File name: Pandora71s1_GreenbeltMD_20250328_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20250508T224557.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20250328_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250328 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250328T110412.4Z 9218.461255 22 1 53.68 2 89.58 86.24 84.39 98.74 0.00 1 0.00 1 0 155 2.210e-02 2.146e-02 1.964e-03 1.929e-03 1.372520e+04 1.202222e+02 7.237875e+02 -6.000000e+00 1.111641e+03 279.34 -2.00 20.00 -2.00 505.57 0.00e+00 6.744495e-03 5.224822e-05 1.974152e-04 -6.000000e+00 5.948839e-04 279.34 -2.00 20.00 -2.00 501.72 0.00e+00 7.575722e-01 3.357348e-02 9.079521e-02 -6.000000e+00 4.188687e-01 227.35 -2.00 3.47 -2.00 503.10 0.00e+00 19.957 0.140 489.00 513.00 1 4.7830e+00 2.5766e-03 3.5556e-02 -6.0000e+00 3.1958e-02 -1.0283e-01 6.0430e-04 2.0684e-03 -6.0000e+00 8.4697e-03 8.4993e-04 9.7908e-02 1.2824e-04 7.4605e-05 -6.0000e+00 1.5018e-03 2.1464e-03 1.6124e-04 12 13 9 12 4 4 96.11 31.47 13.64 0.00215 0.68128 22 2 1 2 0 2439.636 20.07 31.47 12.68 27.00 27.25 8.1 1001.55 4425 4870 4291 2875 2019 1808 -289 -1770 -1587 -1702 -1717 -79 2040 1716 715 948 403 587 2641 2342 2214 2582 555 -4240 -3863 -3871 -3393 -751 3081 1726 -142 213 -749 -2257 -1538 -136 -199 439 1836 2477 2441 1543 1417 287 -2280 -3456 -5162 -4727 -2332 -307 428 504 882 31 608 960 1871 1864 1694 484 -249 -372 -419 -1718 -3222 -2249 -1789 -1007 296 484 -1439 -2420 -2709 -2874 -3149 -1698 -1720 -2742 -1316 -120 -726 -1319 -2174 -1536 -804 80 3094 4026 2673 2664 1515 38 -1061 -3389 -5156 -5694 -4372 -1467 1756 837 -77 -1343 -3524 -2220 -345 382 759 1540 2020 1591 2803 4165 4074 2449 1714 546 -928 242 2272 720 1508 2155 1198 1489 2943 449 -427 -884 -2660 -2957 -503 168 22 892 1554 732 1194 1779 2533 2524 2082 -302 -2548 -3197 -2913 -1752 -134 1087 780 -517 -927 3754 4172 3698 2465 1715 1533 -246 -1500 -1343 -1453 -1484 -69 1715 1467 613 817 350 512 2312 2072 1961 2286 493 -3706 -3320 -3372 -2982 -673 2838 1620 -134 199 -700 -2124 -1448 -129 -182 408 1715 2333 2297 1454 1323 267 -2097 -3142 -4716 -4321 -2164 -293 420 501 879 31 606 966 1897 1895 1725 492 -250 -370 -416 -1703 -3181 -2222 -1784 -1010 300 492 -1456 -2414 -2691 -2841 -3112 -1682 -1723 -2622 -1266 -117 -709 -1284 -2116 -1480 -774 77 3011 3956 2600 2509 1477 36 -1005 -3213 -4905 -5492 -4087 -1415 1751 859 -80 -1393 -3661 -2294 -362 409 819 1672 2092 1656 2928 4420 4396 2649 1838 580 -977 253 2395 774 1622 2334 1301 1618 3210 490 -458 -955 -2919 -3254 -563 192 26 1040 1750 836 1369 2046 2902 2894 2376 -345 -3037 -3626 -3333 -2031 -158 1301 943 -626 -1124 SQ 20250328T110828.3Z 9218.464217 28 1 53.23 2 88.76 86.91 83.59 99.39 0.00 1 0.00 1 0 127 1.982e-02 1.934e-02 3.407e-03 3.348e-03 1.219419e+04 2.111437e+02 5.740074e+02 -6.000000e+00 9.967003e+02 279.34 -2.00 20.00 -2.00 505.60 0.00e+00 5.347554e-03 9.018820e-05 1.183197e-04 -6.000000e+00 5.335562e-04 279.34 -2.00 20.00 -2.00 501.66 0.00e+00 9.969487e-01 5.854375e-02 8.166881e-02 -6.000000e+00 3.758408e-01 227.35 -2.00 3.47 -2.00 503.07 0.00e+00 18.123 0.105 489.00 513.00 1 6.0124e+00 4.4874e-03 3.0432e-02 -6.0000e+00 2.8673e-02 -9.5849e-02 1.0492e-03 1.8185e-03 -6.0000e+00 7.6040e-03 3.2188e-04 9.8138e-02 2.2360e-04 5.5444e-05 -6.0000e+00 1.3481e-03 -1.8619e-02 2.5028e-04 12 13 9 12 4 4 98.36 31.38 12.11 -0.01862 0.66211 14 2 1 2 0 3801.535 20.11 31.38 12.76 27.25 27.50 8.1 1002.03 2459 3468 3453 1998 1009 1645 55 -2274 -1899 -2035 -1617 -736 2466 1160 668 1322 536 -45 2574 2269 1560 1856 1320 -3423 -3949 -3005 -3301 -499 2781 1019 380 -196 -985 -1371 -1371 -488 -302 1135 1722 2650 1798 1732 1251 723 -1926 -2680 -4285 -4718 -2519 -24 703 1154 95 -869 364 1224 1792 1752 1622 240 112 -25 -67 -1478 -3179 -1368 -1322 -820 910 700 -401 -2215 -2454 -2825 -2249 -2116 -1645 -2378 -837 655 -486 -866 -1111 -1980 -1470 416 2710 4479 3029 2018 1928 349 -1093 -3677 -4704 -4659 -3233 -1268 1849 -93 604 -974 -3275 -2339 -468 -237 1006 1859 1603 882 2389 3526 3264 2460 1047 178 -1201 328 1812 -17 1302 1494 912 801 2738 182 -413 -554 -2479 -3579 -836 -247 -767 535 1424 934 1065 1591 2125 2718 2651 -173 -2175 -2398 -3047 -1871 -230 1142 276 -9 -675 2086 2958 2949 1701 851 1374 46 -1905 -1584 -1712 -1371 -635 2154 1043 599 1187 486 -41 2349 2091 1446 1720 1211 -3091 -3528 -2694 -3006 -461 2660 941 347 -179 -898 -1244 -1249 -450 -282 1070 1643 2542 1736 1660 1192 682 -1797 -2455 -3935 -4361 -2363 -23 694 1150 96 -882 367 1235 1827 1791 1659 245 113 -25 -66 -1466 -3144 -1341 -1314 -821 918 672 -380 -2086 -2434 -2793 -2203 -2105 -1556 -2262 -799 629 -473 -840 -1072 -1921 -1428 402 2642 4377 2939 1917 1781 317 -984 -3515 -4232 -4222 -2990 -1219 1840 -97 620 -1005 -3383 -2404 -487 -253 1073 1991 1736 964 2468 3701 3489 2611 1111 187 -1246 355 1883 -18 1374 1592 972 856 2923 195 -433 -582 -2651 -3862 -914 -277 -872 610 1646 1090 1252 1878 2506 3189 3088 -203 -2522 -2761 -3568 -2217 -277 1393 325 -11 -832 SQ 20250328T113436.9Z 9218.482372 51 1 54.09 2 83.67 91.01 78.68 103.43 0.00 1 0.00 1 0 99 1.301e-02 1.291e-02 5.164e-04 5.157e-04 5.347553e+03 2.977600e+01 3.309609e+02 -6.000000e+00 6.548030e+02 279.34 -2.00 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