File name: Pandora156s1_HamptonVA-HU_20220504_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T150539.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220504_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220504T124039.6Z 8159.528236 128 1 46.43 2 60.91 91.33 88.40 58.66 0.00 1 0.00 1 0 17 4.313e-02 8.196e-03 4.187e-02 7.157e-03 2.974549e-01 3.676191e-03 3.356206e-03 -6.000000e+00 2.536629e-02 230.45 -2.00 3.43 -2.00 318.58 0.00e+00 -1.874449e-04 7.427317e-04 1.196269e-04 -6.000000e+00 1.120455e-03 284.82 -2.00 20.00 -2.00 317.76 0.00e+00 2.047 0.000 302.00 328.00 3 5.2499e+00 1.0063e-02 2.5495e-02 -6.0000e+00 6.3330e-02 5.0663e-02 1.1498e-02 1.5029e-02 -6.0000e+00 6.8642e-02 9.1532e-03 7.4884e-03 7.3284e-03 -6.0000e+00 4.0882e-02 -1.2078e-02 3.8000e-03 2.0252e-03 -6.0000e+00 1.7020e-02 2.4117e-04 4.8049e-04 2.2602e-04 2.3142e-05 -6.0000e+00 1.2450e-03 -4.1700e-04 1.9535e-04 11 8 0 10 0 0 99.93 23.51 1.44 -0.00042 0.00319 20 5 1 5 0 2321.050 26.41 20.00 23.51 24.11 6.3 1039.16 -13525 1209 -10158 -6984 -6396 -8362 -13235 29243 2703 7127 -3593 17934 -6627 2831 9346 -851 -1214 1777 5593 1180 611 1837 11499 -1651 -4764 -5823 1248 -4245 -4050 1237 373 4652 6123 -4717 1559 -4496 1041 4182 671 2567 -426 -334 1362 600 -5664 321 -2971 2637 -3930 -329 -188 -575 -182 231 1195 360 868 444 -292 -271 743 -1137 1175 1341 2444 627 -1899 -539 -1711 2072 905 96 25 1357 1594 2809 1212 -1526 -991 -754 -2004 -710 -700 -1347 -1868 -413 -776 417 724 229 -582 -369 204 -671 849 649 214 1669 848 713 -185 -315 -399 833 -1127 -50 -915 -208 -784 26 -468 -246 -304 455 -800 -4 -282 -58 -7 635 -274 539 201 -649 1279 471 564 277 93 522 115 -36 -13 282 -368 587 16 -181 -397 64 -322 -526 301 11 -806 69 -676 -432 -357 -451 -782 1266 171 461 -263 1085 -568 254 905 -102 -155 231 731 168 90 267 1651 -266 -843 -1089 235 -811 -725 204 65 842 1188 -1070 323 -955 221 986 196 868 -166 -139 575 260 -2612 139 -1318 1085 -1699 -137 -82 -269 -90 121 647 202 494 255 -167 -153 420 -692 758 928 1723 432 -1247 -335 -1104 1425 699 79 21 1107 1226 1948 770 -927 -600 -498 -1511 -589 -631 -1296 -1912 -446 -893 495 869 272 -658 -383 193 -602 761 630 232 1978 1101 952 -240 -381 -448 905 -1314 -62 -1198 -283 -1126 39 -758 -413 -509 722 -1194 -6 -373 -77 -10 946 -431 848 311 -980 1812 689 785 375 129 775 183 -60 -21 461 -632 1056 31 -351 -783 124 -615 -969 531 20 SS 20220504T124901.1Z 8159.534041 134 1 5.86 2 59.24 92.62 87.00 59.82 0.00 1 0.00 1 0 17 2.638e-02 7.821e-03 1.896e-02 5.028e-03 2.810391e-01 2.585636e-03 3.248290e-03 -6.000000e+00 1.550701e-02 230.45 -2.00 3.43 -2.00 317.69 0.00e+00 2.690594e-04 4.133325e-04 1.550682e-04 -6.000000e+00 6.850257e-04 284.82 -2.00 20.00 -2.00 316.90 0.00e+00 1.947 0.000 302.00 328.00 3 3.9437e+00 6.9123e-03 2.4244e-02 -6.0000e+00 3.8715e-02 3.3482e-02 7.8035e-03 1.4311e-02 -6.0000e+00 4.1971e-02 -1.6669e-03 4.7344e-03 6.9148e-03 -6.0000e+00 2.4996e-02 -2.8409e-03 2.3332e-03 1.9239e-03 -6.0000e+00 1.0400e-02 1.0176e-03 4.7638e-05 1.5405e-04 2.2906e-05 -6.0000e+00 7.6151e-04 7.8842e-04 9.5923e-05 12 9 1 12 1 1 99.06 23.52 0.46 0.00079 0.00115 3 9 1 5 0 1420.660 26.41 19.99 23.52 24.60 6.3 1042.96 -5623 -3567 4554 -7283 -4516 -3631 -3094 -6655 21 -5752 384 1581 17182 11711 -1579 151 5480 -453 5184 -5675 -647 647 -1764 263 -208 3280 261 2922 -2038 -304 3335 2018 103 1058 -3084 -5866 -591 993 -619 44 -664 -812 -829 -3382 -755 -173 -966 -2681 1652 -948 2402 1538 96 922 542 -188 328 -358 475 2700 -2635 1281 2647 1374 1059 99 -1562 946 290 1246 971 835 -86 300 117 -363 886 -796 465 410 -1042 -2495 -814 -1985 -1017 -874 -779 50 61 134 1406 573 -719 35 -85 1169 1228 877 -479 824 -140 -548 -105 256 -589 -139 -197 -447 -436 -201 -487 -158 -375 -73 -445 389 824 9 -217 161 -249 -195 -324 72 567 648 724 638 582 -301 297 523 77 368 237 -368 120 53 -103 147 -737 -124 -31 -335 -503 -347 422 -726 -396 -298 -263 -653 2 -663 42 175 1796 1486 -262 27 1001 -92 1033 -1230 -145 143 -406 62 -53 833 69 717 -493 -70 773 514 29 308 -908 -1714 -173 327 -233 19 -328 -427 -451 -1812 -418 -95 -529 -1462 847 -498 1269 877 59 562 345 -124 219 -242 314 1722 -1800 889 1964 1108 880 80 -1183 668 212 996 819 750 -79 270 105 -300 652 -586 338 307 -894 -2289 -798 -2083 -1119 -977 -925 61 76 165 1608 640 -744 34 -83 1219 1421 1073 -645 1125 -186 -680 -121 302 -703 -176 -263 -598 -611 -298 -769 -246 -583 -112 -643 542 1097 12 -311 234 -382 -302 -492 105 830 901 957 817 765 -427 425 780 118 580 391 -617 208 95 -186 266 -1305 -211 -50 -545 SS 20220504T125351.0Z 8159.537396 137 1 12.49 2 58.28 93.38 86.19 60.48 0.00 1 0.00 1 0 25 1.882e-02 5.859e-03 1.215e-02 3.222e-03 2.733036e-01 1.652075e-03 3.150466e-03 -6.000000e+00 1.105878e-02 230.45 -2.00 3.43 -2.00 317.79 0.00e+00 -6.863198e-05 2.696755e-04 1.080818e-04 -6.000000e+00 4.885625e-04 284.82 -2.00 20.00 -2.00 316.99 0.00e+00 1.895 0.000 302.00 328.00 3 3.8861e+00 4.4270e-03 2.3567e-02 -6.0000e+00 2.7610e-02 3.3307e-02 5.0052e-03 1.3869e-02 -6.0000e+00 2.9934e-02 -1.4612e-03 3.0390e-03 6.7245e-03 -6.0000e+00 1.7827e-02 -4.3324e-03 1.4908e-03 1.8333e-03 -6.0000e+00 7.4156e-03 1.1523e-03 -2.1678e-04 9.9032e-05 2.1975e-05 -6.0000e+00 5.4325e-04 1.3718e-03 5.0900e-05 12 1 1 12 1 1 99.43 23.52 0.31 0.00137 -0.00026 9 10 1 5 0 1230.250 26.41 19.99 23.52 24.75 6.3 1043.88 -6783 -3475 237 -5717 1183 -11035 -3215 -2093 2029 -2570 -1330 208 7727 1519 -1271 283 773 1079 -36 2457 1317 1764 -83 678 1573 172 527 -5392 -8088 2295 2039 1759 2625 -1531 -1191 -1269 -1150 -847 -707 -593 303 -336 -965 210 -498 69 -1880 -785 -939 -414 -205 431 766 1822 66 1130 774 1375 497 208 783 1015 1992 1369 1056 -452 -110 267 172 -244 533 -286 -452 -91 365 178 -41 -213 -320 -205 -144 -1373 -1738 70 -886 -1276 53 -264 -93 171 613 -169 321 580 704 780 865 102 83 -203 19 -505 -718 -391 -550 -561 -1013 -515 -250 174 -196 -252 254 -179 -133 -94 452 370 200 253 -55 69 117 199 215 752 715 77 865 534 587 295 -173 -188 -23 -133 36 -181 207 -190 -155 92 -213 -723 -617 -338 23 -559 98 -974 -273 -196 204 -287 -148 23 882 211 -208 50 145 210 -7 510 283 378 -18 156 381 44 135 -1406 -2029 503 464 434 695 -441 -331 -341 -325 -274 -273 -251 142 -169 -503 110 -262 36 -989 -400 -469 -205 -106 235 444 1101 42 734 515 912 328 136 517 705 1484 1100 873 -363 -82 189 124 -196 472 -255 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