File name: Pandora71s1_GreenbeltMD_20250509_L2Fit_fout2c1d20220202p1-8.txt File generation date: 20250510T051434.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20250509_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0745 305.2151 305.3557 305.4964 305.6370 305.7776 305.9182 306.0587 306.1993 306.3399 306.4804 306.6209 306.7615 306.9020 307.0425 307.1830 307.3234 307.4639 307.6043 307.7448 307.8852 308.0256 308.1660 308.3064 308.4468 308.5872 308.7276 308.8679 309.0083 309.1486 309.2889 309.4292 309.5695 309.7098 309.8501 309.9903 310.1306 310.2708 310.4110 310.5512 310.6914 310.8316 310.9718 311.1120 311.2521 311.3923 311.5324 311.6725 311.8126 311.9527 312.0928 312.2329 312.3730 312.5130 312.6531 312.7931 312.9331 313.0731 313.2131 313.3531 313.4931 313.6330 313.7730 313.9129 314.0529 314.1928 314.3327 314.4726 314.6124 314.7523 314.8922 315.0320 315.1718 315.3117 315.4515 315.5913 315.7311 315.8708 316.0106 316.1503 316.2901 316.4298 316.5695 316.7092 316.8489 316.9886 317.1283 317.2679 317.4076 317.5472 317.6868 317.8264 317.9660 318.1056 318.2452 318.3848 318.5243 318.6639 318.8034 318.9429 319.0824 319.2219 319.3614 319.5009 319.6403 319.7798 319.9192 320.0586 320.1980 320.3374 320.4768 320.6162 320.7555 320.8949 321.0342 321.1736 321.3129 321.4522 321.5915 321.7307 321.8700 322.0093 322.1485 322.2877 322.4269 322.5662 322.7054 322.8445 322.9837 323.1229 323.2620 323.4011 323.5403 323.6794 323.8185 323.9576 324.0966 324.2357 324.3747 324.5138 324.6528 324.7918 324.9308 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250509T183112.4Z 9260.771672 446 1 1.30 2 28.63 227.76 124.26 72.17 0.00 1 0.00 1 0 57 2.937e-02 2.418e-02 9.938e-03 7.865e-03 1.878408e-01 3.738502e-03 1.325428e-03 -6.000000e+00 1.551246e-02 230.68 -2.00 3.47 -2.00 314.15 0.00e+00 9.919994e-04 2.687279e-04 3.431242e-05 -6.000000e+00 6.221352e-04 283.76 -2.00 20.00 -2.00 313.88 0.00e+00 1.139 0.000 302.00 328.00 3 3.0705e+00 9.6223e-03 1.3697e-02 -6.0000e+00 3.9195e-02 7.2257e-02 1.0874e-02 7.2586e-03 -6.0000e+00 4.2869e-02 -1.5690e-02 6.1793e-03 3.3220e-03 -6.0000e+00 2.5135e-02 8.4174e-04 2.5587e-03 9.0325e-04 -6.0000e+00 1.0621e-02 6.5674e-03 4.8641e-02 1.6471e-04 3.1133e-06 -6.0000e+00 5.9080e-04 6.1139e-02 0.0000e+00 12 9 9 12 5 5 999.00 34.45 1.19 0.06114 0.42665 1 9 1 8 0 650.133 20.03 34.45 20.40 28.25 28.50 8.8 997.55 -4224 -9882 -5428 -3589 7161 1350 658 -4450 -7938 -505 -1876 1814 4612 383 3472 1342 3709 5205 -5003 3299 2050 2616 2132 1439 -1644 -4279 -3528 4991 -1442 2972 3951 -8130 -5004 -4243 -2150 251 2214 -446 1173 -516 21 -275 1802 2134 714 -1118 -3036 1594 3391 664 2867 -215 -1103 2229 -502 -199 -1112 -2520 1054 1937 4149 2837 -782 -2627 -6822 -1603 1757 458 1986 1004 2651 -61 26 -1905 -5792 -4217 -2754 -3171 -87 -2876 -4213 -1837 -1647 2315 334 4405 3469 1343 1800 -2079 -2450 -2292 -1634 -1787 3983 3437 1314 746 -2022 -5195 -3001 1519 -1400 24 -481 -2291 1499 960 3389 1615 1715 -1215 -2546 -2110 -4099 -289 1055 1663 1023 2397 1730 571 2328 -2955 -1645 -618 403 1957 -493 -1059 -2481 869 540 -235 2141 3889 576 1096 -403 -3331 -23 -2137 -969 -1851 -3989 -2043 -1395 2901 603 295 -2004 -3454 -237 -947 955 2595 218 1911 769 2146 3082 -3056 1902 1206 1593 1350 920 -972 -2485 -1944 2746 -877 1819 2522 -4881 -2964 -2666 -1462 188 1775 -377 993 -444 18 -231 1511 1769 575 -886 -2455 1268 2865 572 2489 -194 -1004 2035 -448 -177 -990 -2251 990 1889 4123 2861 -719 -2343 -6129 -1443 1679 465 2005 1017 2625 -59 23 -1634 -4880 -3615 -2547 -3067 -87 -3077 -4460 -2021 -1907 2646 402 5133 4043 1485 1916 -2067 -2375 -2306 -1759 -2000 4588 4199 1579 855 -2291 -5596 -3287 1750 -1649 30 -599 -2913 1966 1271 4553 2129 2137 -1473 -2932 -2442 -4897 -353 1350 2140 1323 3070 2145 698 2736 -3407 -1895 -731 503 2460 -625 -1354 -3264 1176 757 -326 3010 5465 831 1513 -561 -4543 -31 -3057 -1438 SS 20250509T183859.2Z 9260.777075 451 1 2.69 2 29.78 230.75 122.89 73.67 0.00 1 0.00 1 0 81 2.863e-02 2.414e-02 1.574e-03 1.221e-03 1.798246e-01 5.821720e-04 1.651329e-03 -6.000000e+00 1.535604e-02 230.68 -2.00 3.47 -2.00 314.26 0.00e+00 1.118729e-03 4.269164e-05 3.247571e-05 -6.000000e+00 6.102043e-04 283.76 -2.00 20.00 -2.00 314.01 0.00e+00 1.152 0.000 302.00 328.00 3 7.4309e-01 1.5002e-03 1.4468e-02 -6.0000e+00 3.8827e-02 2.6929e-02 1.6882e-03 8.3766e-03 -6.0000e+00 4.2235e-02 8.6966e-04 9.6205e-04 3.9142e-03 -6.0000e+00 2.4748e-02 -4.6412e-03 4.1148e-04 1.0690e-03 -6.0000e+00 1.0732e-02 6.7960e-02 4.5480e-02 2.5787e-05 5.1023e-06 -6.0000e+00 5.8105e-04 8.5779e-02 0.0000e+00 12 9 9 12 5 5 98.74 34.47 1.47 0.08578 0.42754 47 104 1 8 0 55.636 20.03 34.47 21.18 28.25 28.75 8.8 1000.92 -2461 -7605 -4468 -3707 3824 3168 1955 -7568 -6295 161 -138 3568 4449 -523 2444 605 3030 3913 -1696 1338 1482 932 1808 1918 -1687 -3130 -3150 2394 -1107 5236 2916 -8985 -6191 -6018 -3603 750 2486 330 -703 1425 -83 652 2263 693 247 -1750 -2566 907 1005 542 3180 12 -438 2266 479 -1051 -1228 -1717 897 1635 4959 3849 -2671 -1351 -7074 -3317 2075 1261 2510 972 2970 1396 -909 -2250 -7457 -4624 -1427 -2404 -628 -1982 -4061 -890 103 1879 1478 3707 3375 1302 1991 -3504 -4264 -2258 -1684 -1389 2770 3872 2215 976 -2239 -4318 -3067 1488 -2262 -329 -441 -1249 1055 2052 3117 1469 1842 -950 -3598 -2579 -3541 -832 632 776 827 1692 1658 941 2814 -3221 -1794 66 442 1510 -326 -635 -2596 567 1298 -757 2271 2837 1197 1282 -256 -2700 -1248 -2225 900000 -994 -2821 -1673 -1360 1511 1312 863 -3318 -2696 71 -68 1838 2372 -285 1352 347 1759 2230 -954 749 875 575 1095 1163 -999 -1804 -1738 1359 -642 3141 1798 -5451 -3561 -3696 -2390 539 1985 276 -584 1199 -71 543 1891 564 201 -1401 -1998 729 842 468 2758 11 -384 2005 424 -947 -1102 -1533 823 1562 4920 3747 -2515 -1198 -6208 -2964 1990 1275 2536 991 2959 1365 -825 -1967 -6266 -3908 -1321 -2336 -643 -2062 -4336 -980 118 2180 1780 4402 3884 1460 2089 -3593 -4154 -2310 -1790 -1572 3275 4649 2672 1131 -2512 -4696 -3433 1748 -2741 -400 -560 -1601 1381 2735 4169 1925 2333 -1141 -4274 -3064 -4296 -1042 831 1031 1070 2180 2111 1145 3386 -3834 -2074 80 551 1908 -423 -830 -3420 771 1810 -1087 3277 4143 1722 1821 -358 -3785 -1743 -3214 900000 SS 20250509T184257.3Z 9260.779830 454 1 5.16 2 30.38 232.21 122.18 74.42 0.00 1 0.00 1 0 57 2.834e-02 2.391e-02 1.349e-03 1.034e-03 1.809065e-01 4.922140e-04 1.673173e-03 -6.000000e+00 1.519434e-02 230.68 -2.00 3.47 -2.00 314.33 0.00e+00 1.146918e-03 3.648632e-05 3.315300e-05 -6.000000e+00 6.039091e-04 283.76 -2.00 20.00 -2.00 314.08 0.00e+00 1.159 0.000 302.00 328.00 3 1.0384e+00 1.2702e-03 1.4584e-02 -6.0000e+00 3.8418e-02 3.0579e-02 1.4299e-03 8.4706e-03 -6.0000e+00 4.1792e-02 1.0073e-03 8.1494e-04 3.9626e-03 -6.0000e+00 2.4489e-02 -5.0359e-03 3.4904e-04 1.0852e-03 -6.0000e+00 1.0619e-02 5.0043e-02 4.5045e-02 2.1885e-05 5.1508e-06 -6.0000e+00 5.7494e-04 8.7141e-02 0.0000e+00 12 9 9 12 5 5 99.65 34.62 1.48 0.08714 0.42563 73 83 1 8 0 69.355 20.04 34.62 21.59 28.50 28.75 8.8 1002.67 -2015 -7789 -4227 -3460 3186 2606 1880 -7278 -6271 339 -513 3800 4163 -1144 2493 486 3411 4335 -1286 1304 1551 425 1937 1867 -1728 -3301 -3613 2218 -851 5132 2860 -8919 -6359 -5907 -3211 1015 2429 472 -585 1320 77 421 2051 615 253 -1624 -2604 929 1221 429 2881 -84 103 1992 382 -1196 -989 -1837 646 1691 4907 4043 -2749 -1091 -6832 -3153 1839 1335 2478 1126 3001 1693 -853 -2065 -7349 -4761 -1463 -2460 -630 -1924 -4145 -921 -72 1702 1599 3514 3352 1270 1947 -3413 -4540 -2239 -1762 -1207 2543 3936 2551 924 -2127 -4469 -3005 1308 -1983 -187 -663 -1309 960 2136 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