File name: Pandora71s1_GreenbeltMD_20241103_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241113T121447.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241103_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241103T114512.7Z 9073.489730 31 1 53.81 2 89.44 110.33 111.98 105.77 0.00 1 0.00 1 0 106 1.754e-02 1.720e-02 9.788e-04 9.692e-04 1.195789e+04 6.130645e+01 6.313127e+02 -6.000000e+00 8.943770e+02 282.85 -2.00 20.00 -2.00 505.54 0.00e+00 5.147220e-03 2.651425e-05 1.081597e-04 -6.000000e+00 4.766179e-04 282.85 -2.00 20.00 -2.00 501.43 0.00e+00 8.439705e-01 1.697302e-02 6.669497e-02 -6.000000e+00 3.305697e-01 224.53 -2.00 3.47 -2.00 502.89 0.00e+00 19.616 0.133 489.00 513.00 1 3.7453e+00 1.3045e-03 3.4069e-02 -6.0000e+00 2.5266e-02 -6.6829e-02 3.0825e-04 1.9127e-03 -6.0000e+00 6.6791e-03 2.5504e-03 9.5082e-02 6.4467e-05 6.2103e-05 -6.0000e+00 1.1921e-03 -2.3001e-03 2.3711e-04 12 12 8 10 0 0 98.88 25.88 6.37 -0.00230 0.65723 54 6 1 2 0 995.983 19.85 25.88 8.40 26.25 26.50 7.1 963.94 3139 3306 3106 1763 1398 1465 249 -1447 -1438 -1462 -1472 -609 1561 1128 143 554 303 168 1684 1645 1819 2530 1167 -3391 -3141 -2544 -3185 -863 2674 1297 157 -71 -541 -1526 -1438 -277 -412 790 1351 1923 1573 1570 1286 835 -1781 -2824 -4050 -4358 -2422 -404 480 302 628 -375 55 380 1419 1373 1587 923 -67 -279 -243 -1211 -2752 -1650 -1158 -945 904 625 -619 -1675 -1842 -2249 -2600 -1338 -1264 -2254 -774 -7 -287 -1070 -1401 -1249 -935 -224 2114 3580 2279 2119 1720 353 -634 -2700 -4135 -4359 -3556 -1187 1650 709 152 -792 -2858 -2042 -681 318 300 798 1215 817 1742 3069 3304 1597 1368 277 -848 -320 1568 400 839 1546 849 1238 2816 75 -947 -494 -1950 -2890 -431 0 -349 442 1034 556 1020 1501 1754 2141 1780 255 -2089 -2676 -2385 -1600 -138 1174 880 -266 -406 2878 3074 2738 1549 1280 1335 227 -1309 -1298 -1329 -1279 -538 1410 1042 133 514 283 157 1587 1563 1723 2384 1101 -3142 -2848 -2321 -2960 -815 2474 1229 148 -67 -505 -1425 -1346 -261 -395 765 1326 1904 1561 1545 1255 807 -1702 -2654 -3798 -4102 -2315 -397 485 295 614 -368 54 374 1407 1366 1574 911 -66 -270 -234 -1162 -2626 -1569 -1112 -916 882 616 -604 -1608 -1756 -2139 -2471 -1275 -1220 -2192 -755 -7 -286 -1066 -1388 -1232 -925 -223 2118 3612 2284 2061 1633 328 -582 -2475 -3789 -4029 -3369 -1162 1678 708 153 -793 -2859 -2030 -689 327 312 838 1281 866 1851 3303 3607 1747 1478 296 -896 -336 1665 431 905 1677 923 1338 3054 78 -1016 -527 -2108 -2998 -453 0 -382 488 1159 630 1159 1714 2006 2442 2021 288 -2338 -2980 -2673 -1820 -159 1318 999 -302 -459 SQ 20241103T115005.1Z 9073.493115 39 1 13.87 2 88.55 111.11 111.11 106.42 0.00 1 0.00 1 0 99 1.491e-02 1.473e-02 6.097e-04 6.081e-04 9.500788e+03 3.723062e+01 4.915557e+02 -6.000000e+00 7.603761e+02 282.85 -2.00 20.00 -2.00 505.42 0.00e+00 3.226221e-03 1.639913e-05 1.932281e-05 -6.000000e+00 4.051522e-04 282.85 -2.00 20.00 -2.00 501.05 0.00e+00 1.144422e+00 1.070844e-02 6.366319e-02 -6.000000e+00 2.809576e-01 224.53 -2.00 3.47 -2.00 502.57 0.00e+00 17.536 0.095 489.00 513.00 1 1.9912e+00 8.2262e-04 2.8635e-02 -6.0000e+00 2.1476e-02 -3.4779e-02 1.9825e-04 1.6599e-03 -6.0000e+00 5.6753e-03 1.9751e-02 9.4436e-02 4.0878e-05 4.2676e-05 -6.0000e+00 1.0135e-03 5.2318e-03 2.0633e-04 12 13 9 12 1 1 -1.71 25.91 2.82 0.00523 0.66028 70 30 1 2 0 194.913 20.22 25.91 8.41 26.50 26.50 7.1 963.96 1950 2111 2252 1047 464 1020 -219 -1517 -1551 -1714 -1663 -777 1392 893 -341 532 47 262 1583 1427 1601 2381 1380 -3253 -2515 -1955 -2780 -608 2656 1358 110 248 -317 -1105 -1375 -409 -353 759 1212 1749 1610 1423 1448 1154 -1317 -2068 -3272 -3756 -1869 -401 641 424 481 -465 -69 382 1127 1154 1199 726 60 -117 102 -1129 -2270 -1493 -761 -529 1234 1035 -386 -1237 -1294 -1558 -2211 -915 -768 -1917 -358 53 -7 -654 -1060 -1037 -694 -225 1955 3075 2140 1917 1877 838 -195 -2330 -3350 -3659 -2916 -584 1918 870 276 -445 -2312 -1950 -516 289 100 673 877 277 1336 2404 2706 1297 1187 233 -1064 -391 1189 166 575 1371 552 946 2483 126 -1099 -545 -1953 -2794 -440 -69 -400 199 638 173 637 1182 1630 1965 1632 272 -1697 -2281 -2049 -1374 27 1168 876 -134 -291 1863 2046 2184 1011 442 962 -206 -1414 -1442 -1607 -1576 -748 1330 874 -335 522 46 258 1569 1382 1543 2349 1318 -3145 -2365 -1848 -2680 -595 2616 1330 110 246 -313 -1088 -1357 -407 -345 748 1209 1758 1615 1417 1423 1120 -1297 -1992 -3141 -3617 -1826 -393 644 421 479 -463 -68 381 1133 1161 1205 723 59 -116 102 -1119 -2226 -1462 -750 -526 1202 1018 -376 -1217 -1262 -1512 -2151 -893 -759 -1857 -348 52 -7 -648 -1049 -1025 -687 -224 1960 3028 2145 1869 1787 803 -184 -2192 -3139 -3463 -2828 -568 1889 882 280 -450 -2325 -1952 -523 290 102 690 903 288 1386 2523 2795 1337 1238 241 -1087 -397 1220 172 597 1427 561 981 2581 128 -1128 -555 -2010 -2884 -449 -72 -426 208 679 186 686 1277 1763 2121 1754 290 -1783 -2381 -2150 -1463 29 1251 947 -144 -312 SQ 20241103T115238.1Z 9073.494886 43 1 28.48 2 88.09 111.51 110.66 106.77 0.00 1 0.00 1 0 106 1.433e-02 1.412e-02 2.482e-04 2.476e-04 8.435847e+03 1.501674e+01 4.183906e+02 -6.000000e+00 7.305123e+02 282.85 -2.00 20.00 -2.00 505.41 0.00e+00 2.614331e-03 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