751 30 318 222 1041 757 1063 1051 106 -270 -139 50 299 1015 -62 -71 168 237 -18 -425 -160 -737 -829 -334 -1282 -1065 -2036 -1949 -850 -898 -10 189 408 498 360 639 9 536 818 246 473 552 376 -415 -372 -1025 -455 143 -650 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