File name: Pandora32s1_GreenbeltMD_20241030_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20241031T050429.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20241030_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241030 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241030T121824.1Z 9069.512779 99 1 48.63 2 82.65 114.78 64.04 125.58 0.00 1 0.00 1 0 25 3.822e-01 2.163e-02 1.648e-01 8.304e-03 7.250469e-01 4.458992e-03 8.466856e-03 -6.000000e+00 2.157455e-01 224.86 -2.00 3.47 -2.00 321.69 0.00e+00 7.679343e-03 2.281956e-03 3.684466e-03 -6.000000e+00 9.634733e-03 283.32 -2.00 20.00 -2.00 321.16 0.00e+00 7.224 0.007 302.00 328.00 3 1.5660e+00 1.5893e-02 8.1547e-02 -6.0000e+00 5.3251e-01 6.1681e-01 2.0441e-02 4.0495e-02 -6.0000e+00 5.7876e-01 -9.5540e-01 1.7004e-02 2.2164e-02 -6.0000e+00 3.4575e-01 4.0601e-01 8.1608e-03 8.2057e-03 -6.0000e+00 1.4843e-01 4.6057e-05 -1.1840e-03 2.2900e-04 1.4362e-04 -6.0000e+00 1.0173e-02 9.5615e-03 -1.5643e-04 12 8 8 10 0 0 26.57 21.00 1.28 0.00956 0.00066 39 9 1 5 0 1246.740 25.90 19.65 21.00 17.32 5.3 963.56 -122705 -138124 -87530 -71168 -79591 -138110 -56915 -112446 -21003 -108397 -126081 -142661 -85502 -37624 10729 6035 -43500 660 5826 18452 -29047 -1705 18060 -21472 -16295 15081 26163 -23494 1890 -43178 62738 -15858 126700 8320 4012 5707 -8522 24288 1628 15135 11244 59127 19290 52776 58719 24247 4714 44369 33133 17231 26039 38519 49212 31191 27009 21842 15059 13891 12052 21368 21544 7173 18675 17588 11031 12284 9390 11854 9370 15133 8632 1825 3850 6092 2092 3947 -4828 -1626 -6108 -2814 -2536 -901 -1363 -3008 2232 -1416 -1174 -753 -449 1386 312 1568 -4070 -5523 -3812 -1836 -2769 -1690 -1171 -2162 -871 -3195 -4323 -1245 -3191 -1919 -2458 -1774 -1114 -1109 -692 -182 0 933 750 -540 -349 -322 1195 546 548 1102 3019 1923 1119 934 1687 1544 870 913 760 1163 218 693 252 244 -533 -1283 -283 175 42 -942 -1280 -4336 -6609 -2642 -1729 -1816 -4982 -880 -3146 -272 -3112 -4270 -5986 -2700 -945 209 147 -1937 20 179 508 -1270 -54 453 -817 -607 415 636 -894 54 -1993 1169 -783 1744 404 195 254 -449 1042 104 993 856 2969 1500 2992 3138 1846 443 2874 2495 1605 2425 3525 4424 3612 3434 3007 2256 2081 1767 2751 2791 1162 3070 3333 2421 2656 2038 2553 2246 3934 2670 578 1306 1909 622 1026 -1259 -411 -1791 -955 -1023 -376 -637 -1528 1144 -803 -702 -465 -278 821 176 816 -2148 -3025 -2298 -1275 -2283 -1602 -1237 -2387 -906 -3065 -3774 -1031 -2878 -1832 -2498 -1923 -1323 -1498 -965 -275 0 1408 1084 -759 -489 -472 1838 888 893 1723 4444 2783 1582 1398 2420 2281 1341 1623 1513 2490 499 1553 608 624 -1415 -3482 -763 456 102 -2164 -3045 SS 20241030T122918.9Z 9069.520358 102 1 48.42 2 80.74 116.63 62.40 127.93 0.00 1 0.00 1 0 17 4.384e-01 1.070e-02 6.637e-02 2.813e-03 6.294017e-01 1.487607e-03 7.275755e-03 -6.000000e+00 2.474878e-01 224.86 -2.00 3.47 -2.00 321.02 0.00e+00 4.661956e-03 6.746761e-04 1.886915e-03 -6.000000e+00 1.105254e-02 283.32 -2.00 20.00 -2.00 320.45 0.00e+00 5.905 0.004 302.00 328.00 3 1.2816e+00 4.8970e-03 6.6850e-02 -6.0000e+00 6.1086e-01 1.2927e-01 6.5005e-03 3.3833e-02 -6.0000e+00 6.6393e-01 -2.3744e-01 6.1979e-03 1.8884e-02 -6.0000e+00 3.9663e-01 9.6821e-02 3.0018e-03 7.0769e-03 -6.0000e+00 1.7026e-01 2.4297e-04 -9.7977e-04 7.8242e-05 9.1117e-05 -6.0000e+00 1.1671e-02 9.7874e-03 -1.6591e-04 12 8 8 10 0 0 35.06 21.03 0.60 0.00979 0.00243 107 25 1 5 0 452.420 26.00 19.93 21.03 18.14 5.3 967.80 -167164 -130045 -152261 -133512 -138961 -169164 -120237 -125589 -130971 -119829 -128240 -126971 -91549 -85181 -49870 -57312 -53967 -39833 -18103 -1428 -23280 -21748 -5894 -36493 608 -28686 -1905 -29849 -28202 -22942 -9400 -3412 13387 1978 -5260 4427 -5639 422 113 -765 6996 6666 886 12613 5118 11145 3779 12471 6753 2748 7218 11179 9679 7997 7422 5162 4790 3005 4235 2387 3341 3309 5615 4690 4148 2920 2731 2912 1772 3544 825 238 -310 704 -328 -823 -1367 -2985 -2011 -1281 -1178 -1031 -2788 -2294 -929 -689 315 524 262 314 77 477 -933 -1295 -412 -1034 -195 342 234 -355 -996 -1497 -1444 -756 -1248 -1393 -691 -1113 -249 167 190 623 220 373 510 156 -8 269 -12 44 168 434 698 399 853 414 128 957 395 229 410 168 -160 -40 -136 -233 -241 79 116 -172 69 -304 -593 -2797 -1819 -2924 -2124 -2135 -3295 -1484 -1826 -2264 -2005 -2428 -2578 -1607 -1823 -958 -1447 -1510 -1071 -427 -30 -632 -579 -136 -1221 15 -1015 -53 -1073 -975 -787 -328 -136 529 97 -271 199 -297 24 8 -66 639 664 90 1298 525 1211 412 1413 768 345 952 1592 1545 1412 1405 1043 1003 644 875 491 694 748 1413 1353 1299 920 837 902 603 1366 367 103 -136 318 -138 -313 -480 -1054 -769 -576 -573 -577 -1762 -1540 -656 -520 249 430 217 253 59 337 -635 -892 -310 -907 -182 365 278 -435 -1170 -1596 -1396 -715 -1270 -1520 -789 -1363 -330 229 291 1019 367 603 780 229 -11 408 -20 74 287 718 1108 616 1267 595 177 1342 621 410 757 332 -333 -82 -302 -548 -585 194 287 -414 157 -652 -1224 SS 20241030T123954.7Z 9069.527716 107 1 48.53 2 78.92 118.47 60.87 130.28 0.00 1 0.00 1 0 17 2.552e-01 7.088e-03 3.058e-02 1.463e-03 5.499652e-01 7.519085e-04 6.314493e-03 -6.000000e+00 1.440701e-01 224.86 -2.00 3.47 -2.00 320.37 0.00e+00 2.432712e-03 2.816442e-04 7.247325e-04 -6.000000e+00 6.433593e-03 283.32 -2.00 20.00 -2.00 319.74 0.00e+00 5.018 0.002 302.00 328.00 3 1.0932e+00 2.2771e-03 5.6805e-02 -6.0000e+00 3.5560e-01 2.8666e-02 2.8528e-03 2.8422e-02 -6.0000e+00 3.8647e-01 -8.1998e-02 2.5877e-03 1.4755e-02 -6.0000e+00 2.3088e-01 2.9378e-02 1.3118e-03 4.9724e-03 -6.0000e+00 9.9125e-02 7.3431e-04 -7.2961e-04 4.0973e-05 5.4822e-05 -6.0000e+00 6.7923e-03 9.0442e-03 -1.5237e-04 11 9 0 11 8 0 9.48 21.12 0.46 0.00904 0.00356 203 48 1 5 0 239.050 26.00 19.96 21.12 19.01 5.3 972.93 -84386 -86474 -75433 -72501 -102708 -93152 -89371 -85234 -78838 -72774 -59962 -78386 -42616 -47857 -22475 -14403 -22843 -11834 -15150 -3378 -15409 -8315 -10372 -13189 -8763 -12417 -3460 -11305 -9999 -12137 -7380 -572 -138 -3140 -4068 -6299 -5197 -2501 -550 -709 3015 1878 -1620 2185 2822 4369 2467 3526 1696 1214 3288 2516 3165 3386 2905 2734 2305 905 732 536 1914 2311 2923 2739 2100 984 996 327 831 1539 456 346 306 417 -135 -966 -1235 -1868 -1521 -1112 -1317 -1249 -2199 -1911 -992 -537 -7 159 500 471 636 705 -343 20 21 101 23 305 115 -201 -279 -1096 -926 -492 -498 -1463 -751 -624 -43 334 339 426 433 466 206 148 217 32 128 -79 -358 205 282 355 194 429 12 817 498 210 256 3 -76 -44 -16 -228 -232 24 5 -88 94 -208 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