File name: Pandora71s1_GreenbeltMD_20241116_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241127T140635.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241116_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241116T115856.5Z 9086.499265 232 1 53.82 2 89.61 115.02 81.99 294.94 0.00 1 0.00 1 0 134 1.955e-02 1.888e-02 4.231e-03 4.149e-03 2.078639e+04 2.858187e+02 7.651345e+02 -6.000000e+00 9.902655e+02 281.31 -2.00 20.00 -2.00 505.65 0.00e+00 5.370446e-03 1.139537e-04 1.262605e-04 -6.000000e+00 5.293058e-04 281.31 -2.00 20.00 -2.00 501.69 0.00e+00 9.310972e-01 7.261252e-02 1.092049e-01 -6.000000e+00 3.687884e-01 223.57 -2.00 3.47 -2.00 503.12 0.00e+00 19.962 0.140 489.00 513.00 1 5.9313e+00 5.5700e-03 3.5574e-02 -6.0000e+00 2.8168e-02 -9.2631e-02 1.2844e-03 2.1963e-03 -6.0000e+00 7.4619e-03 2.6731e-04 9.9334e-02 2.6199e-04 7.1006e-05 -6.0000e+00 1.3306e-03 -4.0167e-03 1.4504e-04 12 13 8 11 4 0 99.79 27.02 8.29 -0.00402 0.68501 18 2 1 2 0 2989.463 19.99 27.02 16.78 28.00 28.25 7.0 1005.15 4407 4096 3759 2487 2096 2089 564 -969 -1149 -1397 -492 707 1024 1259 582 845 421 -111 2767 1695 1768 2262 596 -4376 -3499 -3062 -2892 24 2020 336 -1018 -668 -526 -1473 -1631 -1158 -298 627 1865 1097 1905 1494 866 896 -2358 -3358 -4115 -4289 -2198 123 826 1086 1038 -1318 -77 1057 2067 1398 1637 252 -712 -295 -848 -1702 -2780 -2188 -1413 -611 1048 330 -1373 -2241 -1603 -2063 -2837 -1640 -1189 -2035 7 -352 -793 -1310 -2660 -1085 -484 250 3378 4053 2315 2130 1440 -283 880 -3368 -4397 -5999 -4427 -730 803 663 697 -1780 -3021 -1497 -122 210 587 616 1287 193 1787 3094 3893 2023 1227 -798 -957 238 1855 705 1113 3061 782 749 2363 343 -290 -398 -2065 -2697 55 52 -490 -188 1197 1181 962 1404 1997 1945 2656 -51 -2248 -2202 -2074 -1563 193 667 866 -270 -898 3764 3560 3281 2157 1795 1782 481 -822 -977 -1201 -424 620 877 1090 504 736 369 -98 2435 1517 1579 2019 531 -3844 -3010 -2658 -2539 21 1888 321 -969 -629 -491 -1376 -1536 -1108 -287 613 1834 1102 1893 1479 853 869 -2273 -3192 -3889 -4079 -2128 115 792 1053 1013 -1306 -76 1040 2044 1395 1629 251 -701 -286 -824 -1643 -2663 -2105 -1368 -594 1028 327 -1349 -2168 -1527 -1956 -2697 -1564 -1142 -1969 7 -350 -794 -1304 -2650 -1055 -471 245 3312 3993 2241 1978 1290 -248 748 -2936 -3816 -5355 -4066 -692 809 689 728 -1784 -3177 -1473 -122 215 602 636 1325 201 1858 3298 4215 2205 1323 -854 -997 245 1934 747 1186 3248 842 808 2557 369 -305 -423 -2233 -2942 61 59 -565 -220 1419 1412 1166 1705 2413 2348 3158 -61 -2686 -2616 -2488 -1909 227 802 1047 -328 -1094 SQ 20241116T144335.0Z 9086.613599 343 1 1.19 2 65.30 146.34 105.75 321.63 0.00 1 0.00 1 0 92 1.216e-02 1.212e-02 4.409e-03 4.402e-03 8.752391e+02 2.276082e+02 9.783670e+01 -6.000000e+00 6.156273e+02 281.30 -2.00 20.00 -2.00 505.26 0.00e+00 1.926874e-04 1.166671e-04 1.282711e-04 -6.000000e+00 3.289284e-04 281.30 -2.00 20.00 -2.00 500.46 0.00e+00 4.877353e-03 7.824672e-02 2.897472e-02 -6.000000e+00 2.291282e-01 223.57 -2.00 3.47 -2.00 502.06 0.00e+00 2.377 0.000 489.00 513.00 1 5.1176e+00 6.0158e-03 4.8485e-03 -6.0000e+00 1.7501e-02 2.1806e-02 1.5010e-03 3.8445e-04 -6.0000e+00 4.6351e-03 8.3413e-03 9.4488e-02 3.0311e-04 2.4686e-05 -6.0000e+00 8.2647e-04 1.1983e-01 -5.9041e-04 12 13 9 12 5 1 999.00 27.65 1.20 0.11983 0.77524 1 10 1 2 0 594.929 20.00 27.65 18.49 28.25 28.75 7.1 1012.11 1812 1442 1425 843 483 1200 -314 -997 -2749 -1382 -1580 -857 555 798 361 523 -35 277 1111 1600 1202 2203 1397 -2772 -1790 -2511 -2970 253 1785 906 380 602 -562 -530 -1009 -864 -418 473 1088 207 1325 1074 1401 718 -1935 -1531 -2378 -2976 -1140 -331 855 -60 664 99 22 193 400 312 785 849 189 423 464 -969 -1551 -1126 -559 -300 2043 1128 -224 -982 -908 -860 -1473 -397 282 -1306 -476 469 382 -527 147 -1159 -909 -126 1124 1591 1059 1192 1903 1289 13 -2186 -2069 -3070 -2117 -280 2108 1822 481 211 -1644 -1250 -528 -986 -232 550 324 365 284 1386 911 560 1354 -314 -472 -752 1106 -851 87 737 895 618 1972 252 93 -722 -1372 -2364 -895 205 -198 46 7 21 -8 378 1849 1280 1954 777 -1083 -1475 -2095 -972 -30 995 1141 -78 119 1899 1539 1521 889 501 1249 -326 -1016 -2835 -1412 -1632 -885 580 845 381 553 -38 292 1178 1687 1264 2288 1440 -2836 -1804 -2525 -3026 259 1854 956 394 627 -584 -542 -1032 -893 -433 484 1122 217 1365 1113 1424 722 -1948 -1510 -2320 -2903 -1124 -332 863 -61 681 101 23 197 406 316 789 855 187 419 457 -953 -1524 -1105 -544 -294 2003 1106 -221 -949 -882 -829 -1425 -387 272 -1273 -467 458 374 -519 143 -1153 -905 -125 1113 1604 1063 1171 1868 1242 12 -2082 -1975 -2921 -2042 -272 2081 1819 478 207 -1625 -1220 -513 -984 -230 548 326 368 287 1400 925 558 1339 -311 -458 -731 1081 -845 86 721 866 607 1908 244 88 -688 -1321 -2233 -857 198 -195 45 7 20 -8 376 1824 1273 1914 762 -1057 -1415 -2026 -946 -30 979 1126 -77 114 SQ 20241116T144805.0Z 9086.616724 345 1 5.91 2 64.82 147.39 106.26 322.49 0.00 1 0.00 1 0 92 1.219e-02 1.215e-02 1.117e-04 1.115e-04 1.142715e+03 5.830602e+00 8.434547e+01 -6.000000e+00 6.174794e+02 281.30 -2.00 20.00 -2.00 505.28 0.00e+00 2.371847e-04 2.960099e-06 1.166393e-04 -6.000000e+00 3.298346e-04 281.30 -2.00 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