File name: Pandora71s1_GreenbeltMD_20241018_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241019T050729.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241018_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241018T112707.6Z 9057.477172 209 1 54.09 2 89.58 103.12 77.10 281.34 0.00 1 0.00 1 0 106 1.632e-02 1.603e-02 3.672e-04 3.648e-04 1.261090e+04 2.309358e+01 6.565026e+02 -6.000000e+00 8.380696e+02 284.77 -2.00 20.00 -2.00 505.49 0.00e+00 4.815553e-03 9.981620e-06 6.697300e-05 -6.000000e+00 4.453853e-04 284.77 -2.00 20.00 -2.00 501.30 0.00e+00 1.329912e+00 6.398943e-03 7.567335e-02 -6.000000e+00 3.076959e-01 225.87 -2.00 3.47 -2.00 502.77 0.00e+00 19.818 0.137 489.00 513.00 1 1.8357e+00 4.9211e-04 3.4650e-02 -6.0000e+00 2.3530e-02 -6.3639e-02 1.1679e-04 1.9860e-03 -6.0000e+00 6.2210e-03 1.6149e-02 9.5769e-02 2.4100e-05 6.0396e-05 -6.0000e+00 1.1089e-03 -5.9517e-04 2.0394e-04 12 12 8 10 0 0 12.99 25.83 4.91 -0.00060 0.66370 266 29 1 2 0 202.963 20.11 25.83 12.48 27.00 27.25 6.8 971.06 2525 2842 2729 1411 940 1279 -102 -1445 -1449 -1580 -1613 -525 1577 938 -209 566 95 249 1759 1465 1726 2351 1288 -3328 -2766 -2449 -2935 -645 2641 1275 58 168 -695 -1349 -1445 -341 -378 810 1326 1777 1574 1393 1350 913 -1578 -2581 -3670 -4041 -2076 -464 562 375 549 -445 -18 480 1241 1249 1417 745 15 -224 32 -1318 -2610 -1638 -1077 -733 1005 939 -661 -1467 -1509 -1880 -2408 -1152 -1137 -2020 -548 62 -34 -830 -1229 -1181 -825 6 2209 3537 2353 2166 1765 621 -124 -2460 -3757 -4096 -3302 -903 1536 803 118 -748 -2726 -2055 -494 359 169 727 1051 488 1451 2776 3010 1607 1299 338 -1012 -270 1391 416 758 1503 674 1104 2714 5 -1095 -543 -1936 -2829 -301 -69 -349 293 864 479 826 1344 1717 2025 1636 146 -1825 -2426 -2192 -1426 5 1089 818 -202 -342 2326 2652 2554 1315 864 1167 -93 -1306 -1307 -1438 -1485 -491 1436 875 -196 530 89 234 1670 1404 1648 2235 1221 -3100 -2516 -2247 -2739 -612 2597 1225 55 159 -658 -1274 -1369 -326 -366 794 1314 1779 1575 1385 1327 888 -1516 -2436 -3451 -3816 -1990 -459 570 370 544 -442 -18 477 1244 1255 1421 743 15 -218 33 -1274 -2616 -1638 -1040 -713 985 927 -648 -1411 -1439 -1787 -2290 -1099 -1098 -1963 -534 62 -34 -826 -1218 -1165 -816 6 2210 3562 2347 2093 1664 598 -118 -2336 -3561 -3924 -3105 -878 1559 803 119 -752 -2732 -2050 -500 370 177 763 1109 518 1546 2878 3166 1690 1349 362 -1070 -283 1478 430 785 1565 704 1147 2827 5 -1128 -556 -2009 -2952 -319 -75 -385 326 941 526 912 1490 1905 2242 1804 160 -1977 -2617 -2381 -1572 6 1241 942 -232 -392 SQ 20241018T113123.6Z 9057.480134 215 1 54.16 2 88.78 103.79 77.87 281.96 0.00 1 0.00 1 0 92 1.457e-02 1.434e-02 2.124e-04 2.116e-04 9.674346e+03 1.313682e+01 4.657278e+02 -6.000000e+00 7.485606e+02 284.77 -2.00 20.00 -2.00 505.45 0.00e+00 3.033371e-03 5.733554e-06 2.216691e-05 -6.000000e+00 3.977949e-04 284.77 -2.00 20.00 -2.00 501.08 0.00e+00 1.392269e+00 3.719348e-03 6.298575e-02 -6.000000e+00 2.747852e-01 225.87 -2.00 3.47 -2.00 502.60 0.00e+00 18.071 0.104 489.00 513.00 1 1.0557e+00 2.8587e-04 2.9906e-02 -6.0000e+00 2.1014e-02 -3.7981e-02 6.8612e-05 1.7310e-03 -6.0000e+00 5.5547e-03 4.5941e-02 9.5041e-02 1.4254e-05 4.0098e-05 -6.0000e+00 9.9042e-04 1.6092e-02 1.1280e-04 12 12 8 10 0 0 0.39 25.77 2.91 0.01609 0.67533 692 74 1 2 0 77.910 20.05 25.77 12.22 27.25 27.25 6.8 971.09 1904 2145 2074 945 595 1011 -229 -1596 -1506 -1630 -1632 -720 1408 793 -290 566 140 193 1580 1380 1546 2328 1364 -3160 -2378 -2000 -2726 -493 2644 1252 126 301 -427 -1112 -1214 -316 -377 732 1209 1700 1493 1461 1370 1072 -1263 -2144 -3244 -3704 -1866 -429 571 321 522 -454 -99 313 1112 1116 1280 770 54 -73 148 -1079 -2261 -1362 -829 -502 1175 1040 -391 -1107 -1228 -1593 -2220 -897 -819 -1835 -375 100 150 -700 -1006 -1036 -694 -110 1954 3121 2073 1931 1750 761 -176 -2231 -3241 -3606 -2919 -658 1844 928 297 -364 -2335 -1802 -494 181 31 513 840 246 1195 2326 2554 1223 1119 194 -1022 -321 1154 125 541 1207 459 906 2519 91 -1041 -588 -1976 -2737 -445 -94 -406 130 651 204 587 1177 1579 1925 1636 274 -1607 -2174 -1975 -1246 60 1094 833 -180 -284 1846 2021 1959 888 574 968 -219 -1511 -1421 -1551 -1506 -675 1351 779 -287 558 138 191 1575 1330 1482 2218 1295 -3066 -2247 -1903 -2643 -467 2593 1257 126 297 -421 -1089 -1191 -312 -378 711 1188 1682 1475 1430 1379 1065 -1236 -2055 -3094 -3544 -1812 -414 564 322 525 -457 -100 316 1130 1136 1299 775 54 -71 144 -1050 -2178 -1309 -804 -490 1158 1033 -385 -1069 -1175 -1520 -2122 -861 -796 -1795 -368 99 150 -702 -1007 -1035 -695 -106 1907 3072 2022 1901 1683 716 -163 -2058 -2980 -3352 -2782 -647 1820 942 302 -369 -2353 -1804 -501 187 32 522 859 253 1231 2423 2690 1285 1159 199 -1036 -323 1176 129 558 1249 475 933 2599 95 -1061 -596 -2021 -2808 -464 -101 -427 138 701 221 640 1289 1730 2105 1781 296 -1710 -2298 -2100 -1344 66 1178 905 -195 -316 SQ 20241018T113521.6Z 9057.482889 221 1 28.47 2 88.03 104.42 78.59 282.54 0.00 1 0.00 1 0 99 1.385e-02 1.366e-02 2.065e-04 2.060e-04 8.040036e+03 1.253933e+01 3.835090e+02 -6.000000e+00 7.115551e+02 284.77 -2.00 20.00 -2.00 505.41 0.00e+00 2.274508e-03 5.564470e-06 4.952633e-05 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