File name: Pandora156s1_HamptonVA-HU_20220506_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T150609.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220506_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220506T111428.8Z 8161.468389 79 1 48.01 2 77.66 78.38 112.50 25.57 0.00 1 0.00 1 0 25 4.669e-01 2.203e-02 3.424e-01 1.262e-02 6.014602e-01 7.017503e-03 7.579358e-03 -6.000000e+00 2.783801e-01 230.59 -2.00 3.43 -2.00 321.38 0.00e+00 1.252882e-02 3.515379e-03 4.396165e-03 -6.000000e+00 1.282116e-02 285.02 -2.00 20.00 -2.00 320.76 0.00e+00 4.545 0.001 302.00 328.00 3 3.2097e+00 2.4688e-02 5.6767e-02 -6.0000e+00 6.9812e-01 2.3467e-01 3.2168e-02 3.4359e-02 -6.0000e+00 7.5933e-01 -3.0965e-01 2.8778e-02 2.2317e-02 -6.0000e+00 4.4806e-01 1.2739e-01 1.3690e-02 1.1001e-02 -6.0000e+00 1.8611e-01 1.1095e-04 -7.2738e-04 3.9411e-04 1.8917e-04 -6.0000e+00 1.4000e-02 4.0856e-03 -6.1588e-05 12 8 8 10 0 0 99.60 23.47 0.72 0.00409 -0.00138 28 8 1 5 0 1714.280 26.32 20.00 23.47 22.80 6.3 1023.33 900000 -111621 39360 -50370 900000 -151017 -147489 900000 -167850 900000 88998 -85087 -89624 900000 700 8750 900000 17113 50629 118939 -136645 130898 -14364 270912 -18416 -29101 -4220 80399 -66233 57889 128698 6132 16352 -5155 38411 30428 8451 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-2819 810 -717 1517 117 -773 819 2405 -2527 -967 -2717 -389 -500 -987 -3118 -122 -713 -2114 -1975 -1704 -476 1156 -1329 -1028 594 -1440 615 -499 224 842 3243 46 -2000 459 3356 2914 -220 -440 3003 -566 1064 -170 735 607 3179 1284 1484 -835 629 -1839 -1183 -798 1209 -1339 -457 -981 -1052 SS 20220506T112015.1Z 8161.472397 82 1 47.39 2 76.53 79.20 112.01 26.80 0.00 1 0.00 1 0 17 3.302e-01 1.084e-02 2.060e-01 5.854e-03 5.746868e-01 3.193533e-03 6.218214e-03 -6.000000e+00 1.941098e-01 230.60 -2.00 3.43 -2.00 321.12 0.00e+00 3.829593e-03 1.490002e-03 4.279581e-04 -6.000000e+00 9.255541e-03 285.02 -2.00 20.00 -2.00 320.49 0.00e+00 4.189 0.001 302.00 328.00 3 2.4197e+00 1.0814e-02 5.1595e-02 -6.0000e+00 4.8496e-01 6.8058e-02 1.4261e-02 3.0672e-02 -6.0000e+00 5.2594e-01 -8.2347e-02 1.3343e-02 1.5707e-02 -6.0000e+00 3.1332e-01 2.8371e-02 6.3990e-03 6.8239e-03 -6.0000e+00 1.3142e-01 3.7109e-04 -2.0368e-04 1.8215e-04 7.6483e-05 -6.0000e+00 9.7325e-03 2.9366e-03 -1.2550e-05 12 8 8 10 0 0 95.47 23.47 0.45 0.00294 0.00141 62 17 1 5 0 764.190 26.32 20.00 23.47 23.10 6.3 1025.85 -204295 -152297 900000 900000 28329 -130466 -122121 -92752 42515 -59543 900000 -66903 -27230 -72669 -44978 52134 16131 -54317 -21460 11175 76524 41719 7618 -31711 -9125 1544 -9912 -17219 -11895 -10599 -10776 215 24188 29348 -91 -38509 -10294 44943 -3076 12875 1622 1537 -12 2519 11376 4249 -4954 -2644 10414 1309 5631 1340 4304 -149 5519 1162 2554 1010 -4429 -3291 763 8973 3326 -218 3110 2388 3256 4345 1433 2457 -399 346 6630 -1223 2205 -1714 -1141 -2328 1401 1250 -444 -1251 -6476 -613 -1030 -212 -24 -353 -434 884 -28 304 -315 408 439 1006 1455 808 -210 -16 -601 259 -902 -874 -1664 -618 -654 -547 -301 -330 -631 -594 884 -161 362 -501 -592 39 613 -300 551 -131 -6 57 452 803 750 729 330 1137 398 -322 -787 401 84 411 -112 485 -593 -415 -573 1163 366 -1267 -4801 -2662 900000 900000 162 -1768 -1612 -1026 243 -573 900000 -811 -272 -1452 -850 446 224 -1686 -521 207 764 595 158 -1041 -257 41 -304 -559 -361 -333 -388 8 837 1047 -4 -2637 -569 1778 -224 955 153 158 -1 280 1181 483 -631 -337 1204 175 783 216 740 -29 1081 248 554 224 -1020 -738 168 1956 859 -65 962 742 973 1290 467 896 -168 154 2802 -540 876 -643 -389 -779 479 491 -207 -674 -4077 -390 -701 -153 -18 -281 -351 691 -21 211 -207 262 299 768 1271 811 -236 -19 -684 270 -867 -808 -1616 -634 -708 -627 -369 -445 -940 -950 1427 -257 546 -722 -833 56 916 -477 891 -211 -9 85 693 1176 1058 1017 492 1867 682 -598 -1545 816 182 941 -268 1184 -1477 -1021 -1354 2556 774 -2696 SS 20220506T113110.6Z 8161.479984 85 1 47.64 2 74.38 80.74 111.04 29.10 0.00 1 0.00 1 0 25 3.776e-01 9.357e-03 2.680e-01 7.712e-03 5.060038e-01 4.176685e-03 5.551929e-03 -6.000000e+00 2.223598e-01 230.60 -2.00 3.43 -2.00 320.70 0.00e+00 2.302470e-03 1.711636e-03 8.555354e-04 -6.000000e+00 1.035584e-02 285.02 -2.00 20.00 -2.00 320.03 0.00e+00 3.648 0.001 302.00 328.00 3 3.5318e+00 1.3283e-02 4.5440e-02 -6.0000e+00 5.5487e-01 4.7281e-03 1.6972e-02 2.7971e-02 -6.0000e+00 6.0156e-01 3.4164e-02 1.5572e-02 1.3091e-02 -6.0000e+00 3.5846e-01 -2.5693e-02 7.6762e-03 5.3546e-03 -6.0000e+00 1.5062e-01 2.2100e-04 -4.9932e-05 2.4426e-04 5.2263e-05 -6.0000e+00 1.1204e-02 1.5433e-03 9.1783e-05 12 8 8 10 0 0 99.93 23.49 0.60 0.00154 0.00117 36 10 1 5 0 1323.140 26.32 20.00 23.49 23.57 6.3 1029.27 -95829 900000 14147 900000 900000 243602 30160 101640 -50512 -5153 289057 -45308 -62175 -40169 95138 20401 -24998 -12555 -6161 -8001 27847 15682 7087 -32508 -708 -5582 -10727 3633 16003 10636 -13475 -187 -22738 42567 -15458 20495 -9172 490 17557 -4668 7257 -1551 -2955 12307 -13437 183 -377 2859 -3373 -7809 -7697 3837 10284 247 -3979 1767 1107 -3055 1602 -299 -3316 1961 7084 1248 412 1790 582 -630 -3524 1250 4329 1197 756 -2329 -1395 3281 -1735 -775 671 -670 593 -89 30 -1560 610 -1880 -287 -899 1155 4237 1138 -1323 -684 -1182 3156 1045 436 526 -921 -329 -410 276 -740 23 -1158 -469 -1949 97 111 28 -459 -149 -73 440 272 -874 390 -39 -197 -377 -314 -59 115 90 158 361 1016 823 436 -343 524 428 90 141 158 77 -359 411 -158 74 -183 122 -142 -630 -1102 900000 106 900000 900000 1831 227 764 -581 -41 2173 -621 -1210 -782 715 336 -685 -333 -166 -234 628 381 206 -1423 -24 -215 -446 137 519 375 -677 -10 -1569 1760 -1066 1030 -664 38 1378 -516 812 -206 -420 1551 -2228 27 -57 422 -543 -1371 -1457 759 2088 56 -1007 440 304 -832 437 -82 -954 573 2187 453 160 680 215 -234 -1424 542 2038 621 401 -1234 -686 1400 -709 -301 268 -307 311 -54 20 -1127 459 -1550 -247 -811 1036 3617 949 -1050 -504 -851 2283 861 412 563 -1103 -407 -491 304 -753 23 -1192 -512 -2279 117 143 40 -708 -245 -122 710 416 -1273 544 -56 -296 -601 -515 -95 182 136 230 505 1354 1080 604 -528 876 765 169 277 328 170 -829 963 -377 176 -418 265 -294 -1300 SS 20220506T114509.7Z 8161.489695 92 1 48.37 2 71.62 82.72 109.68 31.96 0.00 1 0.00 1 0 17 4.929e-01 4.744e-02 3.402e-01 2.845e-02 4.421172e-01 1.525195e-02 5.130045e-03 -6.000000e+00 2.912207e-01 230.60 -2.00 3.43 -2.00 320.14 0.00e+00 -3.649571e-03 4.789975e-03 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