File name: Pandora32s1_GreenbeltMD_20250218_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20250219T054803.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora32_OF_v2d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20250218_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250218T130400.4Z 9180.544449 269 1 21.64 2 78.13 115.50 76.67 234.12 0.00 1 0.00 1 0 17 3.775e-01 1.616e-02 2.318e-01 8.044e-03 6.373651e-01 4.186692e-03 7.339071e-03 -6.000000e+00 2.133229e-01 225.13 -2.00 3.47 -2.00 320.67 0.00e+00 4.567339e-03 1.640777e-03 1.900843e-03 -6.000000e+00 9.285823e-03 276.57 -2.00 20.00 -2.00 320.17 0.00e+00 4.714 0.002 302.00 328.00 3 3.4769e+00 1.2773e-02 5.7032e-02 -6.0000e+00 5.2808e-01 1.9378e-01 1.6309e-02 3.3504e-02 -6.0000e+00 5.7477e-01 -2.3539e-01 1.5784e-02 1.8971e-02 -6.0000e+00 3.4171e-01 9.7387e-02 7.9020e-03 7.4071e-03 -6.0000e+00 1.4670e-01 7.5111e-05 -7.5690e-04 2.1883e-04 9.1853e-05 -6.0000e+00 1.0133e-02 6.8024e-03 -2.3139e-04 12 9 9 12 1 1 88.79 18.76 0.29 0.00680 0.00111 6 4 1 5 0 3091.160 24.14 20.33 18.76 -1.06 5.2 857.52 900000 -91175 -152978 -133575 -124573 -97847 -42159 -125902 -9928 -102733 -30041 -153027 109673 -65106 -15630 -39791 -91704 23860 -31815 104789 22884 -55768 98852 -9165 57385 -19124 -1148 422 -39050 38134 -8427 -6915 15632 -4895 -3719 -39704 -3180 -20047 9664 -2368 296 16823 14134 20610 4007 15473 25561 5039 12956 6922 9436 2399 12352 14633 2186 17648 -926 194 -901 -5160 13347 -4310 6076 967 3779 5818 1552 7937 -542 3791 -1050 866 2105 995 1626 -7689 3115 -4009 -7701 -1038 -3499 2286 -3512 -640 -2155 -688 -1094 -857 1647 -1322 -1285 2546 419 576 28 109 259 -88 1631 -1630 764 -2285 -1723 -1591 -1053 -334 -1117 -397 -787 537 -380 67 560 -609 753 -647 101 449 664 512 16 1033 1272 -260 2079 46 743 -163 701 53 86 149 150 -129 -292 4 -17 -790 640 147 -408 -444 -494 900000 -1245 -4068 -2957 -2332 -1340 -352 -2563 -78 -2025 -310 -5410 860 -1577 -299 -1148 -4890 474 -1155 1111 540 -2723 1149 -312 1126 -809 -42 15 -1947 964 -380 -367 782 -324 -239 -3439 -206 -1760 775 -253 35 1834 1660 2351 542 1918 2950 723 1796 1070 1558 471 2416 3029 538 3910 -251 52 -238 -1385 3073 -1260 1815 340 1385 2081 561 2740 -217 1656 -530 451 1087 497 750 -3496 1188 -1617 -3471 -512 -2039 1429 -2521 -473 -1701 -566 -945 -762 1439 -1158 -1068 1931 309 427 23 100 265 -101 2003 -2093 926 -2609 -1805 -1648 -1143 -380 -1331 -494 -1049 771 -595 110 926 -993 1168 -976 151 687 1060 849 28 1671 1995 -402 3074 67 1045 -235 1083 91 158 284 297 -266 -631 9 -38 -1828 1473 332 -890 -926 -1000 SS 20250218T130904.6Z 9180.547969 272 1 13.50 2 77.25 116.39 77.47 235.02 0.00 1 0.00 1 0 25 2.711e-01 9.821e-03 1.410e-01 4.982e-03 6.115850e-01 2.564355e-03 7.036855e-03 -6.000000e+00 1.531286e-01 225.13 -2.00 3.47 -2.00 320.33 0.00e+00 1.962849e-03 9.169414e-04 1.349908e-03 -6.000000e+00 6.644438e-03 276.57 -2.00 20.00 -2.00 319.81 0.00e+00 4.410 0.001 302.00 328.00 3 2.6579e+00 7.5608e-03 5.3722e-02 -6.0000e+00 3.7907e-01 1.1748e-01 9.4311e-03 3.1979e-02 -6.0000e+00 4.1243e-01 -1.3728e-01 8.9214e-03 1.6742e-02 -6.0000e+00 2.4534e-01 5.3099e-02 4.5558e-03 5.2583e-03 -6.0000e+00 1.0459e-01 2.3790e-04 -8.5690e-04 1.3501e-04 6.2696e-05 -6.0000e+00 7.2171e-03 7.6937e-03 -2.7880e-04 12 9 9 12 1 1 68.95 18.76 0.56 0.00769 0.00125 11 10 1 5 0 1124.910 24.14 19.77 18.76 -1.04 5.2 857.83 -61738 -143941 -10518 -129159 -5198 -94280 -48751 -112413 -91687 -27245 -102255 -79210 -21074 -32483 20280 -36140 -13948 -32219 2557 5105 -23943 -9668 -34108 -20094 -7879 -2530 4293 -16381 -18596 -17979 8570 -2527 -3349 4081 -18132 -7203 -5223 -4809 -3097 2848 7948 -6421 6824 1735 4126 7185 -1308 8528 464 1744 4020 1985 7155 3817 4361 2967 2257 1223 973 3796 1587 4288 851 2980 1977 1319 2950 216 1231 1077 1543 1499 -1215 1441 -3071 -1445 -898 -3154 -1530 -2271 -413 -817 -2142 -1357 -1418 -655 555 -209 407 -708 485 455 603 -599 -761 -484 460 707 593 -67 -485 -1000 -1275 -347 -982 -1768 -430 -930 -410 472 244 890 -232 611 -19 576 665 41 590 -477 -126 183 989 735 83 794 107 293 1048 -70 250 -619 62 -27 -242 -598 -162 -66 53 204 -187 -93 -149 -570 -3306 -77 -3075 -33 -1374 -474 -2349 -1782 -304 -2534 -1693 -307 -679 315 -1194 -420 -1284 78 161 -1047 -366 -1537 -937 -356 -116 188 -860 -967 -961 404 -145 -226 281 -1530 -525 -397 -427 -332 348 1057 -1069 1049 289 678 1165 -235 1424 87 341 843 476 1795 1076 1194 860 682 375 291 1076 467 1328 309 1195 858 569 1209 92 561 566 833 856 -714 786 -1748 -726 -410 -1451 -752 -1320 -256 -582 -1709 -1143 -1180 -578 511 -201 390 -666 422 397 496 -500 -648 -473 513 840 779 -85 -622 -1163 -1442 -383 -1090 -2108 -531 -1227 -547 696 376 1453 -386 977 -29 874 998 64 918 -789 -209 292 1597 1151 125 1148 150 414 1627 -116 458 -1149 120 -55 -499 -1310 -362 -143 114 449 -391 -191 -296 SS 20250218T131426.2Z 9180.551692 275 1 48.55 2 76.32 117.34 78.32 235.96 0.00 1 0.00 1 0 25 1.997e-01 6.396e-03 2.349e-02 1.236e-03 5.715269e-01 6.301595e-04 6.525485e-03 -6.000000e+00 1.127782e-01 225.13 -2.00 3.47 -2.00 319.96 0.00e+00 2.359641e-03 2.020347e-04 5.694479e-04 -6.000000e+00 4.893634e-03 276.57 -2.00 20.00 -2.00 319.41 0.00e+00 4.130 0.001 302.00 328.00 3 1.6703e+00 1.8078e-03 5.0004e-02 -6.0000e+00 2.7918e-01 7.1626e-02 2.1946e-03 2.9170e-02 -6.0000e+00 3.0373e-01 -7.2386e-02 1.9894e-03 1.5220e-02 -6.0000e+00 1.8068e-01 2.1742e-02 1.0348e-03 5.3007e-03 -6.0000e+00 7.7040e-02 8.7444e-04 -5.2756e-04 3.3606e-05 5.4874e-05 -6.0000e+00 5.3138e-03 7.9351e-03 -2.2458e-04 10 0 0 10 0 0 99.50 18.80 0.31 0.00794 0.00397 141 33 1 5 0 344.250 24.14 20.77 18.80 -1.01 5.2 858.06 -69517 -72341 -66634 -61798 -65889 -79167 -74203 -67392 -62616 -46745 -46737 -51006 -41985 -28063 -14095 -17548 -15951 -10739 -8297 -1133 -8665 -7751 -4174 -7720 -5840 -6689 -9432 -9929 -9140 -10667 -926 -3084 1779 -2904 -3812 -3495 -3653 45 -126 1368 961 275 -335 2211 2047 2286 1251 1125 1212 432 2017 1943 2425 2571 1148 2434 1300 230 -66 -500 827 1967 2414 2865 1521 501 492 272 541 1400 862 620 174 88 -169 -1092 -997 -2107 -2033 -1157 -1172 -900 -1701 -1912 -890 -618 3 163 289 657 589 928 -234 100 80 112 132 437 286 -391 -164 -1005 -798 33 -550 -1135 -713 -660 -67 386 272 187 264 262 86 294 269 150 61 57 -113 277 428 214 442 352 -243 789 215 136 74 -209 -277 43 22 -58 -215 87 27 -18 11 -143 -374 -955 -1229 -1172 -1035 -1056 -1374 -1288 -1243 -1260 -879 -918 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