File name: Pandora71s1_GreenbeltMD_20231103_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20231117T193115.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20231103_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20231103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231103T114527.4Z 8707.489901 214 1 54.25 2 89.24 110.19 27.66 253.07 0.00 1 0.00 1 0 113 1.683e-02 1.656e-02 3.685e-04 3.660e-04 1.063943e+04 2.259732e+01 6.671790e+02 -6.000000e+00 8.589840e+02 282.97 -2.00 20.00 -2.00 505.49 0.00e+00 5.463684e-03 9.883144e-06 1.162164e-04 -6.000000e+00 4.575196e-04 282.97 -2.00 20.00 -2.00 501.30 0.00e+00 1.133759e+00 6.411826e-03 6.725465e-02 -6.000000e+00 3.171132e-01 224.61 -2.00 3.47 -2.00 502.77 0.00e+00 19.208 0.125 489.00 513.00 1 1.9444e+00 4.9266e-04 3.2976e-02 -6.0000e+00 2.4242e-02 -5.5283e-02 1.1782e-04 1.8488e-03 -6.0000e+00 6.4038e-03 1.5903e-02 9.0276e-02 2.4548e-05 6.4963e-05 -6.0000e+00 1.1441e-03 -7.7041e-03 3.0360e-04 12 13 8 11 4 0 90.52 29.55 4.85 -0.00770 0.61848 291 31 1 2 0 186.060 20.36 29.55 6.98 26.25 26.00 23.4 932.53 2369 2873 2830 1967 803 1298 265 -1260 -1499 -1689 -1566 -1162 1117 1565 -87 510 428 -5 1524 1724 1822 2296 2321 -2452 -3039 -2526 -2878 -1885 2590 1856 260 159 -468 -1231 -1658 -509 -620 646 1055 1769 1729 1578 1366 1398 -955 -2554 -3325 -4328 -2812 -906 465 382 689 -227 -214 165 1257 1268 1556 1053 235 -106 -94 -650 -2505 -2047 -1017 -1056 778 1123 34 -1567 -1341 -1720 -2417 -1424 -917 -1924 -1183 142 -94 -650 -1279 -1377 -1028 -449 1536 3438 2788 1969 2082 923 24 -1895 -3691 -4159 -3647 -1724 1535 1214 363 -399 -2333 -2491 -993 299 117 758 1159 659 1258 2554 3295 1853 1503 490 -691 -808 1345 612 527 1557 909 684 2732 854 -962 -850 -1596 -3151 -962 9 -346 27 969 482 674 1354 1643 2054 1881 787 -1637 -2464 -2461 -1624 -400 1059 1101 43 -375 2137 2629 2603 1803 727 1163 237 -1120 -1325 -1504 -1407 -1060 1038 1489 -84 488 413 -5 1409 1610 1699 2130 2148 -2245 -2840 -2366 -2742 -1739 2453 1814 254 154 -453 -1188 -1603 -496 -614 615 1020 1726 1691 1535 1315 1330 -943 -2478 -3203 -4186 -2749 -870 459 384 697 -230 -216 167 1285 1303 1594 1075 237 -106 -93 -642 -2461 -2001 -1000 -1049 776 1131 34 -1547 -1307 -1671 -2350 -1386 -902 -1909 -1176 143 -91 -632 -1237 -1329 -991 -435 1498 3386 2740 1890 2038 885 23 -1777 -3457 -3914 -3501 -1703 1502 1229 370 -406 -2371 -2518 -1015 312 118 774 1193 683 1306 2678 3499 1975 1584 512 -713 -829 1387 642 554 1641 964 722 2879 909 -1009 -884 -1675 -3323 -1023 10 -370 30 1056 531 745 1503 1829 2282 2082 864 -1783 -2660 -2668 -1782 -445 1200 1216 48 -429 SQ 20231103T115419.9Z 8707.496064 227 1 28.46 2 87.63 111.61 29.29 255.25 0.00 1 0.00 1 0 113 1.451e-02 1.433e-02 1.944e-04 1.940e-04 7.127231e+03 1.159661e+01 4.835162e+02 -6.000000e+00 7.405344e+02 282.97 -2.00 20.00 -2.00 505.40 0.00e+00 3.317158e-03 5.220400e-06 1.911624e-05 -6.000000e+00 3.943375e-04 282.97 -2.00 20.00 -2.00 500.93 0.00e+00 1.277921e+00 3.433407e-03 5.365865e-02 -6.000000e+00 2.732678e-01 224.61 -2.00 3.47 -2.00 502.47 0.00e+00 15.080 0.060 489.00 513.00 1 6.8916e-01 2.6380e-04 2.3332e-02 -6.0000e+00 2.0891e-02 -2.1341e-02 6.3980e-05 1.3394e-03 -6.0000e+00 5.5181e-03 1.0144e-01 8.8901e-02 1.3138e-05 4.3031e-05 -6.0000e+00 9.8703e-04 4.0723e-02 1.6473e-05 12 13 8 11 4 0 1.95 29.47 1.94 0.04072 0.65737 724 78 1 2 0 38.963 20.58 29.47 7.07 26.25 25.75 23.4 933.13 1451 1804 1901 1281 302 959 78 -1437 -1660 -1789 -1636 -1356 854 1214 -394 327 323 -91 1328 1501 1568 2071 2343 -2242 -2674 -2059 -2573 -1669 2533 1744 427 365 -193 -868 -1467 -400 -589 612 992 1616 1651 1540 1347 1527 -585 -2013 -2852 -3864 -2500 -851 532 300 525 -313 -366 -19 1031 1062 1286 1011 334 3 107 -344 -2153 -1678 -706 -730 984 1256 308 -1085 -1006 -1320 -2120 -1074 -552 -1643 -923 245 38 -419 -971 -978 -858 -514 1107 2971 2400 1756 2055 1260 156 -1579 -2939 -3401 -3063 -1318 1720 1423 580 7 -1924 -2087 -911 90 -118 481 839 297 928 1983 2642 1367 1237 343 -729 -946 1044 264 186 1123 604 405 2414 817 -846 -785 -1481 -3048 -1209 -120 -449 -209 612 130 387 1049 1431 1981 1976 1016 -1243 -2111 -2122 -1407 -336 1053 1056 119 -177 1444 1756 1857 1244 289 942 77 -1396 -1601 -1736 -1542 -1298 833 1214 -398 328 326 -92 1344 1478 1538 2016 2269 -2224 -2570 -1979 -2515 -1657 2493 1773 433 366 -192 -862 -1457 -399 -596 622 987 1620 1655 1531 1371 1531 -579 -1950 -2738 -3714 -2426 -851 527 303 533 -318 -370 -19 1051 1086 1311 1024 334 3 104 -335 -2081 -1610 -682 -711 963 1243 303 -1048 -959 -1254 -2017 -1022 -532 -1596 -898 242 37 -417 -964 -970 -852 -512 1111 2914 2353 1742 1992 1197 146 -1512 -2798 -3253 -2884 -1274 1720 1420 580 7 -1907 -2051 -904 90 -122 499 847 302 944 2031 2730 1413 1260 346 -752 -969 1041 268 188 1137 613 409 2431 830 -846 -802 -1522 -3040 -1214 -124 -473 -222 637 136 408 1108 1516 2094 2079 1058 -1320 -2214 -2231 -1496 -351 1118 1135 128 -189 SQ 20231103T115448.5Z 8707.496395 227 2 28.47 2 87.54 111.68 29.38 255.36 0.00 1 0.00 1 0 113 1.448e-02 1.435e-02 1.868e-04 1.865e-04 7.037478e+03 1.112682e+01 4.807625e+02 -6.000000e+00 7.392518e+02 282.97 -2.00 20.00 -2.00 505.37 0.00e+00 3.270186e-03 5.025478e-06 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