File name: Pandora32s1_GreenbeltMD_20250722_L2Fit_fout2c12d20221109p1-8.txt File generation date: 20250723T052830.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 32 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora32_OF_v2d20220415.txt Instrument calibration file used: Pandora32s1_CF_v12d20221109.txt Level 1 file used: Pandora32s1_GreenbeltMD_20250722_L1_smca1c12d20221109p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 with new SO2 and HCHO field cal First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0059 305.1469 305.2878 305.4288 305.5697 305.7106 305.8515 305.9924 306.1333 306.2742 306.4150 306.5559 306.6967 306.8375 306.9783 307.1191 307.2599 307.4007 307.5415 307.6822 307.8230 307.9637 308.1044 308.2451 308.3858 308.5265 308.6672 308.8079 308.9485 309.0892 309.2298 309.3704 309.5110 309.6516 309.7922 309.9328 310.0733 310.2139 310.3544 310.4950 310.6355 310.7760 310.9165 311.0570 311.1974 311.3379 311.4784 311.6188 311.7592 311.8996 312.0400 312.1804 312.3208 312.4612 312.6015 312.7419 312.8822 313.0226 313.1629 313.3032 313.4435 313.5837 313.7240 313.8643 314.0045 314.1447 314.2849 314.4252 314.5654 314.7055 314.8457 314.9859 315.1260 315.2662 315.4063 315.5464 315.6865 315.8266 315.9667 316.1068 316.2468 316.3869 316.5269 316.6669 316.8070 316.9470 317.0869 317.2269 317.3669 317.5069 317.6468 317.7867 317.9266 318.0666 318.2065 318.3463 318.4862 318.6261 318.7659 318.9058 319.0456 319.1854 319.3252 319.4650 319.6048 319.7446 319.8843 320.0241 320.1638 320.3035 320.4432 320.5829 320.7226 320.8623 321.0020 321.1416 321.2813 321.4209 321.5605 321.7001 321.8397 321.9793 322.1189 322.2584 322.3980 322.5375 322.6770 322.8165 322.9560 323.0955 323.2350 323.3745 323.5139 323.6534 323.7928 323.9322 324.0716 324.2110 324.3504 324.4898 324.6291 324.7685 324.9078 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250722T105622.6Z 9334.455818 141 1 47.67 2 80.72 71.51 51.84 82.27 0.00 1 0.00 1 0 25 4.335e-01 2.288e-02 1.896e-01 8.176e-03 7.224814e-01 4.529515e-03 9.081062e-03 -6.000000e+00 2.537265e-01 232.46 -2.00 3.47 -2.00 321.43 0.00e+00 6.957515e-03 2.202487e-03 6.946637e-03 -6.000000e+00 1.137856e-02 290.38 -2.00 20.00 -2.00 320.81 0.00e+00 5.889 0.004 302.00 328.00 3 2.7985e+00 1.5967e-02 7.6780e-02 -6.0000e+00 6.3590e-01 5.7070e-01 2.0407e-02 5.4896e-02 -6.0000e+00 6.8690e-01 -8.2574e-01 1.6303e-02 2.3746e-02 -6.0000e+00 4.0792e-01 3.4294e-01 7.9123e-03 5.4837e-03 -6.0000e+00 1.7400e-01 4.2991e-05 -1.3495e-03 2.2227e-04 1.3662e-04 -6.0000e+00 1.1749e-02 6.8637e-03 -1.5163e-04 12 8 8 10 0 0 31.66 21.59 1.38 0.00686 -0.00328 21 5 1 5 0 2269.470 26.41 20.00 21.59 24.22 6.3 1001.55 900000 -133959 -108504 -98396 -150571 -130556 900000 -55986 -127893 -108265 -122760 -139666 25232 -96078 29810 -28660 -34039 3208 -16257 81005 1599 -19933 46981 -17432 119206 -31716 146724 -31673 68927 -39165 -39599 8625 84020 28358 -18785 -4551 -17806 -20912 44565 35896 50090 38230 42291 48977 23390 66719 53955 61193 19780 17260 12115 39139 27001 12902 24478 17952 20927 19173 6699 16288 5109 16286 13458 12248 5568 4086 8869 5235 2243 10808 6282 2319 3838 6898 1400 -3706 -8069 -3860 -1669 138 -785 -1759 -339 -1786 433 -788 -427 7 -845 1164 -45 3697 -2400 -5584 -3065 -7925 -4240 -494 -489 -1542 -2620 -3215 -2305 -2064 -3138 -2551 -1991 127 -1173 -857 566 1081 -32 45 1273 455 593 -107 1289 277 630 1578 2759 1076 745 2113 -461 1160 390 1667 483 426 342 638 62 -187 -296 -801 -52 -347 6 -1013 -900 900000 -5436 -3617 -2852 -6437 -4068 900000 -937 -4263 -3060 -4003 -5667 261 -3899 475 -982 -1384 97 -635 1227 54 -794 936 -681 1235 -1517 1169 -1439 1099 -1904 -2241 364 1942 1243 -1273 -250 -1150 -1583 2096 2174 2954 2712 3000 3318 2051 3829 3569 3853 1955 1843 1487 4087 3486 2067 3687 2976 3436 3179 1212 2583 912 2804 2703 2831 1491 1107 2227 1381 660 3046 2071 839 1363 2249 440 -1202 -2502 -1138 -530 51 -317 -830 -175 -1003 253 -496 -283 5 -587 771 -28 2095 -1378 -3354 -1994 -6322 -3822 -497 -551 -1665 -2979 -3315 -2118 -1844 -3017 -2612 -2139 143 -1344 -1107 812 1675 -52 71 1890 652 844 -160 2022 461 1050 2512 4156 1598 1072 2896 -624 1575 599 2904 951 834 707 1400 146 -470 -767 -2116 -136 -888 13 -2280 -1924 SS 20250722T110637.3Z 9334.462931 146 1 48.33 2 78.83 73.01 49.93 83.61 0.00 1 0.00 1 0 25 4.025e-01 9.645e-03 8.544e-02 3.376e-03 6.377411e-01 1.808566e-03 7.351405e-03 -6.000000e+00 2.339915e-01 232.46 -2.00 3.47 -2.00 320.88 0.00e+00 3.215563e-03 8.029071e-04 2.463429e-03 -6.000000e+00 1.049750e-02 290.38 -2.00 20.00 -2.00 320.20 0.00e+00 4.978 0.002 302.00 328.00 3 2.4559e+00 5.9748e-03 6.0588e-02 -6.0000e+00 5.8664e-01 8.8966e-02 7.8515e-03 3.6173e-02 -6.0000e+00 6.3342e-01 -1.7027e-01 7.2320e-03 1.8332e-02 -6.0000e+00 3.7743e-01 6.7624e-02 3.5417e-03 5.3077e-03 -6.0000e+00 1.6158e-01 1.6878e-04 -8.0668e-04 9.1859e-05 7.5597e-05 -6.0000e+00 1.0829e-02 6.3531e-03 -1.3478e-04 12 8 8 10 0 0 -24.43 21.65 0.75 0.00635 0.00029 52 12 1 5 0 929.290 26.51 20.01 21.65 24.54 6.3 1003.42 900000 -164802 -124639 -110451 -145873 -151521 -153376 -118124 -133541 -116339 -77056 -125546 -56851 -89125 -58604 -47849 -55034 -10918 -30526 7919 -43459 -40126 -20110 -18380 9376 -24716 6891 -20873 -26267 -19464 -10359 -5421 -1603 5242 -6730 -7990 -12481 -14198 1217 6301 -705 9423 -4196 9649 6483 12575 4170 6785 983 -4294 4890 5991 4164 5707 1747 5823 1142 4255 1379 121 3570 3738 5077 3960 4293 2785 3476 2346 518 2626 2442 1225 206 422 -598 -1386 -1336 -2846 -2845 -1521 -1642 610 -1584 -1466 -293 -160 -799 9 334 929 968 1710 166 -1265 -735 -915 -754 142 -587 -637 -1106 -1467 -623 -573 -1442 -1247 -808 -825 -210 728 165 511 208 388 515 5 492 61 264 61 263 451 539 270 348 231 -70 894 568 121 -41 236 -289 -9 -43 311 -153 -190 -56 16 -35 -336 -435 900000 -2663 -1641 -1272 -2209 -2294 -2474 -1516 -2286 -1838 -862 -2479 -692 -1936 -1196 -1071 -1522 -216 -804 151 -1445 -1294 -543 -526 222 -879 184 -721 -934 -673 -378 -228 -77 259 -370 -429 -744 -918 83 496 -68 899 -486 1008 710 1324 489 798 128 -623 713 972 761 1120 382 1279 273 993 324 28 815 924 1405 1257 1467 960 1153 797 194 1021 1071 577 99 193 -255 -584 -515 -1098 -1194 -681 -869 364 -1072 -1059 -223 -121 -641 8 277 747 732 1295 121 -937 -595 -791 -755 162 -695 -776 -1289 -1670 -637 -576 -1563 -1443 -981 -990 -272 1044 247 818 340 614 769 8 743 97 412 101 437 726 833 434 538 344 -100 1288 911 207 -76 445 -574 -20 -98 696 -355 -448 -132 36 -76 -732 -909 SS 20250722T111237.1Z 9334.467097 149 1 48.48 2 77.71 73.89 48.80 84.42 0.00 1 0.00 1 0 25 2.985e-01 8.105e-03 5.803e-02 2.327e-03 5.934714e-01 1.233001e-03 6.778373e-03 -6.000000e+00 1.734623e-01 232.45 -2.00 3.47 -2.00 320.51 0.00e+00 3.178659e-03 4.847185e-04 1.349152e-03 -6.000000e+00 7.757262e-03 290.38 -2.00 20.00 -2.00 319.78 0.00e+00 4.560 0.002 302.00 328.00 3 2.2678e+00 3.8884e-03 5.5161e-02 -6.0000e+00 4.3490e-01 6.9468e-02 4.9315e-03 3.1765e-02 -6.0000e+00 4.6936e-01 -1.2285e-01 4.3282e-03 1.6405e-02 -6.0000e+00 2.7988e-01 4.5288e-02 2.1708e-03 5.3056e-03 -6.0000e+00 1.1915e-01 3.1360e-04 -8.0534e-04 6.3782e-05 6.2908e-05 -6.0000e+00 7.9615e-03 6.2697e-03 -1.5565e-04 11 8 0 10 0 0 14.81 21.69 0.60 0.00627 0.00022 77 18 1 5 0 629.580 26.51 20.01 21.69 24.70 6.3 1004.44 -49618 -91266 -103430 -101402 -124198 -119516 -64526 -101388 -102279 -77626 -85172 -97899 -54429 -63654 -26377 -16306 -15808 -15673 -16462 -2225 -18713 -17714 -6470 -18391 2154 -17232 -3017 -15453 -11121 -16052 -19645 -7946 8001 -2643 -5724 -8227 -10772 -11288 -7080 -230 3080 1644 -2265 4525 2955 1879 873 7883 2941 -111 1527 3988 3182 4285 3587 3063 3540 353 1324 1502 2386 3317 4353 3114 2744 1338 1447 1063 1239 1832 350 467 -27 555 135 -1027 -478 -1950 -1452 -1369 -1235 -1022 -1775 -1821 -663 -525 -410 99 446 856 416 1012 -318 32 -480 -872 -338 302 13 -528 -499 -1393 -1192 -320 -991 -1331 -822 -337 -29 316 439 417 346 192 271 438 191 126 118 121 -295 188 534 172 358 578 -64 872 432 64 291 56 -195 -10 -88 35 -162 47 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