File name: Pandora71s1_GreenbeltMD_20250608_L2Fit_fout2c1d20220202p1-8.txt File generation date: 20250609T051529.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20250608_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0745 305.2151 305.3557 305.4964 305.6370 305.7776 305.9182 306.0587 306.1993 306.3399 306.4804 306.6209 306.7615 306.9020 307.0425 307.1830 307.3234 307.4639 307.6043 307.7448 307.8852 308.0256 308.1660 308.3064 308.4468 308.5872 308.7276 308.8679 309.0083 309.1486 309.2889 309.4292 309.5695 309.7098 309.8501 309.9903 310.1306 310.2708 310.4110 310.5512 310.6914 310.8316 310.9718 311.1120 311.2521 311.3923 311.5324 311.6725 311.8126 311.9527 312.0928 312.2329 312.3730 312.5130 312.6531 312.7931 312.9331 313.0731 313.2131 313.3531 313.4931 313.6330 313.7730 313.9129 314.0529 314.1928 314.3327 314.4726 314.6124 314.7523 314.8922 315.0320 315.1718 315.3117 315.4515 315.5913 315.7311 315.8708 316.0106 316.1503 316.2901 316.4298 316.5695 316.7092 316.8489 316.9886 317.1283 317.2679 317.4076 317.5472 317.6868 317.8264 317.9660 318.1056 318.2452 318.3848 318.5243 318.6639 318.8034 318.9429 319.0824 319.2219 319.3614 319.5009 319.6403 319.7798 319.9192 320.0586 320.1980 320.3374 320.4768 320.6162 320.7555 320.8949 321.0342 321.1736 321.3129 321.4522 321.5915 321.7307 321.8700 322.0093 322.1485 322.2877 322.4269 322.5662 322.7054 322.8445 322.9837 323.1229 323.2620 323.4011 323.5403 323.6794 323.8185 323.9576 324.0966 324.2357 324.3747 324.5138 324.6528 324.7918 324.9308 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250608T142910.6Z 9290.603595 298 1 54.22 2 37.01 104.02 161.48 341.01 0.00 1 0.00 1 0 57 3.014e-02 2.428e-02 9.457e-04 6.057e-04 1.720456e-01 2.879995e-04 1.579606e-03 -6.000000e+00 1.627102e-02 232.45 -2.00 3.47 -2.00 315.23 0.00e+00 1.166421e-03 2.525841e-05 3.878865e-05 -6.000000e+00 6.423117e-04 286.73 -2.00 20.00 -2.00 314.92 0.00e+00 1.251 0.000 302.00 328.00 3 1.9315e+00 7.5225e-04 1.5132e-02 -6.0000e+00 4.1317e-02 2.3992e-02 8.4752e-04 8.2039e-03 -6.0000e+00 4.4878e-02 5.0212e-03 4.8363e-04 3.8276e-03 -6.0000e+00 2.6259e-02 -7.6969e-03 2.1337e-04 1.0537e-03 -6.0000e+00 1.1344e-02 1.9186e-02 4.5901e-02 1.3099e-05 3.9364e-06 -6.0000e+00 6.1185e-04 8.4575e-02 0.0000e+00 12 9 8 11 4 0 99.73 26.66 1.40 0.08457 0.42950 362 39 1 8 0 149.386 20.00 26.66 28.25 30.25 30.75 9.4 1019.10 -3027 -8771 -4769 -3886 3032 2662 1636 -8037 -6724 -526 -692 3503 4037 -1547 2694 409 3205 3818 -2003 1252 1534 751 2003 1588 -2082 -3545 -3616 2142 -1262 5623 2848 -9648 -6626 -6203 -3544 1166 2964 408 -583 1203 132 674 2322 249 377 -1567 -2760 1019 1272 318 3046 -27 61 2026 151 -1442 -1212 -1672 957 1960 5054 4019 -3143 -1477 -7639 -3019 2322 1288 2651 983 3212 1203 -1142 -2504 -7931 -5136 -1664 -2233 -620 -2102 -4091 -706 208 2017 1596 3698 3379 1297 1712 -4083 -4763 -2439 -1804 -1241 3042 3947 2132 882 -2670 -4931 -3125 1458 -2054 -59 -517 -1202 1250 2264 3181 1489 1639 -1478 -3785 -2853 -3632 -936 731 849 993 1541 1409 976 2595 -3540 -1811 -89 392 1611 -467 -742 -2674 727 1396 -725 2362 2834 1175 1294 -539 -2760 -1143 -2101 900000 -873 -2204 -1239 -959 811 790 515 -2514 -2058 -176 -259 1431 1798 -706 1234 179 1415 1741 -903 562 724 371 1013 808 -986 -1559 -1662 925 -583 2675 1460 -4665 -3044 -3181 -2050 730 2141 321 -439 921 102 509 1759 184 288 -1177 -2024 769 960 249 2475 -23 52 1738 129 -1221 -1019 -1448 822 1801 4832 3871 -2765 -1265 -6495 -2601 2136 1290 2730 1023 3166 1133 -1035 -2049 -6245 -4078 -1491 -2080 -628 -2152 -4299 -786 234 2354 1933 4423 3914 1473 1774 -4163 -4615 -2475 -1889 -1418 3510 4873 2578 1061 -3036 -5308 -3452 1787 -2501 -74 -680 -1633 1676 3159 4455 1994 2138 -1897 -4543 -3434 -4581 -1180 991 1193 1360 2057 1811 1239 3174 -4163 -2206 -109 510 2175 -648 -1036 -3638 1044 2111 -1129 3702 4497 1838 1953 -803 -4015 -1698 -3309 900000 SS 20250608T143459.7Z 9290.607635 301 1 54.21 2 35.91 105.33 161.81 345.00 0.00 1 0.00 1 0 65 3.024e-02 2.412e-02 1.202e-03 7.525e-04 1.698373e-01 3.570728e-04 1.587540e-03 -6.000000e+00 1.632908e-02 232.45 -2.00 3.47 -2.00 315.35 0.00e+00 1.114409e-03 3.189979e-05 3.925141e-05 -6.000000e+00 6.444900e-04 286.73 -2.00 20.00 -2.00 315.04 0.00e+00 1.234 0.000 302.00 328.00 3 2.2267e+00 9.3437e-04 1.4994e-02 -6.0000e+00 4.1464e-02 2.9409e-02 1.0551e-03 8.2004e-03 -6.0000e+00 4.5037e-02 4.1194e-03 6.0214e-04 3.8281e-03 -6.0000e+00 2.6352e-02 -7.1794e-03 2.6531e-04 1.0580e-03 -6.0000e+00 1.1386e-02 1.4568e-02 4.6003e-02 1.6315e-05 4.3141e-06 -6.0000e+00 6.1394e-04 8.3471e-02 0.0000e+00 12 9 8 11 4 0 99.93 26.68 1.39 0.08347 0.42916 431 46 1 8 0 125.411 20.00 26.68 28.35 30.25 31.00 9.5 1020.42 -3296 -8675 -4550 -4137 3576 2678 2033 -8161 -6737 250 -487 3624 3857 -1430 2560 679 3030 3967 -2282 1373 1301 949 2125 1855 -1899 -3837 -3573 2110 -1519 5479 2819 -10001 -6858 -6217 -3130 1055 2797 433 -653 1318 45 504 2399 172 253 -1582 -2513 894 1247 391 3113 -157 -80 1962 87 -1525 -1248 -1886 944 1913 4885 4022 -3169 -1552 -7442 -3219 2232 1099 2686 1037 2832 1198 -1162 -2513 -7995 -5044 -1596 -2358 -691 -1960 -4059 -848 89 1770 1786 3542 3165 1167 1548 -4210 -4741 -2405 -1729 -1234 2976 3921 2156 680 -2728 -4784 -3235 1372 -2168 -147 -622 -1248 1205 2346 3198 1503 1488 -1526 -3883 -2954 -3681 -1049 753 896 1014 1579 1298 921 2614 -3696 -1989 -129 298 1713 -468 -584 -2613 735 1416 -635 2383 2927 1363 1352 -547 -2654 -1061 -2063 900000 -955 -2181 -1073 -1024 952 795 638 -2556 -2059 83 -165 1338 1555 -589 1060 292 1318 1777 -1015 605 605 460 1055 924 -882 -1661 -1475 893 -688 2551 1413 -4744 -3084 -3114 -1760 640 1960 330 -512 1050 36 397 1892 133 187 -1147 -1774 652 978 293 2422 -127 -65 1612 72 -1236 -1005 -1567 831 1802 4790 3967 -2854 -1270 -6025 -2649 2099 1046 2623 1023 2658 1153 -1005 -1960 -6001 -3807 -1360 -2241 -663 -2021 -4300 -953 100 2070 2159 4242 3674 1339 1619 -4060 -4670 -2302 -1819 -1417 3670 4827 2598 824 -3120 -5170 -3595 1692 -2634 -185 -815 -1689 1704 3447 4718 2119 1933 -1966 -4677 -3566 -4654 -1408 1015 1250 1381 2094 1778 1172 3201 -4361 -2277 -159 388 2311 -649 -814 -3772 1046 2120 -979 3699 4595 2108 2020 -807 -4092 -1671 -3215 900000 SS 20250608T144613.5Z 9290.615434 304 1 4.99 2 33.82 107.99 162.24 352.99 0.00 1 0.00 1 0 57 2.962e-02 2.531e-02 1.834e-03 1.454e-03 1.663260e-01 6.977843e-04 1.675111e-03 -6.000000e+00 1.599270e-02 232.45 -2.00 3.47 -2.00 314.11 0.00e+00 1.236074e-03 4.919885e-05 2.984624e-05 -6.000000e+00 6.312851e-04 286.73 -2.00 20.00 -2.00 313.86 0.00e+00 1.203 0.000 302.00 328.00 3 1.6515e+00 1.8042e-03 1.4910e-02 -6.0000e+00 4.0610e-02 3.3052e-02 2.0252e-03 8.4700e-03 -6.0000e+00 4.4110e-02 1.5922e-03 1.1542e-03 3.9427e-03 -6.0000e+00 2.5810e-02 -5.5334e-03 4.8959e-04 1.0648e-03 -6.0000e+00 1.1151e-02 2.6802e-02 4.5474e-02 3.0698e-05 5.9760e-06 -6.0000e+00 6.0135e-04 8.4191e-02 0.0000e+00 12 9 9 12 5 1 95.67 26.73 1.41 0.08419 0.42590 30 36 1 8 0 159.275 20.01 26.73 29.13 30.25 31.00 9.4 1022.86 -1174 -7838 -3601 -3652 3199 2099 2543 -7321 -6661 396 -208 3943 4402 -1243 2314 1098 3458 4025 -1933 1563 1497 1033 1972 1480 -1597 -3725 -3637 2255 -1328 5677 3213 -9570 -6564 -6268 -3802 792 2816 433 -399 1447 584 545 2484 657 344 -1288 -2659 944 1099 387 3068 -130 138 2036 268 -933 -1126 -1966 796 1887 4860 4552 -2781 -1401 -7265 -3122 2004 1265 2391 1223 3003 1583 -704 -2149 -7625 -5512 -1791 -2515 -569 -1902 -4300 -941 47 1858 1652 3704 3401 1478 1933 -3682 -4697 -2397 -1994 -1225 2786 4311 2252 1106 -2443 -4974 -3488 1347 -1914 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