File name: Pandora32s1_GreenbeltMD_20240519_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20240520T051013.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20240519_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240519T152630.3Z 8905.643407 342 1 48.47 2 28.31 125.21 142.88 32.56 0.00 1 0.00 1 0 17 8.263e-03 6.037e-03 2.481e-03 1.614e-03 1.776110e-01 8.363215e-04 2.110779e-03 -6.000000e+00 4.788456e-03 231.42 -2.00 3.47 -2.00 315.11 0.00e+00 4.164338e-04 7.315292e-05 3.470837e-05 -6.000000e+00 2.098329e-04 284.88 -2.00 20.00 -2.00 314.48 0.00e+00 1.135 0.000 302.00 328.00 3 5.6341e+00 2.1630e-03 1.4583e-02 -6.0000e+00 1.1998e-02 4.2096e-02 2.3956e-03 9.0857e-03 -6.0000e+00 1.2966e-02 -3.3997e-03 1.3699e-03 4.4182e-03 -6.0000e+00 7.7129e-03 -1.6572e-03 6.0831e-04 1.2352e-03 -6.0000e+00 3.2760e-03 5.0266e-04 1.2420e-04 4.5032e-05 1.5286e-05 -6.0000e+00 2.2019e-04 3.2414e-03 5.8533e-05 10 0 0 10 0 0 99.99 22.27 0.43 0.00324 0.00417 19 4 1 5 0 2550.760 26.73 20.00 22.27 28.67 4.5 1032.42 150 -1581 -583 -585 -1970 -1976 588 1163 1442 -783 -1084 -1715 -519 -522 599 883 -570 1168 728 1582 1466 -94 1704 306 648 16 181 -172 -419 568 1091 803 1389 -977 -2404 -1593 -2563 -1747 -728 -171 -776 -313 -369 -77 -412 -112 -108 -822 -802 -490 403 578 789 749 431 796 695 430 438 368 1441 1044 1496 1258 352 -114 -386 -374 19 686 336 323 289 281 -28 -316 -770 -1591 -1526 -1401 -1323 -1091 -1663 -1355 -667 -342 96 345 493 520 15 560 -152 -42 227 40 204 906 702 -100 -103 -722 -494 -275 -755 -945 -580 -315 -75 409 523 631 363 330 -5 -53 52 -164 208 151 134 210 483 213 41 40 53 491 245 93 -95 -274 -337 -45 -87 42 -16 -33 313 -11 -54 -233 -523 44 -514 -193 -187 -579 -535 157 335 457 -267 -367 -573 -180 -199 248 391 -264 540 346 762 722 -46 830 155 339 9 99 -90 -208 267 514 396 717 -529 -1272 -800 -1335 -998 -469 -123 -601 -250 -300 -63 -338 -92 -87 -649 -617 -371 307 459 649 635 374 695 615 381 384 321 1263 950 1428 1252 355 -111 -350 -326 17 647 340 338 306 294 -28 -301 -683 -1343 -1281 -1249 -1271 -1114 -1782 -1488 -757 -405 118 433 623 649 18 636 -161 -43 234 44 234 1100 892 -128 -128 -856 -562 -315 -911 -1190 -749 -415 -101 568 746 908 515 449 -6 -65 63 -203 267 204 184 291 659 284 53 51 64 586 300 118 -125 -366 -452 -61 -122 61 -23 -49 473 -17 -79 -337 -747 SS 20240519T191310.4Z 8905.800815 497 1 0.70 2 33.65 245.03 107.03 85.23 0.00 1 0.00 1 0 17 8.938e-03 7.031e-03 5.030e-03 3.582e-03 1.814715e-01 1.865074e-03 2.184677e-03 -6.000000e+00 5.177237e-03 231.43 -2.00 3.47 -2.00 314.71 0.00e+00 3.956713e-04 1.509403e-04 1.687152e-05 -6.000000e+00 2.269850e-04 284.89 -2.00 20.00 -2.00 314.12 0.00e+00 1.201 0.000 302.00 328.00 3 2.6953e+00 4.8030e-03 1.5236e-02 -6.0000e+00 1.2972e-02 2.4787e-02 5.3090e-03 9.3448e-03 -6.0000e+00 1.4021e-02 -7.4093e-03 3.0388e-03 4.5500e-03 -6.0000e+00 8.3402e-03 -3.7030e-04 1.3316e-03 1.2783e-03 -6.0000e+00 3.5410e-03 8.9250e-03 -4.3724e-04 9.9367e-05 1.6488e-05 -6.0000e+00 2.3820e-04 4.0353e-03 -3.3778e-05 12 9 1 12 1 1 999.00 22.69 0.33 0.00404 0.00075 2 49 1 5 0 231.470 27.05 20.01 22.69 32.20 4.5 1051.03 1512 -838 1142 -2901 -440 -1128 -49 2254 -295 425 -1800 -1771 353 -61 605 -597 -155 110 917 1369 485 1042 870 908 1022 561 271 74 407 -548 1375 -422 95 -1034 -2931 -884 -3113 -1207 -882 -33 -1209 -892 -733 -494 292 -396 -278 -782 -529 -221 699 382 961 1257 1109 593 1290 -534 884 498 1191 1716 1051 1803 105 -202 28 -479 789 1109 156 637 15 343 -536 -160 -1128 -898 -725 -815 -304 -1640 -2040 -1710 -1068 -611 -605 716 -108 399 746 681 239 488 -52 233 352 666 373 -216 -510 -401 -680 -105 -1133 -616 -429 -237 -514 636 560 -9 68 330 -21 595 536 45 35 -181 -235 -313 335 225 517 138 276 762 718 -150 127 -361 375 24 500 -271 333 -128 221 -11 -345 -258 -1013 518 -314 432 -1095 -151 -362 -16 763 -110 165 -708 -686 140 -26 281 -296 -79 56 479 724 263 561 468 499 579 327 159 42 220 -288 716 -231 54 -607 -1694 -486 -1777 -740 -601 -25 -965 -732 -610 -414 243 -331 -230 -634 -419 -173 551 312 809 1083 974 527 1155 -483 787 441 1062 1574 1010 1789 106 -197 26 -426 706 1055 158 665 16 357 -544 -154 -1023 -777 -624 -740 -294 -1686 -2187 -1874 -1205 -715 -733 880 -134 490 882 767 255 499 -54 253 402 800 467 -273 -627 -471 -773 -120 -1355 -764 -544 -306 -682 861 779 -12 94 441 -26 725 645 56 44 -240 -319 -426 450 297 662 172 334 907 874 -190 165 -477 495 32 689 -387 482 -189 326 -16 -501 -368 -1428 SS 20240519T195817.8Z 8905.832150 524 1 48.79 2 41.91 255.93 98.64 92.33 0.00 1 0.00 1 0 17 1.192e-02 7.202e-03 6.184e-03 2.872e-03 2.032861e-01 1.471182e-03 2.408059e-03 -6.000000e+00 6.912271e-03 231.43 -2.00 3.47 -2.00 316.36 0.00e+00 6.554464e-04 1.670270e-04 4.431994e-05 -6.000000e+00 3.027832e-04 284.90 -2.00 20.00 -2.00 315.62 0.00e+00 1.342 0.000 302.00 328.00 3 6.1221e+00 3.8574e-03 1.7045e-02 -6.0000e+00 1.7320e-02 4.2077e-02 4.2995e-03 1.0474e-02 -6.0000e+00 1.8715e-02 5.9864e-03 2.4866e-03 5.0872e-03 -6.0000e+00 1.1133e-02 -7.9162e-03 1.1601e-03 1.4719e-03 -6.0000e+00 4.7303e-03 2.3858e-04 5.5151e-04 8.1534e-05 1.6419e-05 -6.0000e+00 3.1770e-04 2.5136e-03 1.2475e-04 11 9 0 11 8 0 99.99 22.77 0.19 0.00251 0.00666 43 10 1 5 0 1134.590 27.15 20.00 22.77 31.35 4.4 1046.00 4282 -2245 356 -2474 -4552 717 -212 2577 -1320 999 -3251 -1722 1306 -725 1677 -527 -282 677 -124 3118 475 212 763 292 936 -687 2327 -1341 1009 -2270 -22 2159 785 709 -2777 -234 -2775 -1749 -971 -258 -324 -661 -1330 -487 323 -24 -1007 670 -1667 -891 798 762 1502 203 1498 227 827 -575 275 929 698 1671 1423 1625 532 -1508 -207 -556 234 536 157 770 174 1603 -676 21 -1669 -1011 -837 -1962 -1389 -2107 -1739 -1237 -340 231 -172 771 65 860 775 555 -273 -418 529 -278 452 978 134 183 -184 -815 -932 -628 -388 -1125 -444 -610 307 465 555 967 457 514 -162 22 -328 -316 35 152 -505 67 172 135 60 396 -457 784 -296 389 254 -613 -129 2 228 166 -68 -202 69 332 320 -352 -637 731 -452 72 -500 -844 116 -35 454 -270 213 -716 -369 289 -183 465 -163 -91 221 -42 1059 170 76 270 107 358 -277 921 -526 362 -802 -8 788 310 292 -1132 -88 -1113 -783 -504 -153 -210 -449 -931 -343 226 -17 -702 447 -1106 -578 522 527 1082 154 1153 179 659 -464 218 723 553 1377 1251 1504 503 -1378 -173 -444 190 474 152 773 177 1588 -653 19 -1377 -778 -642 -1644 -1272 -2097 -1827 -1338 -382 273 -214 981 84 1085 932 624 -285 -417 532 -300 523 1214 177 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