File name: Pandora156s1_HamptonVA-HU_20220510_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T150947.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220510_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220510T145521.2Z 8165.621773 305 1 14.83 2 33.80 116.18 121.39 39.08 0.00 1 0.00 1 0 17 1.401e-02 8.301e-03 9.809e-03 4.854e-03 1.868025e-01 2.509977e-03 2.185514e-03 -6.000000e+00 8.246616e-03 230.90 -2.00 3.43 -2.00 316.23 0.00e+00 -8.627055e-06 2.800174e-04 2.890586e-05 -6.000000e+00 3.646775e-04 285.43 -2.00 20.00 -2.00 315.47 0.00e+00 1.203 0.000 302.00 328.00 3 5.4893e+00 6.5638e-03 1.5401e-02 -6.0000e+00 2.0607e-02 4.6639e-02 7.3338e-03 9.4619e-03 -6.0000e+00 2.2333e-02 3.8631e-03 4.2109e-03 4.6014e-03 -6.0000e+00 1.3300e-02 -5.6849e-03 1.9019e-03 1.2537e-03 -6.0000e+00 5.5298e-03 5.2981e-04 3.3024e-04 1.4782e-04 1.6494e-05 -6.0000e+00 4.0449e-04 3.9705e-03 1.2748e-04 12 9 1 12 9 1 99.92 23.05 0.47 0.00397 0.00645 3 3 1 5 0 3661.150 26.00 20.00 23.05 20.94 6.4 1012.75 -2134 2959 -3758 -964 1855 -6498 -621 4148 2190 -4308 -3531 1247 1585 -186 2192 -2593 -2384 -1263 -935 -428 -30 -351 3615 -1137 -652 -766 536 -383 -2194 2647 467 1377 1511 2200 -707 1848 -1227 495 -962 1200 499 -634 -419 -1125 -1063 -386 838 -1685 -416 -1914 1561 -102 1436 413 1109 880 1738 280 676 675 940 1142 2084 1566 -302 911 -855 583 -222 -268 -126 335 -404 482 -871 -591 -449 202 -769 -451 524 -1662 -931 -1986 -373 -1257 271 -503 317 -11 -115 142 403 1062 -353 92 -147 987 206 560 181 -850 -1219 -908 -595 -320 -720 -313 -602 -474 -59 -754 652 -362 174 -491 350 -366 781 -262 426 66 39 74 232 1712 2463 1223 1329 1124 368 211 -100 -275 413 197 83 -126 96 -110 -137 -1422 -546 -850 -421 601 -827 -194 347 -1237 -115 809 482 -1062 -857 288 392 -52 672 -847 -806 -432 -328 -153 -11 -127 1353 -434 -260 -316 218 -159 -859 941 172 530 616 916 -290 710 -511 231 -507 720 333 -450 -305 -833 -783 -280 589 -1172 -276 -1266 1021 -72 1046 317 873 707 1405 230 545 539 760 970 1882 1416 -281 841 -734 464 -181 -240 -124 330 -408 472 -872 -540 -368 151 -572 -360 461 -1648 -987 -2108 -412 -1500 338 -661 419 -14 -141 159 435 1058 -356 98 -163 1190 270 745 232 -1026 -1382 -1016 -702 -404 -958 -432 -868 -677 -88 -1161 973 -515 240 -628 424 -453 1007 -366 624 99 58 105 314 2167 3118 1511 1666 1404 488 290 -140 -394 612 309 129 -200 154 -178 -216 -2199 -858 -1331 SS 20220510T145919.8Z 8165.624535 308 1 3.08 2 33.09 117.32 120.92 40.02 0.00 1 0.00 1 0 17 1.268e-02 7.970e-03 1.073e-02 6.118e-03 1.858661e-01 3.187635e-03 2.210869e-03 -6.000000e+00 7.457174e-03 230.90 -2.00 3.43 -2.00 315.68 0.00e+00 3.266824e-04 3.163815e-04 3.665728e-05 -6.000000e+00 3.298360e-04 285.43 -2.00 20.00 -2.00 314.97 0.00e+00 1.193 0.000 302.00 328.00 3 4.3635e+00 8.2810e-03 1.5336e-02 -6.0000e+00 1.8635e-02 4.4377e-02 9.2245e-03 9.4859e-03 -6.0000e+00 2.0200e-02 1.1616e-03 5.2689e-03 4.6204e-03 -6.0000e+00 1.2029e-02 -4.8213e-03 2.3328e-03 1.2817e-03 -6.0000e+00 4.9976e-03 1.6521e-03 -8.3468e-04 1.8376e-04 1.7450e-05 -6.0000e+00 3.6612e-04 4.9545e-03 -3.6429e-05 12 9 1 12 1 1 999.00 23.05 0.25 0.00495 -0.00132 1 9 1 5 0 1451.000 26.00 20.00 23.05 21.06 6.4 1013.90 3017 -6797 454 -1643 -2687 -3348 1091 -3322 81 -3380 -316 -609 440 529 2637 1006 361 1778 186 687 655 672 -2276 973 455 1969 283 -240 -1200 1755 1188 -509 3026 -1194 1950 -2547 -1246 -584 1210 -536 536 -1090 -1695 -175 130 707 793 -3113 -819 389 -8 -182 730 430 -861 978 -196 -26 1254 879 824 941 1014 2697 39 889 -43 -364 -1021 1205 425 -62 -1100 -364 567 -630 520 -211 203 -24 -428 -548 -889 -1152 -1677 -1217 -389 -670 -1153 504 181 25 118 79 687 1355 318 718 154 152 901 -380 201 -227 -481 252 -690 -738 -709 299 -458 5 -821 169 291 -253 800 671 -726 269 -1 81 -221 106 438 748 1355 154 2218 521 458 -120 -1063 509 -154 633 -78 -101 -173 -116 -450 -436 -433 -337 707 -1904 120 -418 -617 -724 232 -815 21 -961 -86 -167 128 172 939 395 140 694 76 286 278 284 -995 427 210 925 135 -109 -541 732 506 -233 1416 -566 909 -1192 -604 -303 729 -362 396 -818 -1314 -135 100 535 588 -2318 -606 280 -6 -142 565 348 -729 827 -170 -22 1059 737 703 843 929 2573 39 825 -39 -309 -884 1121 419 -65 -1138 -384 562 -607 445 -176 166 -20 -401 -539 -945 -1234 -1909 -1413 -476 -858 -1507 637 217 28 129 80 689 1439 357 884 196 198 1121 -466 230 -257 -578 322 -895 -999 -956 418 -678 8 -1184 238 391 -315 987 838 -927 364 -1 113 -304 147 579 978 1670 185 2648 667 592 -162 -1470 706 -225 925 -119 -152 -267 -179 -707 -663 -638 -492 SS 20220510T155509.9Z 8165.663309 342 1 47.26 2 24.22 138.29 113.35 52.04 0.00 1 0.00 1 0 17 8.625e-03 5.432e-03 4.322e-03 2.068e-03 1.706106e-01 1.063244e-03 2.006200e-03 -6.000000e+00 5.076999e-03 230.91 -2.00 3.43 -2.00 316.50 0.00e+00 9.254016e-05 1.240012e-04 2.592983e-05 -6.000000e+00 2.245199e-04 285.44 -2.00 20.00 -2.00 315.70 0.00e+00 1.096 0.000 302.00 328.00 3 4.3734e+00 2.7912e-03 1.4069e-02 -6.0000e+00 1.2687e-02 4.7705e-02 3.1225e-03 8.6735e-03 -6.0000e+00 1.3749e-02 2.0231e-03 1.7894e-03 4.2131e-03 -6.0000e+00 8.1884e-03 -5.3440e-03 8.1281e-04 1.1510e-03 -6.0000e+00 3.4042e-03 1.8578e-03 2.8211e-04 6.3203e-05 1.4954e-05 -6.0000e+00 2.4905e-04 4.0753e-03 1.0530e-04 10 0 0 10 0 0 99.98 23.07 0.13 0.00408 0.00620 108 29 1 5 0 437.470 26.00 20.00 23.07 21.90 6.5 1022.38 -1393 -1431 -1246 -1925 -2689 -2632 2884 1105 1378 1017 -425 -1372 -784 -198 -139 -38 -799 -382 777 460 272 1441 -414 252 508 1462 -573 163 -185 -496 1949 2391 1674 1253 -753 -1456 -1080 -586 371 65 -184 -1019 -1142 -923 -785 -283 -885 -1017 -1301 -678 642 789 672 1472 564 -20 696 575 326 779 953 1156 1297 1107 976 -305 -271 -545 102 352 240 284 294 29 -305 492 -124 235 114 -236 -295 -1102 -1157 -1696 -721 -988 -260 -143 -310 -112 205 365 219 -34 694 426 1051 777 524 61 -23 -547 -363 -431 -661 -164 -685 -661 -492 51 -126 174 -14 -121 -8 74 125 -80 101 349 -269 -48 -26 82 611 744 778 710 1172 422 527 317 -85 175 -119 -220 -44 117 -149 -231 -360 -68 -32 -584 -269 -298 -262 -411 -480 -473 504 217 298 231 -97 -314 -191 -53 -41 -12 -268 -130 268 163 98 513 -151 94 199 583 -232 62 -66 -167 648 832 620 478 -280 -523 -406 -250 185 38 -119 -694 -799 -651 -549 -195 -602 -667 -824 -418 399 516 463 1049 418 -15 530 439 246 579 719 915 1099 993 885 -263 -213 -437 76 287 217 272 287 28 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