File name: Pandora156s1_HamptonVA-HU_20220529_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T151908.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220529_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220529T103100.2Z 8184.438197 61 1 47.61 2 83.14 68.00 75.91 76.31 0.00 1 0.00 1 0 17 6.385e-01 4.731e-02 4.753e-01 3.531e-02 9.173832e-01 2.232514e-02 9.924329e-03 -6.000000e+00 4.005469e-01 231.97 -2.00 3.43 -2.00 322.39 0.00e+00 1.191710e-02 1.324201e-02 9.635457e-03 -6.000000e+00 2.288008e-02 287.24 -2.00 20.00 -2.00 321.90 0.00e+00 7.644 0.007 302.00 328.00 3 8.0657e-01 9.3153e-02 1.1735e-01 -6.0000e+00 1.0015e+00 1.4650e+00 1.1340e-01 1.1420e-01 -6.0000e+00 1.0892e+00 -1.8770e+00 6.9967e-02 2.8439e-02 -6.0000e+00 6.4899e-01 7.4021e-01 3.4799e-02 1.9618e-02 -6.0000e+00 2.7496e-01 3.8456e-05 -2.7930e-03 1.0774e-03 1.4188e-04 -6.0000e+00 2.0003e-02 -1.0827e-03 1.0940e-04 12 8 8 10 0 0 12.66 24.32 0.84 -0.00108 -0.02207 44 12 1 5 0 1081.770 27.05 20.00 24.32 27.33 7.1 1036.28 -75359 900000 163156 900000 -40224 900000 -105623 900000 92515 900000 900000 -75929 900000 148533 3739 900000 138180 -23722 900000 900000 900000 124575 900000 306749 900000 -62197 900000 -61473 900000 34793 900000 -593 900000 22930 31734 44792 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900000 900000 5147 5305 5579 4924 4183 4337 7026 -1699 6191 1792 5715 -502 1215 -188 6603 -1767 8633 -2471 -3365 2460 -294 7075 -1835 3819 374 7880 -4854 421 3152 -5343 -2087 -3509 5655 1798 -2376 -3419 -3177 -4218 2862 -10535 -3095 -4726 7745 -6290 3178 -8520 4674 -7042 -1319 611 3433 -3196 -2864 -1968 -4782 9012 -318 1381 2961 5893 4347 3730 -154 1882 236 4347 362 -2814 4172 16388 -7806 86 -1993 -3838 2061 -1989 2280 -437 -6600 SS 20220529T104152.9Z 8184.445751 64 1 46.95 2 81.11 69.53 73.84 77.74 0.00 1 0.00 1 0 17 6.365e-01 1.942e-02 3.655e-01 9.372e-03 7.655709e-01 5.499773e-03 8.136016e-03 -6.000000e+00 3.792850e-01 231.97 -2.00 3.43 -2.00 321.99 0.00e+00 1.848212e-03 3.392601e-03 9.245946e-04 -6.000000e+00 1.855221e-02 287.24 -2.00 20.00 -2.00 321.45 0.00e+00 6.120 0.004 302.00 328.00 3 8.0827e-01 2.2590e-02 7.4079e-02 -6.0000e+00 9.4830e-01 3.9167e-01 3.1845e-02 4.3437e-02 -6.0000e+00 1.0278e+00 -5.6850e-01 2.9641e-02 2.1210e-02 -6.0000e+00 6.1182e-01 2.3207e-01 1.3304e-02 7.0746e-03 -6.0000e+00 2.5905e-01 2.4320e-04 -1.0410e-03 2.8554e-04 9.3930e-05 -6.0000e+00 1.8823e-02 -8.8676e-04 3.3459e-05 12 8 8 10 0 0 39.86 24.31 0.41 -0.00089 -0.00871 95 26 1 5 0 494.090 27.05 20.00 24.31 28.05 7.0 1041.23 900000 -289118 900000 900000 -152085 900000 -197526 76693 -209894 -56069 -207254 900000 -125419 900000 -120994 900000 31053 -19850 -32812 93092 141694 301790 165189 900000 23950 -2375 60832 -27798 158316 -31269 900000 138996 44759 2726 24210 85215 32316 -30980 1284 47903 24350 100666 -416 79481 19579 -23541 49976 24710 3121 52339 4075 36116 37134 7724 33910 21526 15762 13836 17531 31293 4857 8518 26330 8640 24151 10916 7419 11547 4191 8851 11577 5722 6491 -975 4599 6697 -2949 2774 -3125 9239 -442 -1074 -1319 -2927 -1001 -381 -4661 4127 166 -953 2217 -4089 3243 -3438 -1615 -706 -1495 -1581 196 -1374 1411 -2817 -2880 -116 -2541 -2321 -1931 -1707 -552 -1155 -1955 322 -1106 669 -832 25 15 -366 396 545 284 655 360 1322 2310 851 2173 358 1301 1192 1023 593 7 108 274 189 -48 19 -867 546 -858 550 -186 -1456 900000 -11640 900000 900000 -1470 900000 -2969 700 -4394 -512 -4784 900000 -1860 900000 -2760 900000 283 -249 -505 850 1293 2754 1508 900000 260 -35 555 -523 1445 -624 900000 1268 689 70 497 985 627 -1308 48 1339 986 2067 -25 2176 983 -1839 1910 1254 207 2269 316 2287 2584 789 2863 2161 1735 1563 1860 2802 568 1025 2989 1331 3485 1837 1282 1963 829 1903 2727 1527 1740 -270 1112 1429 -634 554 -717 2192 -138 -392 -545 -1332 -477 -193 -2600 2194 93 -530 1135 -2092 1474 -1681 -844 -422 -1055 -1297 178 -1342 1313 -2526 -2334 -86 -1997 -1942 -1705 -1607 -559 -1319 -2542 451 -1651 983 -1203 34 20 -508 574 829 440 991 524 1837 3073 1109 2708 453 1762 1841 1789 1146 14 240 648 476 -126 50 -2379 1455 -2209 1308 -421 -3270 SS 20220529T105340.1Z 8184.453937 69 1 46.10 2 78.90 71.16 71.58 79.28 0.00 1 0.00 1 0 17 3.612e-01 5.210e-03 2.567e-01 3.198e-03 6.527015e-01 1.789045e-03 7.010526e-03 -6.000000e+00 2.135691e-01 231.97 -2.00 3.43 -2.00 321.51 0.00e+00 1.669789e-03 9.586992e-04 8.603014e-04 -6.000000e+00 9.925499e-03 287.25 -2.00 20.00 -2.00 320.90 0.00e+00 5.006 0.002 302.00 328.00 3 3.1541e-01 6.6081e-03 6.1215e-02 -6.0000e+00 5.3505e-01 5.0904e-02 9.3427e-03 3.6509e-02 -6.0000e+00 5.7929e-01 -3.9858e-02 9.3310e-03 1.7821e-02 -6.0000e+00 3.4477e-01 4.8654e-03 4.3255e-03 6.4164e-03 -6.0000e+00 1.4373e-01 1.3115e-03 -5.3804e-04 9.8241e-05 7.2390e-05 -6.0000e+00 1.0497e-02 -1.9645e-03 1.6363e-05 10 0 0 10 0 0 42.89 24.31 0.38 -0.00196 -0.00601 298 80 1 5 0 154.590 27.05 20.00 24.31 29.05 7.1 1050.50 -201094 -92804 -120558 -142193 151740 11634 -146512 -22634 -53818 -125655 900000 -113611 -2104 -764 -49673 -26357 -8248 -62367 2314 49820 17195 22742 20365 -36597 -1573 -788 -37829 15193 -36986 17189 13209 -13667 -9203 6356 -12862 4664 -4797 -11721 -2589 -2800 -15925 6124 99 -3002 1882 -4037 -1377 2251 -3829 -1863 4708 -6939 5430 3155 131 1495 39 30 2115 262 34 6492 1457 2893 857 1571 550 3183 510 663 1921 963 1322 700 -809 658 -1095 -2168 1095 -661 264 -667 -1352 -1295 -919 -1518 0 483 161 963 817 615 276 72 -297 1096 560 648 74 -100 -563 217 -1004 -230 -736 -756 -549 -612 -311 -20 -696 180 271 -151 2 176 288 -134 485 -41 79 -351 -439 285 48 326 907 499 218 659 -306 547 -210 -128 -146 37 -299 180 111 -244 296 -19 -221 -132 -1539 -318 -547 -887 473 36 -960 -71 -185 -980 900000 -957 -7 -3 -449 -230 -69 -1011 22 311 156 199 191 -662 -22 -12 -849 199 -807 231 214 -350 -264 172 -425 128 -156 -479 -119 -156 -1172 397 7 -236 144 -335 -114 186 -352 -179 468 -872 671 437 20 239 7 5 350 43 6 1101 293 647 212 391 136 777 138 203 655 355 494 255 -278 202 -314 -612 319 -227 106 -312 -712 -736 -555 -987 0 340 115 672 543 382 163 42 -187 775 461 612 78 -112 -615 217 -924 -200 -667 -732 -560 -664 -363 -26 -1001 279 435 -240 3 255 406 -193 731 -66 129 -566 -683 424 69 451 1202 658 307 1038 -542 1045 -429 -276 -336 91 -764 467 293 -637 737 -44 -496 -291 SS 20220529T105926.1Z 8184.457941 72 1 45.68 2 77.80 71.95 70.47 80.04 0.00 1 0.00 1 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