File name: Pandora156s1_HamptonVA-HU_20220613_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T152529.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220613_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220613T103805.5Z 8199.443119 189 1 46.81 2 81.37 67.36 111.72 256.30 0.00 1 0.00 1 0 25 6.618e-01 4.586e-02 4.635e-01 3.827e-02 7.315140e-01 2.209637e-02 9.079648e-03 -6.000000e+00 4.001082e-01 232.72 -2.00 3.43 -2.00 321.93 0.00e+00 2.128183e-02 1.166300e-02 1.349717e-03 -6.000000e+00 2.152188e-02 288.67 -2.00 20.00 -2.00 321.33 0.00e+00 6.283 0.004 302.00 328.00 3 2.5922e+00 8.3571e-02 7.5114e-02 -6.0000e+00 1.0092e+00 1.0467e+00 1.0142e-01 5.0094e-02 -6.0000e+00 1.0979e+00 -1.3443e+00 6.4946e-02 1.9598e-02 -6.0000e+00 6.4303e-01 5.3770e-01 3.2076e-02 1.8811e-02 -6.0000e+00 2.6820e-01 2.9738e-05 -1.0221e-03 1.1640e-03 2.9876e-04 -6.0000e+00 1.9787e-02 -5.7120e-04 1.1505e-04 12 8 8 10 0 0 2.12 24.57 1.20 -0.00057 -0.00825 19 5 1 5 0 2463.230 27.26 19.99 24.57 30.28 7.3 1027.03 -74998 900000 -44346 900000 5456 900000 -50865 -58217 900000 900000 900000 -66422 -75637 -74617 33773 38541 153143 82071 102081 -22748 900000 328092 6049 3858 76461 -67744 900000 51799 180374 900000 -19184 900000 -47132 143672 -90 900000 -76576 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159 8914 1836 -6461 -4590 -953 4281 -5102 1553 -3723 2537 2312 3012 -4122 885 -3673 -1394 -2049 1937 -1742 -2725 2296 -4990 -3519 -6638 3915 -6199 -791 -8121 1563 1764 1278 -3 2333 -1232 213 -741 -6062 4567 -2788 2578 -7161 1789 2214 2294 -1767 2159 -408 1985 2443 -2010 3192 2186 2972 -2708 4200 377 6227 5923 2732 -284 422 -9524 3272 -4997 1142 9094 -557 -2753 -8231 SS 20220613T105130.4Z 8199.452435 194 1 47.30 2 78.89 69.20 114.22 257.97 0.00 1 0.00 1 0 25 3.790e-01 8.413e-03 3.590e-01 8.981e-03 6.370484e-01 5.076662e-03 6.858339e-03 -6.000000e+00 2.256746e-01 232.72 -2.00 3.43 -2.00 321.56 0.00e+00 -8.714602e-04 2.756852e-03 6.244715e-04 -6.000000e+00 1.047502e-02 288.67 -2.00 20.00 -2.00 320.93 0.00e+00 5.002 0.002 302.00 328.00 3 2.1279e+00 1.9072e-02 6.0378e-02 -6.0000e+00 5.6510e-01 1.4199e-02 2.6778e-02 3.4543e-02 -6.0000e+00 6.1139e-01 -8.7153e-02 2.5729e-02 1.7174e-02 -6.0000e+00 3.6395e-01 3.0889e-02 1.1864e-02 4.8223e-03 -6.0000e+00 1.5254e-01 2.3107e-04 -4.0992e-04 2.8210e-04 6.2787e-05 -6.0000e+00 1.1006e-02 1.0483e-03 1.2258e-05 11 8 0 10 0 0 11.30 24.57 0.58 0.00105 -0.00203 69 19 1 5 0 685.310 27.26 20.00 24.57 31.06 7.4 1034.50 -192965 900000 900000 -66993 -73190 900000 -204465 -216705 -7505 -66361 -87802 -63043 82321 900000 -66712 -4213 20797 -24693 8354 -22626 120252 -16335 -23118 -28826 22046 -39752 -7798 -57697 -43997 -16604 -22524 -11933 3161 -21210 9256 -966 -1796 -6986 -3868 -2494 -3486 -13229 10067 -990 12234 7890 13544 -540 2630 9986 5227 -2607 -1930 3270 -2426 -198 7943 4001 2538 -4665 3962 3073 -383 4644 1161 5627 -1131 1445 -452 -188 3906 2830 418 2335 2050 -1805 944 -3893 959 963 91 -1210 -1872 -2021 107 -94 1333 935 -939 204 2636 572 -1479 -751 -1843 488 -252 1430 -114 90 -1415 -421 -1445 -600 -322 -782 -1513 -503 8 -889 405 -669 565 -264 1138 486 254 282 -612 -206 316 -418 229 -164 40 854 -34 694 585 892 98 1074 -490 36 -283 310 -280 -98 -211 -282 -53 364 285 -513 -1689 900000 900000 -586 -641 900000 -2603 -3622 -66 -581 -769 -552 721 900000 -818 -37 182 -303 80 -317 1053 -229 -364 -530 270 -974 -143 -1717 -1117 -334 -552 -313 83 -780 251 -29 -58 -281 -186 -144 -235 -1077 687 -78 857 587 972 -46 226 848 512 -310 -253 447 -378 -32 1231 655 416 -805 635 533 -77 1000 280 1305 -275 348 -119 -56 1269 996 153 813 668 -555 259 -1091 273 316 35 -551 -960 -1122 62 -59 869 638 -663 140 1675 347 -867 -434 -1153 339 -204 1303 -117 98 -1509 -411 -1299 -513 -285 -745 -1535 -538 9 -1136 567 -1027 886 -412 1678 686 351 398 -918 -326 507 -667 350 -244 57 1166 -45 908 819 1397 172 2026 -995 76 -644 748 -710 -255 -553 -733 -131 851 634 -1141 SS 20220613T105731.4Z 8199.456614 197 1 46.87 2 77.76 70.02 115.35 258.73 0.00 1 0.00 1 0 25 2.975e-01 5.737e-03 2.954e-01 5.821e-03 5.894000e-01 3.211807e-03 6.404244e-03 -6.000000e+00 1.763118e-01 232.72 -2.00 3.43 -2.00 321.32 0.00e+00 2.555613e-03 1.618920e-03 5.999277e-04 -6.000000e+00 7.850478e-03 288.67 -2.00 20.00 -2.00 320.66 0.00e+00 4.577 0.002 302.00 328.00 3 1.8820e+00 1.1522e-02 5.5590e-02 -6.0000e+00 4.4209e-01 1.1313e-02 1.5630e-02 3.2473e-02 -6.0000e+00 4.7816e-01 -4.3507e-02 1.4748e-02 1.5728e-02 -6.0000e+00 2.8488e-01 8.5714e-03 6.9551e-03 6.0417e-03 -6.0000e+00 1.1841e-01 4.5215e-04 -6.8602e-04 1.8249e-04 6.6504e-05 -6.0000e+00 8.5962e-03 1.0718e-03 2.0107e-05 10 0 0 10 0 0 24.15 24.57 0.41 0.00107 -0.00408 103 28 1 5 0 454.980 27.26 20.00 24.57 31.41 7.4 1037.19 19593 -61141 -74669 -133569 -107391 -83472 -160125 -53346 -15232 -94851 -13258 -71904 -100258 -63958 -83346 26799 -57131 31033 -13467 25296 8128 35983 -39089 -21720 -15650 6617 -15541 17292 -20568 5704 1962 14715 -3498 1018 5505 -6316 -12529 739 -3707 -3031 -4529 1002 2375 -1693 3853 -1475 -1967 -518 3702 1537 2718 702 2840 4148 398 589 1269 517 615 -34 582 -244 1761 5275 1776 1911 -367 -191 -175 1790 122 679 499 -400 -314 846 589 -2090 -870 145 937 -561 -574 -1253 -1368 -861 -92 -38 504 200 559 1167 -13 1057 1799 856 429 622 169 446 -316 -716 -1084 -774 -935 -589 -1428 -575 -570 -362 -153 -134 318 198 -58 -18 -53 120 56 -4 -39 -388 348 -120 337 663 972 443 373 528 374 311 -349 -527 -28 92 -92 180 -54 118 -21 88 -165 -414 111 -347 -424 -1241 -721 -474 -1901 -303 -86 -916 -75 -653 -1480 -835 -1656 213 -1200 300 -222 302 120 409 -977 -493 -364 132 -397 314 -537 120 49 384 -127 39 200 -255 -576 35 -223 -219 -381 87 216 -166 365 -151 -207 -55 391 175 335 98 431 676 72 112 248 103 121 -7 115 -52 413 1339 502 541 -104 -54 -53 602 47 278 208 -163 -120 290 185 -653 -284 54 404 -282 -322 -761 -887 -595 -67 -29 386 151 401 775 -8 650 1168 633 367 607 184 507 -352 -743 -1030 -704 -885 -594 -1534 -650 -692 -482 -224 -212 515 316 -89 -26 -74 173 84 -7 -64 -633 547 -184 493 929 1307 592 530 833 655 589 -703 -1117 -63 220 -230 460 -141 301 -51 206 -367 -916 SS 20220613T110256.2Z 8199.460373 200 1 46.86 2 76.74 70.75 116.37 259.40 0.00 1 0.00 1 0 25 2.217e-01 5.319e-03 2.468e-01 4.642e-03 5.515532e-01 2.537950e-03 6.019491e-03 -6.000000e+00 1.314130e-01 232.72 -2.00 3.43 -2.00 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