File name: Pandora71s1_GreenbeltMD_20241206_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20241207T051101.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20241206_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20241206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241206T121920.4Z 9106.513430 29 1 54.10 2 89.66 119.93 139.02 73.53 0.00 1 0.00 1 0 113 1.729e-02 1.697e-02 6.892e-04 6.804e-04 6.576902e+03 3.935824e+01 6.269421e+02 -6.000000e+00 8.689845e+02 279.18 -2.00 20.00 -2.00 505.54 0.00e+00 7.249357e-03 1.828650e-05 1.852556e-04 -6.000000e+00 4.655376e-04 279.18 -2.00 20.00 -2.00 501.56 0.00e+00 1.071595e+00 1.183254e-02 5.388117e-02 -6.000000e+00 3.259947e-01 223.25 -2.00 3.47 -2.00 502.98 0.00e+00 20.097 0.143 489.00 513.00 1 2.9824e+00 9.0796e-04 3.5525e-02 -6.0000e+00 2.4887e-02 -7.8903e-02 2.1606e-04 1.9401e-03 -6.0000e+00 6.5835e-03 4.9452e-03 9.2191e-02 4.6841e-05 7.1463e-05 -6.0000e+00 1.1749e-03 -9.8088e-03 2.8671e-04 12 12 8 10 0 0 94.56 24.28 7.88 -0.00981 0.62967 112 12 1 2 0 482.673 20.23 24.28 1.69 24.75 24.50 7.1 968.77 2668 3085 2878 2020 898 1320 160 -1382 -1639 -1755 -1693 -1105 1108 1580 216 512 510 285 1574 1955 2063 2576 2159 -2750 -3227 -2765 -3092 -1798 2303 1814 340 225 -516 -1280 -1601 -441 -556 650 1166 1935 1878 1502 1379 1304 -1082 -2837 -3595 -4453 -2826 -832 533 540 906 -287 -184 434 1505 1428 1672 1228 234 -137 -37 -841 -2460 -1883 -1082 -1087 791 986 -264 -1686 -1556 -1808 -2517 -1413 -945 -2132 -982 70 -12 -762 -1421 -1409 -1317 -925 1068 2950 2293 1697 1880 951 -325 -2336 -3595 -4132 -3503 -1269 1588 1246 438 -400 -2460 -2328 -938 126 381 1146 1574 1231 1880 2862 3318 1854 1610 526 -718 -611 1132 424 557 1356 825 722 2497 711 -804 -876 -1954 -3164 -1137 -52 -231 232 927 522 649 1478 1789 2269 1906 536 -1686 -2729 -2662 -1709 -266 1062 1142 -69 -362 2317 2715 2547 1778 781 1136 138 -1181 -1395 -1506 -1466 -971 993 1444 198 471 472 265 1473 1750 1846 2294 1921 -2419 -2923 -2517 -2711 -1604 2120 1712 320 211 -482 -1196 -1502 -418 -537 604 1098 1841 1792 1429 1299 1216 -999 -2722 -3429 -4272 -2610 -790 520 537 905 -288 -185 438 1527 1457 1703 1245 235 -137 -36 -830 -2409 -1837 -1064 -1080 789 994 -265 -1667 -1524 -1766 -2465 -1387 -938 -2132 -934 67 -11 -739 -1376 -1364 -1280 -906 1056 2956 2303 1675 1823 907 -305 -2290 -3503 -3853 -3320 -1228 1587 1274 448 -408 -2513 -2371 -970 127 392 1191 1654 1305 1999 3071 3593 2008 1723 561 -760 -646 1210 459 605 1480 903 790 2736 783 -874 -945 -2126 -3449 -1252 -57 -254 256 1039 590 735 1678 2039 2584 2165 604 -1875 -3016 -2960 -1927 -305 1238 1289 -81 -425 SQ 20241206T122321.5Z 9106.516221 35 1 24.72 2 88.99 120.56 138.29 74.35 0.00 1 0.00 1 0 106 1.507e-02 1.486e-02 5.381e-04 5.354e-04 5.238762e+03 3.039936e+01 4.733419e+02 -6.000000e+00 7.571048e+02 279.18 -2.00 20.00 -2.00 505.46 0.00e+00 5.035200e-03 1.434949e-05 7.313939e-05 -6.000000e+00 4.056012e-04 279.18 -2.00 20.00 -2.00 501.22 0.00e+00 1.337072e+00 9.374681e-03 4.379198e-02 -6.000000e+00 2.840231e-01 223.25 -2.00 3.47 -2.00 502.71 0.00e+00 18.709 0.115 489.00 513.00 1 2.0945e+00 7.1985e-04 3.1398e-02 -6.0000e+00 2.1683e-02 -5.4209e-02 1.7339e-04 1.7227e-03 -6.0000e+00 5.7359e-03 1.4708e-02 9.2165e-02 3.6769e-05 4.7413e-05 -6.0000e+00 1.0237e-03 -1.9017e-03 2.3858e-04 12 13 9 12 1 1 -3.24 24.35 4.46 -0.00190 0.63739 103 24 1 2 0 237.368 19.99 24.35 1.66 24.75 24.75 7.2 969.32 1841 2181 2218 1431 495 949 99 -1536 -1599 -1785 -1720 -1163 1114 1141 -47 446 361 26 1526 1566 1829 2319 2103 -2558 -2621 -2148 -2715 -1478 2495 1658 409 347 -369 -1092 -1496 -342 -604 657 1182 1745 1622 1565 1307 1267 -950 -2287 -3221 -4077 -2436 -880 487 434 576 -198 -127 169 1166 1313 1502 1024 330 33 94 -611 -2096 -1671 -849 -678 1086 1142 87 -1268 -1255 -1473 -2238 -1048 -649 -1807 -679 140 9 -677 -1101 -1135 -993 -738 1024 2694 2054 1501 1849 851 -208 -2050 -3098 -3565 -2950 -1019 1821 1308 436 -93 -2198 -1975 -882 140 -3 838 1212 727 1434 2413 2733 1332 1328 413 -916 -660 1117 206 366 1029 561 681 2502 630 -799 -723 -1801 -2903 -1000 27 -311 -10 647 238 445 1196 1662 2106 1832 713 -1568 -2354 -2198 -1472 -214 959 958 -66 -259 1743 2011 2051 1316 468 888 93 -1423 -1473 -1658 -1549 -1064 1039 1090 -45 427 348 25 1483 1477 1719 2168 1961 -2443 -2434 -2004 -2579 -1374 2393 1634 402 337 -359 -1058 -1453 -335 -579 635 1158 1725 1607 1539 1272 1218 -903 -2214 -3100 -3940 -2295 -856 486 440 567 -195 -125 167 1161 1310 1495 1014 322 33 94 -607 -2063 -1640 -840 -676 1050 1117 85 -1211 -1232 -1441 -2197 -1031 -624 -1749 -657 137 9 -670 -1088 -1123 -985 -739 1034 2663 2032 1511 1828 828 -199 -1942 -2915 -3374 -2840 -1006 1791 1317 439 -93 -2197 -1962 -890 144 -3 859 1254 759 1500 2543 2903 1413 1389 429 -946 -679 1162 218 386 1091 595 720 2646 670 -837 -752 -1885 -3041 -1059 28 -334 -11 709 263 493 1327 1793 2271 2033 783 -1699 -2525 -2367 -1609 -230 1051 1061 -73 -284 SQ 20241206T122722.1Z 9106.519005 41 1 54.15 2 88.32 121.20 137.57 75.16 0.00 1 0.00 1 0 113 1.418e-02 1.399e-02 2.201e-04 2.194e-04 4.382431e+03 1.229596e+01 3.922192e+02 -6.000000e+00 7.124937e+02 279.18 -2.00 20.00 -2.00 505.43 0.00e+00 3.988603e-03 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