File name: Pandora32s1_GreenbeltMD_20250709_L2Fit_fwvt1c12d20221109p1-8.txt
File generation date: 20250710T052205.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c12p1-8
Local principal investigator: Thomas Hanisco
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 32
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora32_OF_v2d20220415.txt
Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt
Level 1 file used: Pandora32s1_GreenbeltMD_20250709_L1_smca1c12d20221109p1-8.txt
Full location name: Goddard Space Flight Center
Short location name: GreenbeltMD
Country of location: USA
Location latitude [deg]: 38.9926
Location longitude [deg]: -76.8396
Location altitude [m]: 90
Local noon date: 20250709
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 11 with new SO2 and HCHO field cal
First and last pixel inside fitting window: 1680 1830
Nominal wavelengths inside fitting window [nm]: 492.0337 492.1546 492.2756 492.3965 492.5174 492.6382 492.7591 492.8799 493.0008 493.1216 493.2424 493.3631 493.4839 493.6046 493.7254 493.8461 493.9668 494.0874 494.2081 494.3287 494.4493 494.5700 494.6905 494.8111 494.9317 495.0522 495.1727 495.2933 495.4137 495.5342 495.6547 495.7751 495.8955 496.0159 496.1363 496.2567 496.3771 496.4974 496.6177 496.7380 496.8583 496.9786 497.0989 497.2191 497.3393 497.4595 497.5797 497.6999 497.8201 497.9402 498.0603 498.1804 498.3005 498.4206 498.5406 498.6607 498.7807 498.9007 499.0207 499.1407 499.2606 499.3806 499.5005 499.6204 499.7403 499.8602 499.9800 500.0999 500.2197 500.3395 500.4593 500.5790 500.6988 500.8185 500.9383 501.0580 501.1776 501.2973 501.4170 501.5366 501.6562 501.7758 501.8954 502.0150 502.1345 502.2541 502.3736 502.4931 502.6126 502.7321 502.8515 502.9709 503.0904 503.2098 503.3291 503.4485 503.5679 503.6872 503.8065 503.9258 504.0451 504.1644 504.2836 504.4028 504.5221 504.6413 504.7604 504.8796 504.9988 505.1179 505.2370 505.3561 505.4752 505.5942 505.7133 505.8323 505.9513 506.0703 506.1893 506.3083 506.4272 506.5462 506.6651 506.7840 506.9028 507.0217 507.1405 507.2594 507.3782 507.4970 507.6157 507.7345 507.8533 507.9720 508.0907 508.2094 508.3281 508.4467 508.5653 508.6840 508.8026 508.9212 509.0397 509.1583 509.2768 509.3954 509.5139 509.6324 509.7508 509.8693 509.9877
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250709T102251.0Z 9321.432535 165 1 4.82 2 85.21 65.04 112.35 250.20 0.00 1 0.00 1 0 22 3.579e-03 3.553e-03 9.228e-04 9.212e-04 2.411617e+04 7.438743e+01 1.514339e+03 -6.000000e+00 2.120960e+02 289.63 -2.00 20.00 -2.00 505.37 0.00e+00 2.353565e-03 2.648518e-05 1.594673e-04 -6.000000e+00 1.035929e-04 289.63 -2.00 20.00 -2.00 500.64 0.00e+00 8.285360e-01 1.846211e-02 1.360044e-01 -6.000000e+00 7.203226e-02 232.71 -2.00 3.47 -2.00 502.20 0.00e+00 10.100 0.018 489.00 513.00 1 3.9145e+00 1.4210e-03 1.8991e-02 -6.0000e+00 5.5546e-03 -2.8729e-02 3.4870e-04 3.4821e-03 -6.0000e+00 1.4100e-03 8.1813e-03 1.4978e-03 8.7096e-05 1.2983e-04 -6.0000e+00 4.1171e-04 -3.0855e-02 1.2386e-04 12 1 1 12 1 1 11.08 22.40 2.85 -0.03085 -0.02047 10 26 1 4 0 437.960 27.15 19.99 22.40 28.84 6.2 1027.59 -363 -152 -12 145 441 586 750 872 779 691 346 55 -72 -216 -225 -171 -159 -161 230 158 -63 -24 171 182 484 429 278 62 -134 -447 -744 -397 -548 -187 214 53 -386 -83 -150 -98 -102 7 5 20 155 458 340 172 -38 -233 -508 -510 -786 -559 -364 -306 7 -39 235 218 417 343 352 273 216 141 21 -279 -202 -356 -410 -412 -228 -240 -187 -107 -488 -438 -476 -315 -453 -219 -395 -287 -126 -321 -453 -181 21 90 167 205 377 259 298 275 173 18 -311 -666 -651 -535 -741 -444 -462 -214 -315 -374 -200 -46 201 67 97 224 610 861 785 744 310 219 -13 169 131 543 453 348 447 179 -382 -51 27 -362 -246 -104 -79 -182 179 98 0 182 277 299 363 325 358 328 62 -246 -373 -225 -251 -345 -143 -12 142 436 583 759 877 787 694 350 55 -72 -212 -223 -167 -157 -160 233 160 -64 -24 176 187 492 438 283 64 -136 -451 -738 -393 -551 -189 218 55 -395 -85 -153 -100 -103 7 5 21 162 478 355 178 -39 -237 -506 -504 -771 -550 -364 -310 7 -40 243 223 426 352 362 282 222 144 22 -281 -204 -356 -407 -410 -228 -238 -187 -107 -490 -432 -470 -308 -442 -214 -389 -281 -125 -316 -448 -181 21 89 165 203 374 254 289 261 160 16 -278 -600 -588 -485 -689 -420 -451 -211 -311 -370 -197 -45 199 67 98 226 614 858 793 751 317 223 -13 169 131 537 449 347 442 178 -381 -50 27 -360 -241 -102 -78 -179 179 99 0 186 283 309 378 340 373 340 64 -250 -381 -229 -258
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SQ 20250709T104452.2Z 9321.447826 171 1 49.12 2 81.28 68.31 116.24 252.97 0.00 1 0.00 1 0 22 2.651e-03 2.641e-03 4.381e-04 4.374e-04 1.548940e+04 3.324991e+01 9.919035e+02 -6.000000e+00 1.570926e+02 289.63 -2.00 20.00 -2.00 505.33 0.00e+00 1.397836e-03 1.251703e-05 1.007772e-04 -6.000000e+00 7.672640e-05 289.63 -2.00 20.00 -2.00 500.56 0.00e+00 5.016410e-01 8.782517e-03 9.405860e-02 -6.000000e+00 5.335201e-02 232.71 -2.00 3.47 -2.00 502.14 0.00e+00 6.224 0.004 489.00 513.00 1 5.4312e+00 6.7646e-04 1.2150e-02 -6.0000e+00 4.1141e-03 -1.8968e-02 1.6748e-04 2.3377e-03 -6.0000e+00 1.0444e-03 3.2726e-03 8.3440e-04 4.4579e-05 8.5949e-05 -6.0000e+00 3.0503e-04 1.0821e-02 -1.2782e-04 10 0 0 10 0 0 4.90 22.41 1.98 0.01082 0.01661 42 10 1 4 0 1169.290 27.15 20.00 22.41 29.03 6.2 1028.69 -269 -189 -46 79 263 355 592 649 539 349 195 -7 -40 -244 -155 -92 -83 -128 196 86 18 92 278 307 364 287 131 70 -79 -398 -456 -258 -263 -98 93 -35 -234 -127 -66 -130 -38 25 89 226 193 302 198 85 -7 -187 -325 -504 -485 -451 -246 -159 -114 -22 66 85 236 266 174 235 258 167 -13 -57 -234 -232 -262 -304 -269 -241 -179 -144 -321 -306 -248 -245 -286 -302 -276 -280 -337 -191 -270 -260 -110 106 85 146 200 289 122 167 135 -134 -235 -431 -404 -462 -547 -352 -379 -360 -399 -223 -151 46 156 -14 228 336 471 635 610 608 334 226 202 217 276 408 353 203 190 75 -119 77 66 -124 -59 27 -34 32 52 5 -35 130 174 141 234 294 71 41 74 -193 -277 -228 -279 -258 -183 -45 78 261 361 603 667 556 358 198 -7 -40 -244 -153 -92 -84 -129 202 89 19 95 289 320 381 296 134 73 -81 -403 -453 -256 -264 -100 95 -37 -243 -131 -68 -134 -39 25 92 234 200 313 205 88 -7 -191 -324 -501 -476 -443 -246 -160 -116 -22 67 87 240 272 179 241 263 172 -13 -57 -235 -231 -259 -300 -267 -242 -178 -143 -320 -300 -240 -240 -279 -296 -268 -274 -335 -188 -267 -257 -109 104 83 144 199 285 118 160 127 -125 -218 -395 -370 -423 -510 -337 -371 -355 -396 -220 -148 46 155 -14 229 334 470 637 617 611 338 227 203 215 274 402 349 202 190 74 -117 77 65 -121 -57 26 -33 31 51 5 -35 131 175 144 239 302 73 42 75 -195 -277 -227 -279
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