File name: Pandora71s1_GreenbeltMD_20250522_L2Fit_fout2c1d20220202p1-8.txt File generation date: 20250523T051751.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20250522_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0745 305.2151 305.3557 305.4964 305.6370 305.7776 305.9182 306.0587 306.1993 306.3399 306.4804 306.6209 306.7615 306.9020 307.0425 307.1830 307.3234 307.4639 307.6043 307.7448 307.8852 308.0256 308.1660 308.3064 308.4468 308.5872 308.7276 308.8679 309.0083 309.1486 309.2889 309.4292 309.5695 309.7098 309.8501 309.9903 310.1306 310.2708 310.4110 310.5512 310.6914 310.8316 310.9718 311.1120 311.2521 311.3923 311.5324 311.6725 311.8126 311.9527 312.0928 312.2329 312.3730 312.5130 312.6531 312.7931 312.9331 313.0731 313.2131 313.3531 313.4931 313.6330 313.7730 313.9129 314.0529 314.1928 314.3327 314.4726 314.6124 314.7523 314.8922 315.0320 315.1718 315.3117 315.4515 315.5913 315.7311 315.8708 316.0106 316.1503 316.2901 316.4298 316.5695 316.7092 316.8489 316.9886 317.1283 317.2679 317.4076 317.5472 317.6868 317.8264 317.9660 318.1056 318.2452 318.3848 318.5243 318.6639 318.8034 318.9429 319.0824 319.2219 319.3614 319.5009 319.6403 319.7798 319.9192 320.0586 320.1980 320.3374 320.4768 320.6162 320.7555 320.8949 321.0342 321.1736 321.3129 321.4522 321.5915 321.7307 321.8700 322.0093 322.1485 322.2877 322.4269 322.5662 322.7054 322.8445 322.9837 323.1229 323.2620 323.4011 323.5403 323.6794 323.8185 323.9576 324.0966 324.2357 324.3747 324.5138 324.6528 324.7918 324.9308 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250522T124510.3Z 9273.531370 216 1 54.06 2 57.92 88.61 40.35 175.22 0.00 1 0.00 1 0 65 4.191e-02 2.237e-02 1.625e-02 4.252e-03 2.769484e-01 1.997266e-03 1.700279e-03 -6.000000e+00 2.250336e-02 231.52 -2.00 3.47 -2.00 317.87 0.00e+00 1.431191e-03 3.210033e-04 1.028238e-04 -6.000000e+00 8.926862e-04 285.06 -2.00 20.00 -2.00 317.54 0.00e+00 1.876 0.000 302.00 328.00 3 4.3984e+00 5.3613e-03 2.1203e-02 -6.0000e+00 5.7014e-02 4.5034e-03 6.0879e-03 9.7532e-03 -6.0000e+00 6.2010e-02 1.2852e-02 3.8962e-03 4.6262e-03 -6.0000e+00 3.6316e-02 -3.7952e-03 1.9847e-03 1.3654e-03 -6.0000e+00 1.5697e-02 7.3677e-04 4.3944e-02 9.5679e-05 8.9040e-07 -6.0000e+00 8.4842e-04 9.7229e-02 0.0000e+00 12 9 9 12 4 4 99.96 -62.18 2.11 0.09723 0.42744 43 5 1 8 0 1256.822 19.98 -62.18 18.17 28.25 28.75 8.9 984.06 -12337 -16939 -7249 -6433 7702 1824 12416 -14823 -15541 495 -2791 2833 2839 -1797 1010 -3441 2197 2909 -4245 4172 1832 2028 2138 1969 -2451 -4899 -2480 2438 503 3209 3392 -10240 -14215 -6852 -3854 3910 4092 1141 1064 1029 12 1336 2421 -521 2120 -1790 -3279 2524 1430 539 2772 701 -904 1510 549 -1886 -823 -2271 928 2548 4363 3545 -3031 -1021 -6384 -3696 2456 889 3006 1207 1997 1469 -1013 -3762 -7309 -4559 -2087 -2673 -732 -1792 -3952 256 -156 1607 1216 4296 2652 1460 1077 -3680 -4402 -3000 -2004 -1234 2616 3634 1953 574 -2754 -4957 -2691 2085 -2290 388 -544 -1064 975 2289 2700 522 1066 -1592 -4335 -2525 -3490 -433 893 581 531 1358 1700 348 2323 -3594 -2111 88 53 1477 -676 -696 -2980 975 1171 -865 2356 3015 1308 1060 -638 -2837 -752 -1732 900000 -1141 -1362 -523 -491 597 167 1091 -1573 -1695 55 -373 418 473 -312 182 -672 424 581 -854 801 386 448 493 460 -543 -1032 -499 527 118 825 928 -2704 -3825 -1929 -1229 1430 1613 499 479 483 6 621 1143 -246 949 -821 -1500 1183 742 293 1589 417 -552 937 339 -1153 -494 -1417 616 1824 3348 2786 -2197 -682 -4276 -2576 1952 713 2461 998 1575 1086 -734 -2518 -4717 -3019 -1599 -2113 -633 -1681 -3823 260 -172 1837 1443 4977 3016 1522 1038 -3290 -3801 -2775 -2060 -1396 3215 4816 2546 701 -3151 -5301 -2916 2500 -2925 509 -752 -1536 1497 3414 4111 772 1581 -2194 -5634 -3264 -4742 -620 1370 917 813 2014 2424 467 2998 -4464 -2567 117 76 2208 -1051 -1094 -4892 1683 2136 -1620 4425 5714 2433 1891 -1114 -4814 -1301 -3198 900000 SS 20250522T160708.1Z 9273.671622 341 1 54.40 2 22.16 142.35 57.78 238.82 0.00 1 0.00 1 0 49 3.546e-02 2.714e-02 1.842e-02 9.280e-03 1.803350e-01 4.384171e-03 1.510614e-03 -6.000000e+00 1.907866e-02 231.53 -2.00 3.47 -2.00 316.14 0.00e+00 5.718606e-04 4.599186e-04 4.780739e-05 -6.000000e+00 7.557370e-04 285.08 -2.00 20.00 -2.00 315.78 0.00e+00 1.080 0.000 302.00 328.00 3 6.4565e+00 1.1545e-02 1.3629e-02 -6.0000e+00 4.8339e-02 4.5567e-02 1.3047e-02 7.9125e-03 -6.0000e+00 5.2545e-02 1.6698e-02 7.5814e-03 3.7239e-03 -6.0000e+00 3.0768e-02 -1.2983e-02 3.4903e-03 1.0471e-03 -6.0000e+00 1.3318e-02 2.3730e-04 4.4087e-02 2.0879e-04 2.4582e-06 -6.0000e+00 7.1975e-04 8.5373e-02 0.0000e+00 12 9 9 12 4 4 99.96 -62.18 4.26 0.08537 0.41666 16 2 1 8 0 3399.217 20.01 -62.18 23.98 28.50 28.75 9.2 1007.52 -6761 -4659 -6235 -2376 627 4397 -418 -10387 -3750 -1939 3119 -354 8428 -5741 7619 2874 5105 -3711 256 2330 3800 58 2580 -478 -2018 -4454 -1960 -1713 -4852 2137 1779 -5870 -7451 -8228 -3119 8503 2596 815 -868 -1297 1150 354 6271 -1156 -469 785 -3157 185 480 -428 2664 -328 842 3554 56 -2634 -977 534 -113 1652 3648 3350 -1846 -669 -11950 -4107 3138 1208 3973 -312 1017 2080 48 -2978 -8855 -7590 -2685 -3070 -2193 -374 -5990 -486 1827 2978 1048 4847 3797 -20 3146 -3084 -4197 -4079 -2071 -1338 2750 4495 2975 1015 -2658 -3859 -4685 3230 -2466 686 -636 -462 -2 3638 2050 744 692 -1104 -4918 -3452 -4876 -2447 789 1355 125 1220 587 -113 3222 -2374 -3592 -311 -731 1696 702 -1483 -1672 327 1359 633 2406 3104 1932 1038 -1516 -1571 -2027 -2064 900000 -1468 -808 -1063 -410 122 918 -98 -2444 -803 -472 807 -108 2599 -1987 2401 973 1744 -1449 90 817 1396 23 1039 -201 -775 -1595 -649 -610 -1858 831 746 -2231 -2742 -3425 -1418 4238 1627 558 -616 -955 832 252 4289 -818 -314 504 -2021 122 342 -316 2033 -261 662 2827 45 -2127 -769 422 -90 1401 3252 3036 -1507 -535 -9250 -3047 2623 1119 3725 -307 949 1811 37 -2300 -6617 -5684 -2069 -2639 -2058 -370 -6275 -526 2098 3561 1327 5951 4574 -22 3162 -2886 -3698 -3813 -2105 -1482 3256 5710 3717 1193 -2971 -3997 -5031 3733 -3096 873 -857 -637 -3 5422 3162 1097 945 -1377 -5785 -4345 -5974 -3169 1084 1931 175 1661 777 -151 4060 -2880 -4277 -393 -988 2345 997 -2148 -2459 513 2237 1065 4093 5360 3282 1709 -2492 -2454 -3277 -3498 900000 SS 20250522T162253.1Z 9273.682559 352 1 3.08 2 20.48 151.40 60.33 242.18 0.00 1 0.00 1 0 49 2.891e-02 2.389e-02 7.346e-03 5.708e-03 1.784953e-01 2.720614e-03 1.334989e-03 -6.000000e+00 1.530540e-02 231.53 -2.00 3.47 -2.00 314.26 0.00e+00 1.355304e-03 1.993496e-04 3.174358e-05 -6.000000e+00 6.121981e-04 285.08 -2.00 20.00 -2.00 313.98 0.00e+00 1.067 0.000 302.00 328.00 3 3.6457e+00 7.0266e-03 1.3067e-02 -6.0000e+00 3.8750e-02 4.2190e-02 7.9306e-03 7.1793e-03 -6.0000e+00 4.2365e-02 -5.6671e-03 4.4978e-03 3.3031e-03 -6.0000e+00 2.4823e-02 -2.2551e-03 1.8682e-03 8.9728e-04 -6.0000e+00 1.0462e-02 4.0539e-03 4.6414e-02 1.2030e-04 3.3920e-06 -6.0000e+00 5.8295e-04 6.6186e-02 0.0000e+00 12 9 9 12 5 5 999.00 -62.18 1.39 0.06619 0.41496 2 6 1 8 0 1025.022 20.02 -62.18 25.67 28.50 29.00 9.2 1014.40 -1 -8657 -3491 -3363 2510 1455 4427 -5877 -7263 -2286 507 4874 5677 -628 2170 1025 3393 3997 -2164 -596 2805 1005 1839 2115 -2647 -2953 -1714 1622 -400 3275 4372 -9069 -7235 -6465 -2479 -631 2629 -476 -125 453 -108 -275 2463 -706 -410 -2006 -3531 438 1515 978 2722 773 -731 2075 1463 -387 -426 -1640 1156 1495 5229 4518 -2246 -1248 -6512 -4214 2261 1126 3038 1153 2597 711 86 -2561 -7611 -4999 -1896 -2562 -823 -1172 -3839 -940 732 1442 1545 4021 3296 947 1718 -3259 -4298 -2030 -1601 -1777 2429 4393 2727 1213 -1865 -4452 -3121 647 -879 -588 323 -970 -166 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