File name: Pandora71s1_GreenbeltMD_20231023_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20240113T164741.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20231023_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20231023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231023T113441.4Z 8696.482424 33 1 54.28 2 89.00 105.58 158.53 325.50 0.00 1 0.00 1 0 106 1.555e-02 1.529e-02 1.503e-03 1.497e-03 1.104298e+04 9.516766e+01 5.524853e+02 -6.000000e+00 7.973906e+02 284.29 -2.00 20.00 -2.00 505.45 0.00e+00 2.590798e-03 4.071078e-05 2.191482e-05 -6.000000e+00 4.247131e-04 284.29 -2.00 20.00 -2.00 501.02 0.00e+00 1.464526e+00 2.662952e-02 6.366381e-02 -6.000000e+00 2.960303e-01 225.53 -2.00 3.47 -2.00 502.55 0.00e+00 18.629 0.114 489.00 513.00 1 4.7480e+00 2.0461e-03 3.1287e-02 -6.0000e+00 2.2590e-02 -2.4179e-02 4.9628e-04 1.7849e-03 -6.0000e+00 6.0538e-03 1.0525e-03 8.6645e-02 9.9597e-05 4.4427e-05 -6.0000e+00 1.0665e-03 1.7822e-02 2.8638e-04 12 13 8 11 4 0 46.32 27.44 3.24 0.01782 0.61882 16 2 1 2 0 3390.853 19.72 27.44 10.47 26.25 26.00 23.7 930.91 1683 2346 2009 1375 329 981 9 -1515 -1767 -1728 -1532 -1117 914 1482 -291 384 380 95 1460 1466 1533 1966 2388 -2273 -2665 -2118 -2870 -1936 2500 1459 450 263 -390 -906 -1624 -366 -476 598 1134 1727 1685 1558 1365 1636 -851 -2147 -3252 -3825 -2751 -852 642 372 920 -280 -169 83 1066 1393 1237 936 410 -90 -132 -653 -2382 -1776 -878 -941 878 1248 144 -961 -1106 -1537 -2523 -1130 -767 -1979 -1094 -72 97 -539 -951 -1110 -876 -325 1777 3238 2889 1957 2029 1199 72 -1905 -3591 -3915 -3136 -1790 1512 1541 551 -438 -2215 -1664 -836 149 -68 313 814 418 992 2333 2911 1401 1089 185 -702 -746 1089 605 571 1116 724 392 2647 562 -779 -828 -1521 -3041 -1021 -246 -675 -134 916 347 578 1338 1398 2014 1977 558 -1481 -2250 -2234 -1424 -303 1033 743 110 900000 1621 2290 1979 1349 319 939 9 -1438 -1667 -1640 -1465 -1085 860 1428 -284 373 371 93 1429 1449 1511 1926 2325 -2187 -2487 -1979 -2736 -1875 2484 1426 438 267 -375 -910 -1633 -369 -462 584 1120 1720 1678 1540 1334 1574 -812 -2105 -3170 -3719 -2575 -819 633 374 927 -284 -171 84 1084 1417 1259 947 408 -89 -130 -637 -2308 -1708 -850 -920 863 1238 142 -930 -1059 -1465 -2413 -1077 -742 -1933 -1071 -72 96 -541 -949 -1106 -873 -325 1779 3123 2901 1916 1933 1113 66 -1735 -3267 -3581 -2925 -1732 1446 1525 550 -438 -2204 -1630 -830 151 -70 323 842 434 1031 2446 2959 1431 1150 193 -722 -760 1116 629 594 1166 758 409 2748 591 -803 -847 -1570 -3156 -1070 -254 -709 -142 981 377 629 1461 1534 2201 2151 605 -1586 -2386 -2376 -1531 -331 1146 801 123 900000 SQ 20231023T113857.5Z 8696.485388 39 1 54.38 2 88.20 106.26 158.95 327.85 0.00 1 0.00 1 0 92 1.446e-02 1.427e-02 1.031e-03 1.029e-03 8.189573e+03 6.242238e+01 4.393406e+02 -6.000000e+00 7.419857e+02 284.29 -2.00 20.00 -2.00 505.39 0.00e+00 1.985104e-03 2.768968e-05 4.605214e-05 -6.000000e+00 3.951284e-04 284.29 -2.00 20.00 -2.00 500.88 0.00e+00 1.325848e+00 1.821057e-02 6.263652e-02 -6.000000e+00 2.757056e-01 225.53 -2.00 3.47 -2.00 502.43 0.00e+00 16.573 0.080 489.00 513.00 1 4.3254e+00 1.3998e-03 2.6486e-02 -6.0000e+00 2.1032e-02 -1.5512e-02 3.4319e-04 1.5601e-03 -6.0000e+00 5.6449e-03 2.1926e-03 8.8374e-02 6.9190e-05 3.5616e-05 -6.0000e+00 9.8940e-04 3.3252e-02 1.0228e-04 12 13 8 11 4 0 78.49 27.47 2.32 0.03325 0.64625 31 3 1 2 0 1753.839 19.62 27.47 10.51 26.50 26.00 23.7 931.48 1513 1697 1885 1309 147 969 138 -1624 -1591 -1782 -1721 -1513 925 1091 -475 277 251 -138 1333 1391 1632 2037 2251 -2536 -2668 -2012 -2609 -1688 2464 1769 202 523 -71 -841 -1322 -176 -615 689 1022 1669 1524 1524 1252 1625 -576 -1917 -2791 -3648 -2294 -740 473 226 637 -395 -295 77 1142 1054 1224 1003 89 -154 49 -341 -2202 -1503 -707 -808 851 1277 59 -1029 -1027 -1476 -2141 -935 -590 -1537 -743 274 -112 -527 -916 -859 -855 -471 1297 3083 2476 1726 2105 1155 -20 -1620 -2997 -3506 -3077 -1146 1806 1200 476 291 -1984 -1989 -861 176 -254 411 905 122 872 1984 2676 1457 1296 390 -665 -1032 1145 254 285 1144 595 229 2341 777 -674 -902 -1681 -2925 -999 -156 -336 -190 614 180 334 928 1355 1753 2172 943 -1391 -1934 -2102 -1476 -365 886 867 94 900000 1443 1647 1836 1268 141 916 130 -1522 -1477 -1668 -1626 -1455 905 1097 -482 280 255 -140 1355 1358 1664 2064 2270 -2530 -2574 -1942 -2563 -1684 2410 1784 203 519 -70 -827 -1299 -173 -614 692 1039 1708 1561 1547 1256 1603 -561 -1825 -2634 -3440 -2186 -726 478 232 657 -390 -304 79 1128 1046 1212 985 91 -154 49 -337 -2166 -1465 -695 -803 851 1288 59 -1012 -999 -1431 -2076 -906 -580 -1523 -738 264 -109 -513 -889 -833 -832 -460 1272 3051 2442 1663 2070 1112 -19 -1521 -2802 -3302 -2960 -1082 1770 1220 485 295 -2005 -1988 -869 181 -265 412 911 124 885 2029 2763 1504 1319 393 -663 -1022 1137 257 287 1154 602 231 2350 786 -670 -890 -1671 -2911 -1002 -162 -353 -202 661 196 365 976 1428 1845 2364 1020 -1488 -2040 -2226 -1581 -396 938 930 100 900000 SQ 20231023T114337.7Z 8696.488631 46 1 53.98 2 87.33 107.01 159.38 330.51 0.00 1 0.00 1 0 99 1.406e-02 1.391e-02 7.522e-04 7.511e-04 6.073917e+03 4.429036e+01 3.524855e+02 -6.000000e+00 7.213299e+02 284.29 -2.00 20.00 -2.00 505.35 0.00e+00 1.589616e-03 2.018296e-05 6.199898e-05 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