File name: Pandora32s1_GreenbeltMD_20250226_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20250227T052625.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora32_OF_v2d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20250226_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250226T121610.6Z 9188.511234 47 1 48.44 2 84.68 105.47 79.76 125.49 0.00 1 0.00 1 0 17 5.837e-01 4.546e-02 2.615e-01 2.514e-02 1.022926e+00 1.387597e-02 1.129831e-02 -6.000000e+00 3.305728e-01 225.52 -2.00 3.47 -2.00 321.77 0.00e+00 -1.987147e-02 3.875192e-03 5.764322e-03 -6.000000e+00 1.434313e-02 277.04 -2.00 20.00 -2.00 321.24 0.00e+00 9.386 0.014 302.00 328.00 3 4.5803e-01 4.2548e-02 1.1653e-01 -6.0000e+00 8.1893e-01 2.0354e+00 4.9419e-02 8.8367e-02 -6.0000e+00 8.9026e-01 -2.4314e+00 2.8077e-02 2.5463e-02 -6.0000e+00 5.2959e-01 9.0941e-01 1.6996e-02 2.0434e-02 -6.0000e+00 2.2598e-01 1.0907e-05 5.8312e-04 6.2033e-04 2.2022e-04 -6.0000e+00 1.5530e-02 3.3513e-03 -8.6232e-05 12 8 8 10 0 0 31.96 20.26 2.65 0.00335 0.00773 22 5 1 5 0 2201.570 25.39 19.81 20.26 12.76 5.5 940.33 253315 67819 4988 23970 -2425 -28872 -4200 -12141 9185 -25700 -1442 -36111 63952 -2221 45883 17831 -26572 9986 -5770 30468 -9531 -20905 35411 -25004 83420 14443 63016 29525 -42708 4019 -1289 -45237 377841 -5104 -12552 -43533 15034 -8234 -15568 42205 35816 199426 59988 246238 25138 116784 104253 42577 55158 12032 41862 7539 99006 69934 2154 130579 12285 34741 59450 50128 60395 -50836 -12310 11732 44594 34210 90089 81963 11550 73147 16535 1919 37801 21065 -7184 -29217 39051 -13659 -24700 -8627 -9686 35298 -12214 5063 31289 5139 34220 5207 13151 2224 -11790 10598 -7144 3912 2314 12420 -2915 6402 5255 -10932 970 -11283 -12652 -12918 -10775 -901 -1353 -4928 -5311 1985 -2672 2035 1350 -434 1571 -1566 -458 496 1999 1771 1190 2562 5417 2263 516 -294 2253 -620 -727 1731 -198 3475 -1851 1234 -973 635 -993 -3155 1595 1026 1251 -853 -1221 6210 7557 934 3045 -308 -3989 -449 -1542 1023 -4181 -180 -6277 4276 -307 4192 2265 -5271 1335 -862 2920 -1232 -2702 2525 -3566 4462 1577 3932 2171 -5330 287 -103 -6351 9263 -535 -1287 -5433 1039 -807 -1978 3574 3592 4889 5147 6037 2527 4294 4089 3027 3516 1239 3489 980 5582 5658 364 6402 2018 4429 5392 4424 4442 -11590 -2112 1783 5247 4445 6626 6832 2152 8428 3689 513 6858 4131 -1638 -7163 4404 -2645 -5995 -2136 -2897 7875 -4941 1849 9281 2079 10738 2221 5094 916 -5203 3533 -2820 1477 1027 5937 -1923 4488 4187 -10586 792 -9266 -9305 -9184 -7951 -643 -1025 -4192 -5117 2088 -3439 2544 1796 -593 2058 -2059 -657 736 2802 2569 1695 3730 7277 3062 694 -389 2828 -846 -1162 2924 -391 7318 -4451 3126 -2732 1864 -3028 -9906 4739 2926 3272 -2073 -2807 SS 20250226T122842.5Z 9188.519937 50 1 48.83 2 82.34 107.51 77.83 127.66 0.00 1 0.00 1 0 17 5.583e-01 1.852e-02 1.059e-01 4.246e-03 8.591989e-01 2.318174e-03 9.494223e-03 -6.000000e+00 3.160828e-01 225.52 -2.00 3.47 -2.00 321.81 0.00e+00 7.995802e-03 1.209687e-03 1.970643e-03 -6.000000e+00 1.371722e-02 277.04 -2.00 20.00 -2.00 321.35 0.00e+00 6.980 0.006 302.00 328.00 3 5.5353e-01 8.2204e-03 8.2592e-02 -6.0000e+00 7.8303e-01 6.3657e-01 1.1475e-02 4.6855e-02 -6.0000e+00 8.5132e-01 -9.1329e-01 1.1391e-02 2.6671e-02 -6.0000e+00 5.0642e-01 3.7991e-01 5.3355e-03 1.1612e-02 -6.0000e+00 2.1603e-01 1.3271e-04 -1.3801e-03 1.1013e-04 1.5716e-04 -6.0000e+00 1.4856e-02 4.1092e-03 -1.3877e-04 12 8 8 10 0 0 6.58 20.36 0.73 0.00411 -0.00626 103 24 1 5 0 474.010 25.39 19.72 20.36 13.31 5.5 943.82 -145677 -142388 -132456 -146639 -150228 -211350 -145906 -196712 -170626 -149690 -195136 -172853 -164078 -109424 -68039 -61055 -40570 -61840 -51560 -22401 -20676 -60790 -23311 -50669 -57991 -45467 -41050 -32538 -25495 -46934 -4277 -35125 53107 -2659 4606 10533 3156 13233 1309 38772 35956 32946 7447 30098 41029 21362 23382 42652 16398 16139 19515 34481 32069 27598 27419 17762 24585 14069 14554 13732 16808 18048 13177 19712 10861 14481 13782 9922 12546 12528 8875 7259 8777 9717 1071 -40 -3878 895 -4169 -2397 2122 1071 -131 -1070 1505 -1141 274 803 -836 459 -924 1269 -2736 -2809 -2555 -3068 -1873 -1961 -1310 -1319 -1390 -1551 -3308 -1336 -2508 -2610 -1522 -2632 -1096 -1161 -441 37 -227 332 -91 -307 -374 4 347 392 1204 1239 2229 1586 1336 1590 679 1072 644 678 767 577 352 161 -77 -275 55 168 -122 -252 -392 -555 -1334 -1974 -2251 -2044 -2539 -2375 -5490 -2115 -4517 -3533 -2603 -4922 -4152 -4552 -2356 -1268 -1315 -823 -1716 -1388 -464 -420 -1762 -454 -1343 -1729 -1224 -1054 -741 -528 -1283 -92 -1295 968 -94 147 297 98 422 56 1365 1474 1501 459 1521 1869 1203 1326 2084 1107 1176 1527 2627 2775 2720 2884 2133 2820 1777 1754 1598 1900 2182 1926 3134 1901 2491 2371 1834 2475 2853 2349 2058 2435 2509 273 -9 -847 189 -1042 -715 730 436 -61 -538 782 -647 162 487 -517 273 -523 660 -1434 -1526 -1571 -2069 -1485 -1826 -1372 -1440 -1454 -1456 -2800 -1064 -2135 -2379 -1449 -2730 -1243 -1518 -607 56 -359 518 -138 -448 -545 5 556 654 1975 1937 3280 2280 1869 2151 971 1577 1004 1239 1475 1214 791 390 -188 -710 145 449 -325 -653 -1012 -1321 -3022 SS 20250226T123931.6Z 9188.527448 53 1 48.50 2 80.34 109.32 76.21 129.59 0.00 1 0.00 1 0 25 5.725e-01 1.063e-02 5.736e-02 1.746e-03 7.390478e-01 9.252251e-04 8.250869e-03 -6.000000e+00 3.242315e-01 225.52 -2.00 3.47 -2.00 321.18 0.00e+00 4.755391e-03 4.254065e-04 1.416222e-03 -6.000000e+00 1.406904e-02 277.04 -2.00 20.00 -2.00 320.70 0.00e+00 5.691 0.003 302.00 328.00 3 4.8650e-01 3.0096e-03 6.8076e-02 -6.0000e+00 8.0322e-01 1.6594e-01 4.1902e-03 3.9461e-02 -6.0000e+00 8.7321e-01 -2.4411e-01 4.4573e-03 2.2536e-02 -6.0000e+00 5.1944e-01 9.8427e-02 2.1426e-03 9.0820e-03 -6.0000e+00 2.2164e-01 5.6241e-04 -8.4466e-04 4.5993e-05 1.0371e-04 -6.0000e+00 1.5234e-02 2.9946e-03 -1.2325e-04 12 8 8 10 0 0 -2.09 20.45 0.44 0.00299 -0.00335 232 54 1 5 0 209.040 25.47 20.10 20.45 14.03 5.5 947.38 -169168 -180889 -193300 -172311 -216475 -167766 -197660 -173768 -139879 -173078 -149228 -192019 -127434 -86114 -80412 -56610 -82520 -43413 -64846 -19659 -43039 -40708 -33686 -56986 -24907 -43734 -21800 -35193 -39825 -30928 -35550 -17104 710 -5693 -2677 -14680 -8482 -11541 -2835 3082 6382 8217 -1665 10184 4414 5950 7626 4715 7859 228 6893 7234 9594 11283 6581 7025 3823 4207 3011 3420 4859 3522 6876 4598 5686 4560 4170 3380 2114 4608 2067 2286 1983 1504 408 -1317 -1155 -2688 -1615 -735 -1220 -942 -2784 -1814 -1602 -698 45 -239 141 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