File name: Pandora32s1_GreenbeltMD_20240915_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20240916T050927.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20240915_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20240915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240915T130842.8Z 9024.547718 189 1 48.60 2 64.14 108.97 150.83 303.87 0.00 1 0.00 1 0 17 1.213e-02 5.173e-03 7.762e-03 1.547e-03 3.096585e-01 7.823915e-04 3.650549e-03 -6.000000e+00 6.968972e-03 229.16 -2.00 3.47 -2.00 318.20 0.00e+00 5.104959e-04 1.459291e-04 8.690775e-05 -6.000000e+00 3.130593e-04 288.63 -2.00 20.00 -2.00 317.36 0.00e+00 2.278 0.000 302.00 328.00 3 3.8759e+00 2.1140e-03 2.7674e-02 -6.0000e+00 1.7342e-02 -3.9558e-03 2.4056e-03 1.5966e-02 -6.0000e+00 1.8767e-02 1.4041e-02 1.5391e-03 7.8031e-03 -6.0000e+00 1.1210e-02 -1.1701e-02 7.9329e-04 2.2259e-03 -6.0000e+00 4.7977e-03 7.8259e-04 8.0822e-05 4.4606e-05 2.3672e-05 -6.0000e+00 3.2334e-04 6.8677e-03 -4.7222e-05 11 1 0 11 8 0 100.00 21.56 0.14 0.00687 0.00748 226 53 1 5 0 215.000 26.41 20.01 21.56 23.98 5.2 1001.22 -3111 -4227 -577 -2752 -3667 2573 -4153 1805 -3490 557 -2287 -3065 1426 -2703 1805 -36 -600 -234 729 2018 -711 529 981 1123 663 -343 1026 -1588 -820 -242 302 1739 2516 -572 -3722 -514 -1319 -1351 -451 -1113 -564 -1285 -1563 -758 -419 290 -855 160 -712 -1052 501 894 1409 1028 773 283 917 475 429 912 870 1465 1481 1212 610 -887 236 -86 592 752 121 103 -93 334 126 -87 -236 -754 -603 -306 -731 -1168 -1662 -1536 -887 -641 -253 28 30 643 521 852 44 515 904 408 334 814 116 -99 -485 -737 -679 242 -320 -1127 -451 -715 -457 433 84 330 273 201 156 248 316 99 18 -131 -360 -237 53 78 284 480 72 927 484 294 283 -368 -217 67 127 173 -363 172 -70 -86 -36 -106 -402 -189 -293 -41 -194 -238 147 -260 119 -273 45 -192 -263 129 -294 217 -5 -89 -36 116 331 -124 91 170 204 129 -71 212 -325 -157 -45 58 364 572 -141 -916 -117 -319 -374 -147 -425 -237 -574 -722 -354 -196 136 -401 73 -325 -484 238 453 755 580 454 170 563 294 262 548 532 942 1028 901 466 -659 162 -58 410 575 102 90 -83 289 104 -66 -165 -505 -412 -229 -611 -1068 -1627 -1562 -942 -717 -296 33 36 762 588 898 44 490 888 435 389 1022 156 -134 -632 -900 -786 281 -394 -1469 -605 -996 -659 653 133 534 436 308 225 341 429 138 27 -202 -567 -372 81 117 411 670 97 1232 676 435 439 -588 -352 112 220 310 -669 321 -132 -160 -66 -187 -696 SS 20240915T132528.0Z 9024.559352 205 1 1.68 2 61.09 112.20 153.25 309.98 0.00 1 0.00 1 0 17 1.781e-02 7.705e-03 1.270e-02 4.889e-03 2.818231e-01 2.486663e-03 3.351408e-03 -6.000000e+00 1.022455e-02 229.16 -2.00 3.47 -2.00 316.78 0.00e+00 -3.097180e-04 3.191415e-04 5.848293e-05 -6.000000e+00 4.593755e-04 288.63 -2.00 20.00 -2.00 315.97 0.00e+00 2.059 0.000 302.00 328.00 3 3.1507e+00 6.5200e-03 2.5019e-02 -6.0000e+00 2.5444e-02 3.4572e-03 7.3076e-03 1.4411e-02 -6.0000e+00 2.7537e-02 -4.9123e-03 4.2909e-03 7.0380e-03 -6.0000e+00 1.6448e-02 3.2425e-04 2.0724e-03 1.9659e-03 -6.0000e+00 7.0376e-03 2.0930e-03 -3.7810e-04 1.3730e-04 2.2353e-05 -6.0000e+00 4.7462e-04 7.2356e-03 -1.2566e-04 12 9 1 12 1 1 999.00 21.70 0.40 0.00724 0.00439 2 20 1 5 0 557.890 26.51 20.00 21.70 25.18 5.1 1008.32 -1228 -2631 -790 -995 -2979 -2617 3202 -873 274 1884 -2640 -13800 -2664 2816 -3659 3680 -447 -888 5431 -1287 2708 -942 1518 594 -1334 1134 -3626 2253 -969 2087 436 -1460 3 -1216 -659 -2398 -1808 766 1819 2237 -841 570 401 -1509 118 -966 -975 -1436 -250 1559 621 1593 540 1136 269 412 678 -197 735 259 1180 1577 1312 1037 27 -676 -169 222 -416 1298 977 -849 227 -664 357 380 446 -936 -759 538 -1655 -1380 -1496 -2040 -765 -1619 249 -689 -194 869 -753 1002 -137 1155 1265 514 301 678 316 -420 -665 -65 -888 289 -228 -780 -757 -263 216 -44 54 -78 250 340 782 675 272 573 -831 -210 -249 -68 155 282 408 712 368 432 534 1077 -289 -116 -446 206 81 -603 246 419 92 -640 15 -337 -556 -160 -387 -119 -146 -406 -332 396 -124 43 313 -459 -2649 -504 576 -886 922 -122 -251 1515 -390 817 -292 465 191 -459 399 -1333 767 -319 653 143 -518 1 -481 -252 -894 -699 324 876 1213 -502 351 253 -974 75 -622 -624 -908 -155 954 394 1057 376 818 201 311 520 -152 559 196 897 1245 1096 910 24 -589 -139 178 -343 1142 920 -835 224 -648 334 335 367 -746 -610 461 -1553 -1379 -1567 -2205 -853 -1892 298 -849 -239 1053 -887 1111 -144 1176 1318 570 355 848 415 -557 -855 -79 -1045 340 -282 -1004 -1002 -356 300 -64 80 -118 374 491 1077 894 357 766 -1161 -305 -367 -100 224 400 564 957 481 559 715 1502 -419 -172 -668 314 128 -980 406 698 155 -1071 24 -540 -877 SS 20240915T134117.6Z 9024.570342 217 1 48.57 2 58.28 115.42 155.33 316.59 0.00 1 0.00 1 0 17 8.369e-03 5.226e-03 1.524e-03 5.390e-04 2.577104e-01 2.732221e-04 3.069860e-03 -6.000000e+00 4.807729e-03 229.16 -2.00 3.47 -2.00 317.06 0.00e+00 3.410588e-04 3.750537e-05 6.948583e-05 -6.000000e+00 2.159268e-04 288.63 -2.00 20.00 -2.00 316.23 0.00e+00 1.895 0.000 302.00 328.00 3 2.4963e+00 7.1937e-04 2.2998e-02 -6.0000e+00 1.1964e-02 -1.7221e-03 8.0800e-04 1.3218e-02 -6.0000e+00 1.2946e-02 5.0275e-03 4.7854e-04 6.4549e-03 -6.0000e+00 7.7328e-03 -6.1794e-03 2.3380e-04 1.8072e-03 -6.0000e+00 3.3104e-03 4.8966e-03 2.4835e-04 1.5322e-05 2.0128e-05 -6.0000e+00 2.2297e-04 6.0680e-03 -5.2647e-06 10 0 0 10 0 0 99.99 21.85 0.26 0.00607 0.00793 692 162 1 5 0 70.170 26.62 20.00 21.85 26.00 5.1 1011.03 -4 -755 -1031 -2799 -2960 -3255 -718 -286 1227 -339 -1713 -1096 -770 180 49 335 -196 -64 766 517 1224 645 1095 772 299 282 -191 -423 -370 -290 1029 750 1714 -397 -2307 -1854 -1939 -989 -418 -205 -920 -708 -696 -723 -136 -223 -496 -339 -663 -470 491 744 585 932 674 839 1119 204 611 394 944 1240 1503 1512 403 -162 -94 -365 595 997 174 52 -23 -20 53 -185 -415 -677 -625 -456 -1094 -970 -1664 -1785 -744 -719 -133 38 165 442 350 719 -128 494 774 335 302 401 337 -204 -198 -881 -685 162 -444 -938 -630 -585 -148 356 333 299 302 276 139 262 146 201 7 -53 -406 -83 89 122 432 407 42 830 440 307 227 -192 -198 73 94 0 -106 132 -32 -167 25 -341 -505 0 -102 -146 -390 -370 -375 -82 -36 175 -53 -271 -172 -131 35 10 77 -48 -16 200 141 341 180 305 226 94 93 -64 -135 -110 -83 298 237 584 -146 -825 -625 -687 -401 -188 -109 -513 -417 -423 -447 -83 -137 -302 -201 -384 -270 291 471 396 662 467 594 807 149 436 278 674 939 1237 1338 347 -140 -74 -275 462 870 160 50 -22 -19 48 -161 -324 -526 -492 -375 -1024 -948 -1764 -1878 -824 -856 -158 47 206 536 420 784 -136 492 795 358 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