File name: Pandora71s1_GreenbeltMD_20241031_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241101T055133.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241031_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241031T114131.8Z 9070.487174 43 1 23.24 2 89.50 109.03 80.52 115.07 0.00 1 0.00 1 0 92 1.845e-02 1.803e-02 9.437e-04 9.382e-04 2.581005e+04 6.638586e+01 1.008431e+03 -6.000000e+00 9.420206e+02 283.21 -2.00 20.00 -2.00 505.51 0.00e+00 5.569201e-03 2.549473e-05 1.248064e-04 -6.000000e+00 5.017849e-04 283.21 -2.00 20.00 -2.00 501.17 0.00e+00 1.276560e+00 1.667859e-02 1.349704e-01 -6.000000e+00 3.478337e-01 224.78 -2.00 3.47 -2.00 502.67 0.00e+00 19.720 0.135 489.00 513.00 1 2.9195e+00 1.2808e-03 3.5292e-02 -6.0000e+00 2.6587e-02 -6.7942e-02 3.0161e-04 2.2960e-03 -6.0000e+00 7.0308e-03 5.3740e-03 9.7670e-02 5.6915e-05 8.2515e-05 -6.0000e+00 1.2541e-03 6.0786e-04 1.9724e-04 12 13 9 12 5 1 38.86 27.26 4.76 0.00061 0.67809 40 10 1 2 0 566.341 20.02 27.26 20.09 28.25 28.50 7.2 1010.90 3675 3703 3486 1814 1519 1849 -20 -1201 -900 -1309 -1266 52 1940 910 -114 573 91 307 1860 1431 1803 2651 690 -3921 -2882 -2317 -3230 -224 2673 865 -481 -389 -1067 -1926 -1527 -428 -579 573 1299 1730 1362 1006 1153 481 -2166 -2753 -3943 -4031 -1705 -196 618 369 661 -562 -18 641 1081 1249 1308 308 -485 -395 -408 -1758 -2904 -1747 -1298 -658 1077 708 -1083 -1548 -1528 -1871 -2351 -1088 -897 -1691 -361 118 51 -779 -1633 -1447 -267 1038 3792 4808 3034 2940 1728 426 727 -2573 -4834 -5277 -4309 -1505 1180 535 114 -1289 -3231 -1984 -119 539 -228 132 396 -641 1190 3147 3310 1699 983 -271 -1748 -277 1710 699 1255 2238 908 1578 3155 -821 -1476 -172 -1831 -2099 681 -40 -344 681 1249 980 1350 1540 1795 1980 1647 29 -1695 -2449 -2210 -1291 208 1194 609 -352 -622 3447 3521 3178 1724 1423 1719 -18 -1110 -829 -1220 -1142 47 1820 874 -110 553 88 299 1821 1356 1700 2485 647 -3770 -2707 -2193 -2994 -211 2609 862 -477 -384 -1050 -1894 -1505 -426 -562 562 1289 1732 1365 1003 1134 468 -2083 -2707 -3868 -3815 -1638 -194 629 367 684 -561 -18 642 1094 1263 1321 309 -481 -402 -414 -1778 -2915 -1751 -1311 -643 1059 700 -1061 -1545 -1507 -1833 -2296 -1063 -885 -1679 -348 115 50 -761 -1583 -1438 -264 1027 3760 4752 2927 2699 1589 379 636 -2291 -4331 -4812 -3919 -1434 1140 538 116 -1273 -3305 -2016 -118 545 -232 134 402 -656 1216 3292 3427 1768 1046 -283 -1794 -280 1739 722 1303 2339 954 1646 3303 -868 -1526 -178 -1929 -2145 710 -43 -371 744 1346 1069 1485 1700 1973 2165 1792 32 -1831 -2656 -2417 -1430 234 1324 685 -398 -703 SQ 20241031T114421.3Z 9070.489136 47 1 54.26 2 88.98 109.48 80.05 115.55 0.00 1 0.00 1 0 106 1.676e-02 1.643e-02 3.460e-04 3.443e-04 2.333140e+04 2.398589e+01 8.865757e+02 -6.000000e+00 8.553800e+02 283.21 -2.00 20.00 -2.00 505.49 0.00e+00 4.371467e-03 9.339582e-06 7.272026e-05 -6.000000e+00 4.556745e-04 283.21 -2.00 20.00 -2.00 501.09 0.00e+00 1.425532e+00 6.110375e-03 1.291187e-01 -6.000000e+00 3.159329e-01 224.78 -2.00 3.47 -2.00 502.61 0.00e+00 18.616 0.114 489.00 513.00 1 1.8931e+00 4.6942e-04 3.2241e-02 -6.0000e+00 2.4147e-02 -5.1585e-02 1.1092e-04 2.1688e-03 -6.0000e+00 6.3879e-03 1.7624e-02 9.7916e-02 2.1127e-05 6.9401e-05 -6.0000e+00 1.1389e-03 2.9388e-03 1.6411e-04 12 13 8 11 4 0 -0.50 27.27 3.41 0.00294 0.68213 281 30 1 2 0 192.733 20.02 27.27 20.20 28.25 28.75 7.2 1011.19 2961 3006 2758 1273 1098 1412 -137 -1352 -1173 -1305 -1324 -145 1890 671 -306 580 -64 291 1689 1382 1557 2430 706 -3775 -2594 -2134 -2817 5 2682 862 -292 -152 -943 -1531 -1385 -456 -343 717 1172 1618 1266 1238 1194 591 -1844 -2506 -3675 -3676 -1561 -163 693 399 401 -633 -109 418 1129 1099 1110 407 -313 -376 -143 -1572 -2623 -1510 -998 -458 1219 808 -929 -1302 -1287 -1599 -2210 -832 -803 -1824 -80 250 57 -763 -1412 -1185 -200 1036 3590 4437 2841 2897 1742 606 559 -2381 -4439 -4750 -3640 -1176 1248 548 120 -1018 -3057 -1924 -135 413 -330 51 291 -760 837 2790 3058 1452 879 -257 -1550 -291 1572 533 1099 2073 665 1176 2852 -722 -1433 -191 -1943 -2191 571 -236 -417 547 1000 678 1127 1324 1690 1954 1575 103 -1630 -2193 -1991 -1264 172 1179 644 -252 -512 2777 2859 2630 1209 1027 1311 -127 -1243 -1076 -1208 -1240 -138 1842 641 -294 555 -62 281 1640 1352 1517 2353 681 -3578 -2508 -1989 -2675 5 2689 846 -285 -153 -910 -1537 -1393 -444 -338 714 1182 1644 1285 1245 1188 581 -1784 -2483 -3630 -3489 -1505 -163 707 413 417 -633 -109 419 1140 1111 1120 407 -309 -382 -144 -1583 -2617 -1504 -1002 -463 1191 794 -942 -1291 -1261 -1555 -2148 -809 -788 -1808 -80 243 56 -743 -1363 -1177 -197 1026 3563 4399 2750 2670 1614 543 494 -2130 -3992 -4340 -3301 -1118 1203 549 122 -1034 -3096 -1935 -137 412 -332 51 292 -767 846 2876 3224 1538 917 -264 -1557 -289 1570 540 1118 2119 683 1201 2920 -744 -1445 -192 -1994 -2260 600 -247 -438 581 1086 745 1247 1471 1868 2148 1724 113 -1765 -2376 -2174 -1400 187 1303 720 -282 -574 SQ 20241031T114731.1Z 9070.491332 51 1 54.20 2 88.40 109.98 79.51 116.09 0.00 1 0.00 1 0 92 1.555e-02 1.522e-02 2.295e-04 2.288e-04 2.034930e+04 1.570056e+01 7.893133e+02 -6.000000e+00 7.937669e+02 283.21 -2.00 20.00 -2.00 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