File name: Pandora71s1_GreenbeltMD_20241204_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241205T054856.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241204_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241204T121933.9Z 9104.513587 35 1 54.21 2 89.31 119.92 123.51 99.36 0.00 1 0.00 1 0 113 1.639e-02 1.608e-02 4.991e-04 4.949e-04 9.048421e+03 2.954625e+01 6.449154e+02 -6.000000e+00 8.240848e+02 279.39 -2.00 20.00 -2.00 505.50 0.00e+00 5.946168e-03 1.330823e-05 1.254904e-04 -6.000000e+00 4.413432e-04 279.39 -2.00 20.00 -2.00 501.38 0.00e+00 1.203060e+00 8.643205e-03 6.755566e-02 -6.000000e+00 3.088481e-01 223.28 -2.00 3.47 -2.00 502.84 0.00e+00 19.451 0.130 489.00 513.00 1 2.4844e+00 6.6328e-04 3.3648e-02 -6.0000e+00 2.3580e-02 -6.3148e-02 1.5818e-04 1.8846e-03 -6.0000e+00 6.2369e-03 8.9019e-03 9.2727e-02 3.3677e-05 6.3928e-05 -6.0000e+00 1.1133e-03 -7.2720e-03 2.7597e-04 12 12 8 10 0 0 76.14 24.64 5.80 -0.00727 0.63592 191 21 1 2 0 283.424 19.60 24.64 1.82 25.00 25.00 7.2 967.05 2307 2811 2798 1798 917 1349 167 -1409 -1488 -1668 -1680 -1017 1163 1374 -27 499 335 67 1552 1599 1862 2362 1976 -2911 -2955 -2413 -2961 -1418 2524 1655 286 208 -479 -1242 -1641 -409 -714 553 1115 1769 1666 1495 1288 1144 -1138 -2532 -3536 -4178 -2451 -684 405 351 643 -389 -136 375 1300 1387 1490 1069 161 -77 19 -937 -2518 -1689 -1132 -952 783 977 -299 -1465 -1342 -1855 -2411 -1255 -1061 -1927 -850 40 -27 -769 -1336 -1337 -1032 -556 1454 3130 2347 1824 1826 709 -135 -2140 -3647 -3995 -3334 -1270 1655 1016 351 -511 -2326 -2219 -877 277 215 882 1389 796 1593 2769 3147 1713 1469 481 -777 -458 1265 484 662 1388 792 835 2631 474 -801 -756 -1737 -3069 -796 -78 -323 186 813 420 686 1369 1744 2079 1656 502 -1780 -2584 -2384 -1598 -185 1085 996 -101 -296 2101 2591 2587 1655 833 1213 150 -1257 -1322 -1494 -1521 -934 1091 1247 -24 455 308 62 1439 1497 1737 2194 1831 -2661 -2631 -2158 -2697 -1313 2412 1623 279 201 -464 -1202 -1594 -401 -676 529 1081 1731 1633 1457 1243 1092 -1074 -2348 -3265 -3873 -2301 -662 403 355 654 -397 -139 384 1275 1365 1464 1044 163 -77 19 -933 -2488 -1660 -1124 -953 789 945 -288 -1454 -1318 -1820 -2367 -1234 -1057 -1838 -812 39 -26 -750 -1298 -1296 -1002 -544 1434 3123 2335 1773 1737 695 -130 -2049 -3483 -3835 -3108 -1217 1643 1038 359 -522 -2371 -2256 -905 278 219 908 1440 833 1669 2931 3373 1836 1556 505 -809 -474 1324 514 704 1483 850 892 2815 510 -848 -797 -1846 -3275 -858 -83 -348 202 895 467 765 1530 1955 2328 1850 555 -1948 -2809 -2603 -1772 -208 1243 1153 -116 -340 SQ 20241204T122344.7Z 9104.516490 41 1 54.20 2 88.61 120.58 122.74 99.90 0.00 1 0.00 1 0 99 1.481e-02 1.463e-02 2.448e-04 2.438e-04 7.608504e+03 1.438110e+01 5.155432e+02 -6.000000e+00 7.449956e+02 279.39 -2.00 20.00 -2.00 505.45 0.00e+00 4.279986e-03 6.514029e-06 4.892243e-05 -6.000000e+00 3.989894e-04 279.39 -2.00 20.00 -2.00 501.15 0.00e+00 1.413127e+00 4.285212e-03 5.713889e-02 -6.000000e+00 2.792093e-01 223.28 -2.00 3.47 -2.00 502.65 0.00e+00 17.757 0.099 489.00 513.00 1 1.3886e+00 3.2880e-04 2.9109e-02 -6.0000e+00 2.1317e-02 -4.1971e-02 7.9286e-05 1.6417e-03 -6.0000e+00 5.6385e-03 3.3951e-02 9.2566e-02 1.6589e-05 4.7515e-05 -6.0000e+00 1.0065e-03 3.4625e-03 2.1013e-04 12 12 8 10 0 0 -20.10 24.71 3.35 0.00346 0.64554 529 57 1 2 0 102.099 20.33 24.71 2.00 25.00 25.00 7.2 967.82 1789 2091 2158 1197 505 1007 -17 -1477 -1588 -1704 -1643 -1052 1137 1057 -297 461 218 105 1477 1496 1694 2315 1953 -2713 -2534 -2111 -2661 -1243 2588 1589 285 428 -337 -1014 -1351 -382 -494 662 1101 1664 1621 1499 1364 1311 -1032 -2196 -3159 -3865 -2332 -703 521 325 614 -306 -149 225 1105 1139 1368 940 203 -48 163 -727 -2226 -1610 -775 -689 1046 1150 -106 -1157 -1200 -1471 -2229 -1052 -733 -1840 -636 90 30 -650 -1089 -1078 -949 -569 1357 2873 2081 1659 1851 876 -119 -2001 -3202 -3550 -2958 -985 1840 1103 419 -240 -2216 -2005 -735 172 19 600 1046 503 1335 2306 2764 1374 1290 376 -856 -560 1196 201 398 1218 601 729 2568 488 -867 -704 -1767 -2941 -849 -47 -383 -1 639 230 500 1166 1524 1991 1668 565 -1587 -2292 -2110 -1435 -140 1057 965 -105 -246 1668 1978 2047 1130 469 927 -16 -1344 -1439 -1555 -1514 -985 1088 1036 -292 453 207 100 1408 1438 1621 2201 1851 -2531 -2397 -2006 -2574 -1173 2521 1589 283 422 -331 -993 -1326 -378 -496 643 1084 1653 1608 1476 1328 1260 -1020 -2127 -3042 -3732 -2282 -681 518 329 624 -311 -151 229 1134 1172 1348 957 204 -48 160 -715 -2168 -1563 -757 -679 1039 1153 -105 -1130 -1161 -1417 -2153 -1018 -718 -1815 -629 90 29 -630 -1054 -1043 -920 -555 1335 2859 2065 1608 1825 847 -113 -1887 -3004 -3351 -2849 -938 1816 1120 426 -242 -2235 -2009 -747 172 19 614 1077 522 1385 2419 2926 1453 1345 388 -877 -570 1230 210 415 1274 630 761 2682 514 -896 -722 -1827 -3050 -891 -49 -405 -1 691 251 547 1280 1678 2188 1827 612 -1698 -2430 -2246 -1550 -153 1139 1050 -113 -265 SQ 20241204T122922.6Z 9104.520401 48 1 28.48 2 87.68 121.49 121.71 100.63 0.00 1 0.00 1 0 92 1.384e-02 1.369e-02 2.056e-04 2.052e-04 6.213075e+03 1.192295e+01 4.165605e+02 -6.000000e+00 6.963619e+02 279.39 -2.00 20.00 -2.00 505.41 0.00e+00 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