File name: Pandora71s1_GreenbeltMD_20241111_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241127T135853.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241111_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241111T124949.8Z 9081.534604 127 1 5.93 2 79.92 122.68 146.87 352.76 0.00 1 0.00 1 0 92 1.350e-02 1.342e-02 4.167e-03 4.159e-03 6.488586e+03 2.477748e+02 2.875743e+02 -6.000000e+00 6.853418e+02 281.88 -2.00 20.00 -2.00 505.30 0.00e+00 8.240145e-04 1.107971e-04 1.004680e-04 -6.000000e+00 3.658608e-04 281.88 -2.00 20.00 -2.00 500.49 0.00e+00 5.887711e-01 7.466123e-02 5.329927e-02 -6.000000e+00 2.544901e-01 223.85 -2.00 3.47 -2.00 502.09 0.00e+00 5.471 0.003 489.00 513.00 1 6.0858e+00 5.7336e-03 8.8404e-03 -6.0000e+00 1.9441e-02 1.5301e-02 1.4116e-03 7.3570e-04 -6.0000e+00 5.1484e-03 1.9247e-03 9.5162e-02 2.8091e-04 2.8125e-05 -6.0000e+00 9.1796e-04 1.1879e-01 -5.8245e-04 12 13 9 12 5 1 999.00 27.62 0.85 0.11879 0.77887 1 2 1 2 0 2962.967 19.99 27.62 19.94 28.00 28.50 6.9 1009.21 2012 895 1343 39 -95 1045 -205 -1511 -1454 -1461 -1486 -743 1408 419 -562 1253 -78 -125 1966 1121 1296 2227 1325 -3662 -1626 -1433 -2308 62 2535 1557 486 714 -492 -1288 -1388 -320 -882 320 1097 1027 1316 838 1820 1211 -1426 -1952 -2303 -3868 -1413 -242 -6 228 33 -1245 285 3 723 1176 1506 616 520 291 797 -217 -1698 -1211 -615 -902 1237 1673 -771 -922 -1223 -1251 -1400 -1028 221 -1584 24 -11 341 -868 77 -1245 -414 -22 1868 2927 2023 1887 1591 371 132 -2023 -2452 -2903 -3060 -477 2022 1150 833 -393 -1803 -2260 -1188 -109 301 -83 596 -792 1404 1363 1615 1240 499 282 -554 748 462 -464 2 972 -38 474 3496 730 -420 -714 -1618 -2045 -685 -112 -264 -361 -113 -179 917 573 1571 1980 1641 583 -1824 -1578 -1576 -1553 -423 1699 572 281 -490 2082 949 1418 41 -98 1083 -211 -1539 -1474 -1488 -1528 -761 1473 440 -591 1299 -82 -131 2046 1177 1349 2295 1355 -3765 -1641 -1456 -2335 64 2648 1617 511 740 -509 -1325 -1423 -329 -918 335 1128 1066 1381 872 1847 1240 -1438 -1916 -2276 -3782 -1390 -241 -6 235 34 -1266 290 3 732 1211 1540 626 517 292 791 -214 -1661 -1184 -606 -901 1211 1640 -756 -898 -1181 -1198 -1337 -994 214 -1553 24 -10 334 -856 75 -1227 -405 -22 1848 2920 1999 1814 1534 351 124 -1893 -2272 -2719 -2890 -461 1988 1134 815 -384 -1777 -2222 -1182 -108 298 -84 598 -788 1404 1358 1618 1249 498 276 -546 725 451 -455 2 946 -37 468 3396 715 -403 -683 -1551 -1950 -667 -110 -262 -362 -113 -179 911 576 1571 1973 1627 582 -1797 -1525 -1529 -1533 -423 1671 572 276 -491 SQ 20241111T131515.0Z 9081.552257 142 1 1.85 2 75.88 127.29 146.90 3.81 0.00 1 0.00 1 0 113 1.273e-02 1.264e-02 4.174e-03 4.169e-03 4.484858e+03 2.386552e+02 2.188950e+02 -6.000000e+00 6.459108e+02 281.88 -2.00 20.00 -2.00 505.30 0.00e+00 7.652110e-04 1.110396e-04 9.803776e-05 -6.000000e+00 3.448059e-04 281.88 -2.00 20.00 -2.00 500.56 0.00e+00 2.860296e-01 7.437667e-02 4.774072e-02 -6.000000e+00 2.398347e-01 223.85 -2.00 3.47 -2.00 502.15 0.00e+00 4.008 0.001 489.00 513.00 1 5.1783e+00 5.7146e-03 6.8952e-03 -6.0000e+00 1.8322e-02 -3.5720e-03 1.4076e-03 6.4563e-04 -6.0000e+00 4.8516e-03 6.0336e-03 9.6255e-02 2.8310e-04 2.4002e-05 -6.0000e+00 8.6512e-04 1.1567e-01 -5.5893e-04 12 13 9 12 5 1 999.00 26.75 0.97 0.11567 0.78333 1 6 1 2 0 923.190 20.00 26.75 20.16 28.25 28.75 7.0 1010.45 1733 1682 1247 62 597 482 -678 -702 -1499 -1664 -1392 -625 930 911 -223 -18 -196 -39 1616 1066 963 2300 806 -2520 -2882 -1823 -2300 -429 2772 1261 345 511 -78 -1064 -1235 -314 -90 591 1109 1277 1071 1506 1950 1291 -2364 -1602 -2847 -2966 -1371 -509 868 280 140 -650 27 461 522 446 1372 159 52 -190 405 -1179 -2366 -1176 7 501 1399 1263 377 -1003 -925 -954 -1559 181 -560 -1293 325 54 -131 -230 -619 -338 -821 -643 1311 2874 1783 1121 1584 1367 -313 -1785 -2638 -2699 -2189 -146 1721 936 479 -18 -1933 -1333 -324 165 -229 397 673 -144 1149 1725 1988 95 381 -64 -1579 -184 832 -886 605 592 -360 1109 2462 837 -887 -537 -2100 -2801 -661 403 -492 -126 293 -71 396 877 1749 1278 1763 203 -1680 -1095 -1732 -1013 367 797 950 224 -70 1789 1759 1309 65 607 497 -694 -702 -1506 -1683 -1418 -638 959 951 -233 -19 -205 -41 1690 1101 1006 2370 826 -2545 -2873 -1816 -2322 -436 2850 1320 357 523 -79 -1094 -1269 -318 -91 608 1150 1310 1112 1536 1985 1297 -2362 -1568 -2769 -2883 -1355 -513 875 287 143 -653 27 469 528 451 1394 161 52 -189 399 -1161 -2306 -1141 7 490 1389 1239 370 -970 -901 -923 -1514 176 -545 -1262 318 53 -129 -226 -610 -333 -814 -631 1297 2850 1756 1103 1551 1302 -299 -1686 -2483 -2560 -2090 -141 1702 941 478 -18 -1894 -1314 -318 165 -229 399 678 -146 1159 1728 1994 95 380 -63 -1568 -180 827 -878 601 590 -353 1088 2418 817 -857 -521 -2052 -2690 -643 401 -491 -127 293 -71 398 886 1759 1293 1758 203 -1652 -1071 -1713 -997 365 796 950 225 -69 SQ 20241111T132720.3Z 9081.560651 146 1 5.92 2 74.04 129.59 146.59 9.01 0.00 1 0.00 1 0 85 1.225e-02 1.219e-02 1.314e-04 1.312e-04 4.129704e+03 7.486945e+00 2.108754e+02 -6.000000e+00 6.216664e+02 281.88 -2.00 20.00 -2.00 505.29 0.00e+00 5.234087e-04 3.497287e-06 1.044555e-04 -6.000000e+00 3.318297e-04 281.88 -2.00 20.00 -2.00 500.51 0.00e+00 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