File name: Pandora71s1_GreenbeltMD_20250723_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20250724T052326.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20250723_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20250723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250723T101923.4Z 9335.430132 88 1 52.65 2 87.55 66.10 70.55 70.56 0.00 1 0.00 1 0 113 1.898e-02 1.861e-02 1.997e-03 1.983e-03 1.579031e+04 1.346791e+02 4.701734e+02 -6.000000e+00 9.964953e+02 290.40 -2.00 20.00 -2.00 505.53 0.00e+00 3.061121e-03 5.513034e-05 2.686802e-05 -6.000000e+00 5.253194e-04 290.40 -2.00 20.00 -2.00 501.24 0.00e+00 1.279243e+00 3.508005e-02 7.841589e-02 -6.000000e+00 3.600078e-01 232.42 -2.00 3.47 -2.00 502.74 0.00e+00 14.790 0.057 489.00 513.00 1 5.6766e+00 2.7022e-03 2.3180e-02 -6.0000e+00 2.7567e-02 -8.9028e-02 6.3613e-04 1.5366e-03 -6.0000e+00 7.2950e-03 7.1777e-04 9.9970e-02 1.2877e-04 4.0412e-05 -6.0000e+00 1.2917e-03 6.6271e-03 8.9983e-05 12 13 9 12 4 4 24.14 38.88 9.29 0.00663 0.70006 14 2 1 2 0 3759.844 20.00 38.88 24.69 26.50 27.00 11.0 981.70 2999 3131 3254 894 698 718 -767 -2216 -1431 -1612 -1916 -258 2100 585 -65 963 171 651 2075 1439 2024 2612 68 -4054 -2983 -2682 -3325 201 2546 1610 503 -28 -812 -1748 -601 102 -215 1314 1999 2498 1868 1544 1092 455 -2348 -3295 -4385 -4168 -2014 443 640 569 943 9 672 1139 1779 1925 1701 591 -294 -257 -331 -1976 -2711 -1935 -1489 -628 378 542 -1055 -1701 -2650 -2994 -2633 -1473 -1061 -2507 -679 -466 -528 -767 -1435 -870 -80 660 3034 4237 2837 1997 1337 117 -558 -3722 -4447 -4780 -3888 -469 1445 285 -179 -1100 -2998 -1951 -288 101 261 939 1623 1392 2079 3030 3200 2064 1160 407 -762 -136 1850 541 1295 1905 602 1567 2518 -667 -853 -912 -2675 -2970 -41 -230 -158 552 989 1119 1377 1954 2205 2208 2046 -193 -2158 -2798 -2537 -1663 31 864 472 -589 -760 2769 2928 3039 838 646 663 -705 -2027 -1301 -1480 -1787 -244 2028 546 -61 898 161 611 1959 1371 1911 2460 64 -3748 -2702 -2453 -3099 190 2499 1596 496 -28 -797 -1714 -585 100 -215 1320 2027 2548 1908 1566 1100 452 -2306 -3188 -4226 -4026 -1979 445 626 562 932 8 661 1129 1776 1921 1697 587 -289 -249 -321 -1913 -2596 -1860 -1443 -612 374 536 -1030 -1633 -2546 -2863 -2501 -1407 -1019 -2444 -666 -465 -529 -763 -1424 -855 -79 652 3014 4198 2759 1887 1227 104 -494 -3333 -3970 -4345 -3652 -455 1473 283 -179 -1097 -2979 -1928 -288 103 267 962 1660 1425 2147 3198 3421 2199 1225 423 -779 -139 1901 564 1350 1995 633 1637 2649 -704 -879 -946 -2818 -3149 -44 -254 -176 592 1080 1227 1522 2164 2442 2443 2248 -212 -2353 -3053 -2790 -1853 35 994 547 -682 -879 SQ 20250723T102707.3Z 9335.435501 96 1 54.15 2 86.17 67.28 69.18 71.56 0.00 1 0.00 1 0 113 1.658e-02 1.632e-02 7.068e-04 7.046e-04 1.397144e+04 4.649550e+01 4.465254e+02 -6.000000e+00 8.709340e+02 290.40 -2.00 20.00 -2.00 505.44 0.00e+00 2.406378e-03 1.931448e-05 4.177468e-05 -6.000000e+00 4.590034e-04 290.40 -2.00 20.00 -2.00 500.99 0.00e+00 1.229544e+00 1.246938e-02 8.408151e-02 -6.000000e+00 3.144394e-01 232.42 -2.00 3.47 -2.00 502.53 0.00e+00 11.737 0.028 489.00 513.00 1 4.2553e+00 9.6054e-04 1.8142e-02 -6.0000e+00 2.4079e-02 -7.6711e-02 2.2956e-04 1.3832e-03 -6.0000e+00 6.3686e-03 4.6244e-03 9.9135e-02 4.6097e-05 3.6350e-05 -6.0000e+00 1.1277e-03 2.0464e-02 3.7958e-05 12 13 9 12 4 4 -20.08 38.63 4.66 0.02046 0.70811 65 7 1 2 0 832.590 20.00 38.63 25.08 26.50 27.00 10.9 982.23 2385 2550 2326 939 813 797 -722 -2145 -1751 -1732 -1774 -465 1693 565 -61 741 152 590 1812 1374 1519 2288 60 -3779 -2720 -2197 -2906 295 2623 1221 206 262 -531 -1190 -989 -205 103 1220 1784 1995 1694 1463 1429 498 -1934 -2566 -3799 -3742 -1671 -113 767 689 734 -202 198 825 1431 1537 1460 607 -98 -349 -222 -1566 -2558 -1493 -1117 -499 999 880 -995 -1532 -1739 -2091 -2571 -982 -1179 -1971 -246 -318 -52 -729 -1013 -547 -268 708 2894 3676 2373 2492 1491 606 -579 -2982 -3982 -4256 -3137 -446 1700 678 63 -983 -2681 -1719 -287 213 259 683 1128 525 1784 3062 2750 1481 1045 94 -1140 147 1467 396 1059 1606 361 1344 2491 -513 -1156 -774 -2722 -2634 -355 -73 -289 739 902 577 905 1473 1780 1909 1590 -247 -1751 -2406 -2248 -1437 153 1021 640 -224 -544 2349 2414 2206 885 756 777 -702 -2072 -1687 -1597 -1656 -442 1645 561 -60 736 152 588 1818 1386 1525 2286 60 -3679 -2594 -2110 -2843 294 2580 1218 204 257 -520 -1159 -965 -201 102 1220 1801 2030 1718 1471 1420 489 -1869 -2434 -3592 -3548 -1613 -112 779 709 756 -198 204 812 1419 1524 1445 596 -99 -351 -222 -1559 -2526 -1475 -1113 -501 966 853 -1002 -1514 -1705 -2041 -2514 -962 -1168 -1968 -236 -311 -51 -711 -984 -527 -259 686 2827 3596 2279 2419 1413 559 -530 -2736 -3653 -3971 -3013 -425 1692 694 64 -1007 -2727 -1739 -294 213 260 688 1135 531 1807 3151 2874 1543 1074 95 -1140 146 1472 402 1074 1634 368 1362 2534 -523 -1156 -775 -2765 -2680 -368 -78 -310 800 954 615 972 1586 1915 2050 1697 -262 -1834 -2520 -2374 -1538 166 1126 710 -248 -601 SQ 20250723T103926.6Z 9335.444058 99 1 54.21 2 83.95 69.15 66.99 73.14 0.00 1 0.00 1 0 106 1.491e-02 1.471e-02 3.126e-04 3.121e-04 1.037307e+04 1.997114e+01 3.622764e+02 -6.000000e+00 7.831123e+02 290.40 -2.00 20.00 -2.00 505.38 0.00e+00 1.872571e-03 8.530397e-06 6.311814e-05 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