File name: Pandora32s1_GreenbeltMD_20241225_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20241226T051203.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora32_OF_v1d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20241225_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241225T164334.1Z 9125.696922 350 1 49.55 2 62.61 173.74 77.41 236.87 0.00 1 0.00 1 0 17 1.876e-02 6.141e-03 7.246e-03 2.222e-03 2.827791e-01 1.102865e-03 3.394639e-03 -6.000000e+00 1.055379e-02 223.39 -2.00 3.47 -2.00 317.30 0.00e+00 6.946542e-04 1.589160e-04 6.229699e-05 -6.000000e+00 4.622319e-04 277.66 -2.00 20.00 -2.00 316.68 0.00e+00 2.163 0.000 302.00 328.00 3 5.0518e+00 2.8846e-03 2.5561e-02 -6.0000e+00 2.6016e-02 4.4193e-02 3.2500e-03 1.4155e-02 -6.0000e+00 2.8310e-02 -1.0152e-02 1.9824e-03 7.0595e-03 -6.0000e+00 1.6875e-02 1.0178e-03 9.9514e-04 2.1145e-03 -6.0000e+00 7.2449e-03 2.7962e-04 -2.8271e-05 6.2881e-05 2.3196e-05 -6.0000e+00 4.9886e-04 -1.9313e-03 6.3587e-06 10 0 0 10 0 0 99.99 20.98 0.38 -0.00193 -0.00214 24 6 1 5 0 2064.120 26.00 19.91 20.98 13.57 5.4 943.59 8881 -10796 -6578 57 -2346 1329 -3977 -5080 790 -2013 -2490 -4734 2056 -3637 1520 1448 -2308 2487 1105 3374 523 69 3708 -943 1258 659 38 -1788 -661 -535 1126 2250 3020 -319 -3330 -3125 -3128 -1574 -1374 -49 -605 -321 123 -146 -613 -27 -714 184 -7 -434 1394 709 1212 624 505 1402 284 666 267 927 324 831 1790 1491 -38 104 -619 -672 -36 1336 -231 47 -270 103 -76 -585 75 -416 -1025 -786 -1161 -727 -1673 -1895 -1032 -404 310 -253 536 560 123 914 -47 175 999 488 367 488 683 -127 -269 -751 -460 -295 -450 -1303 -776 -428 -205 354 -18 520 86 161 229 -8 360 -50 80 -72 -190 256 356 150 529 194 113 404 754 294 127 -174 -383 262 121 2 -95 -280 254 -185 46 -358 -479 803 -1324 -816 6 -248 125 -399 -567 94 -264 -331 -643 285 -610 278 296 -519 555 260 805 132 17 909 -251 346 191 11 -518 -179 -140 299 639 925 -106 -1102 -983 -1020 -570 -580 -24 -321 -179 70 -85 -358 -16 -415 105 -4 -243 795 431 774 417 349 980 204 478 190 648 231 616 1408 1246 -33 86 -486 -510 -28 1117 -212 45 -261 98 -69 -497 58 -309 -772 -640 -1041 -701 -1721 -2021 -1141 -466 371 -313 663 684 144 1006 -49 174 1016 532 431 615 908 -171 -351 -928 -539 -347 -556 -1697 -1037 -588 -290 521 -28 812 134 240 323 -10 477 -68 113 -106 -287 386 528 218 744 264 149 525 1013 417 188 -263 -588 409 196 4 -162 -486 445 -322 77 -594 -779 SS 20241225T164843.7Z 9125.700505 353 1 22.72 2 62.52 175.07 78.24 237.77 0.00 1 0.00 1 0 17 1.243e-02 5.695e-03 5.524e-03 1.941e-03 2.799045e-01 9.684857e-04 3.354916e-03 -6.000000e+00 6.997729e-03 223.39 -2.00 3.47 -2.00 317.04 0.00e+00 5.436942e-04 1.306502e-04 6.810811e-05 -6.000000e+00 3.069922e-04 277.65 -2.00 20.00 -2.00 316.42 0.00e+00 2.156 0.000 302.00 328.00 3 4.1167e+00 2.5221e-03 2.5400e-02 -6.0000e+00 1.7251e-02 2.7496e-02 2.8356e-03 1.3958e-02 -6.0000e+00 1.8779e-02 -2.7631e-03 1.7100e-03 6.9599e-03 -6.0000e+00 1.1186e-02 -2.5026e-03 8.5147e-04 2.0583e-03 -6.0000e+00 4.8364e-03 7.3018e-04 3.5546e-04 5.4914e-05 2.2741e-05 -6.0000e+00 3.3330e-04 -2.9424e-03 9.7606e-05 12 1 1 12 1 1 99.98 21.05 0.25 -0.00294 -0.00027 22 11 1 5 0 987.440 26.00 19.98 21.05 13.94 5.4 945.33 900000 -3313 -567 -4711 -3653 -6599 1818 -2321 981 -833 -4556 -673 -1541 -205 936 10 -570 -265 1680 1865 1278 -338 467 794 53 1021 401 -816 -839 -1492 1233 266 3099 657 -3279 -2107 -1742 -1375 -522 533 -955 -366 -621 -245 384 486 -968 -16 -133 -544 536 1337 771 951 806 702 791 -9 223 -242 1013 1218 1227 1257 185 -25 13 -416 -16 997 235 109 -22 60 -27 58 -671 -475 -833 -443 -1293 -1414 -1519 -1428 -1099 -659 -15 -306 349 575 341 908 139 158 720 155 629 429 747 -523 -269 -971 -526 222 -711 -931 -751 -615 -171 523 239 318 216 213 143 131 485 185 308 3 -473 49 355 167 418 370 -77 807 386 247 90 -147 -105 -18 80 -144 -151 155 38 -264 86 -93 -703 900000 -424 -74 -629 -440 -751 195 -284 131 -122 -694 -99 -247 -37 191 2 -139 -67 433 495 351 -94 130 228 16 323 129 -257 -249 -432 359 84 1032 235 -1179 -716 -610 -536 -234 271 -536 -215 -374 -149 233 295 -592 -9 -79 -321 323 847 514 660 577 511 586 -7 164 -177 742 929 995 1076 163 -21 11 -325 -13 855 219 105 -21 57 -25 50 -542 -365 -646 -369 -1180 -1387 -1573 -1525 -1217 -761 -18 -377 431 700 400 1004 145 160 739 169 736 536 982 -699 -348 -1196 -617 260 -876 -1199 -994 -837 -240 756 359 488 328 312 199 175 637 249 429 4 -705 72 518 239 582 501 -101 1041 517 347 131 -219 -158 -28 128 -236 -253 261 65 -448 142 -150 -1122 SS 20241225T165317.6Z 9125.703676 356 1 7.42 2 62.45 176.25 78.99 238.56 0.00 1 0.00 1 0 17 1.214e-02 6.368e-03 9.665e-03 3.565e-03 2.796037e-01 1.775049e-03 3.364839e-03 -6.000000e+00 6.829930e-03 223.39 -2.00 3.47 -2.00 316.84 0.00e+00 2.841842e-04 2.280921e-04 1.146171e-04 -6.000000e+00 2.990576e-04 277.65 -2.00 20.00 -2.00 316.23 0.00e+00 2.151 0.000 302.00 328.00 3 4.0949e+00 4.6073e-03 2.5353e-02 -6.0000e+00 1.6837e-02 2.6108e-02 5.1756e-03 1.3932e-02 -6.0000e+00 1.8320e-02 -3.6951e-03 3.0864e-03 6.9509e-03 -6.0000e+00 1.0920e-02 -1.0297e-03 1.5164e-03 2.0120e-03 -6.0000e+00 4.6892e-03 7.4643e-04 1.6008e-04 1.0001e-04 2.2809e-05 -6.0000e+00 3.2276e-04 -2.7613e-03 2.8351e-05 12 1 1 12 9 1 97.68 21.05 0.31 -0.00276 -0.00156 4 8 1 5 0 1483.330 26.00 19.61 21.05 14.13 5.3 945.74 4005 -3695 -472 -1553 -2404 -3743 -722 -22 -3504 -2003 -2484 -4230 -714 -1291 1244 -368 3 47 2001 493 1060 -13 1893 -670 557 -856 707 -993 -844 -1252 3296 613 3478 -857 -2854 -1860 -1598 -1749 -982 320 -1138 -633 135 -203 -775 555 218 -116 -368 -877 709 702 592 1118 13 1057 1660 202 790 489 921 1468 1590 2040 554 -217 85 -576 -497 724 -107 514 113 -82 -334 -228 -166 -1014 -1234 -569 -689 -1545 -1523 -1718 -840 -1105 -102 -176 -147 258 46 1063 84 753 375 218 516 472 651 -610 -412 -890 -468 43 -349 -1295 -612 -223 -320 511 136 598 453 387 267 335 619 482 -95 -38 45 -171 25 192 456 220 59 517 795 511 93 -594 -604 -281 396 160 -44 -79 88 -216 -63 -287 -442 470 -523 -68 -221 -314 -457 -87 -3 -537 -325 -408 -707 -125 -258 276 -91 1 13 555 143 314 -4 557 -209 182 -295 243 -336 -270 -389 1014 206 1233 -329 -1087 -672 -595 -726 -466 171 -668 -387 84 -128 -493 350 137 -72 -226 -539 443 462 408 798 10 789 1255 154 596 366 694 1147 1315 1771 495 -189 70 -461 -406 634 -101 501 112 -80 -314 -201 -137 -802 -983 -485 -637 -1537 -1593 -1855 -936 -1287 -123 -217 -183 315 54 1183 89 766 391 241 607 591 855 -815 -533 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