File name: Pandora156s1_HamptonVA-HU_20220626_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T153228.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220626_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220626T130831.5Z 8212.547587 212 1 46.76 2 52.71 87.16 29.47 111.05 0.00 1 0.00 1 0 17 3.482e-02 1.152e-02 2.877e-02 7.904e-03 2.330951e-01 4.068319e-03 2.682343e-03 -6.000000e+00 2.063574e-02 232.72 -2.00 3.43 -2.00 317.93 0.00e+00 1.216563e-03 6.851002e-04 9.204057e-05 -6.000000e+00 9.233599e-04 289.84 -2.00 20.00 -2.00 316.99 0.00e+00 1.647 0.000 302.00 328.00 3 5.2119e+00 1.1051e-02 2.0475e-02 -6.0000e+00 5.1722e-02 3.2977e-02 1.2525e-02 1.2151e-02 -6.0000e+00 5.5928e-02 9.7783e-03 7.4694e-03 5.7787e-03 -6.0000e+00 3.3346e-02 -6.4195e-03 3.6270e-03 1.9135e-03 -6.0000e+00 1.3878e-02 4.1386e-04 7.1236e-04 2.4961e-04 2.2296e-05 -6.0000e+00 1.0060e-03 1.7771e-03 7.2194e-05 12 8 8 10 0 0 99.99 24.57 0.76 0.00178 0.00713 96 26 1 5 0 486.930 27.26 19.99 24.57 31.30 7.9 1026.98 -1740 4804 2590 -6666 -19559 -10332 969 3199 -3289 11363 6256 2648 -4594 -14979 -7658 3007 -4481 8164 6856 2778 2451 -759 -4053 822 -2974 -1401 998 9242 4929 -2653 3958 164 3149 -2034 -2825 -388 485 1351 5827 61 -1402 -3230 -3865 -506 -4370 4006 626 761 1557 -3911 -472 489 -1598 -16 1962 944 590 22 6266 2087 -796 -616 1397 1307 1677 357 532 83 -2310 -212 248 1908 1364 734 14 1906 -1695 -90 -22 416 -45 -3522 1331 -1128 -736 -1249 -64 -1056 -549 -1344 275 187 793 822 -61 1059 285 240 270 40 118 145 140 452 -2760 -198 -666 -738 -405 -37 287 488 -903 198 -1061 -1324 -348 -577 64 1295 497 150 452 -226 564 -760 2088 1483 1421 1439 521 788 -196 264 -539 -522 -211 229 996 676 -471 -554 -1236 -895 -167 474 268 -716 -2151 -977 85 303 -367 1151 666 297 -607 -2502 -1350 524 -884 1469 1297 566 511 -163 -908 182 -720 -346 241 2097 1094 -615 887 41 820 -578 -778 -101 132 417 2041 26 -682 -1690 -2098 -270 -2423 2039 325 384 760 -2001 -241 263 -929 -10 1196 593 378 14 3751 1291 -516 -422 1013 1011 1316 269 368 55 -1603 -159 205 1646 1203 638 11 1414 -1174 -57 -14 283 -35 -3096 1204 -1103 -759 -1388 -75 -1297 -680 -1649 314 195 751 729 -55 1015 305 283 344 53 148 169 152 521 -3229 -242 -859 -996 -570 -54 446 779 -1445 319 -1601 -1853 -464 -782 91 1945 790 243 714 -348 823 -1067 2708 1872 1836 1975 764 1200 -307 422 -908 -928 -390 433 1897 1288 -885 -1005 -2185 -1566 SS 20220626T132413.3Z 8212.558487 224 1 45.83 2 49.58 89.45 26.63 115.57 0.00 1 0.00 1 0 17 1.026e-02 5.179e-03 3.024e-03 9.479e-04 2.195142e-01 4.892441e-04 2.552700e-03 -6.000000e+00 6.080923e-03 232.72 -2.00 3.43 -2.00 317.49 0.00e+00 -1.520082e-04 7.419355e-05 7.222686e-05 -6.000000e+00 2.720728e-04 289.84 -2.00 20.00 -2.00 316.58 0.00e+00 1.539 0.000 302.00 328.00 3 2.5392e+00 1.3119e-03 1.9187e-02 -6.0000e+00 1.5241e-02 2.2181e-02 1.4784e-03 1.1325e-02 -6.0000e+00 1.6479e-02 8.2234e-03 8.7476e-04 5.4473e-03 -6.0000e+00 9.8258e-03 -8.0063e-03 4.2073e-04 1.4692e-03 -6.0000e+00 4.0904e-03 6.9071e-03 1.0447e-04 2.9484e-05 1.8235e-05 -6.0000e+00 2.9635e-04 6.9431e-04 9.2319e-05 11 1 0 11 8 0 99.98 24.57 0.52 0.00069 0.00148 347 93 1 5 0 132.050 27.26 20.00 24.57 32.04 7.8 1033.16 -3035 -1313 -5636 -2123 -3959 -2885 -876 533 2253 -377 -1484 -1215 -678 -112 276 -559 246 -373 978 205 116 483 658 418 710 275 316 -332 -260 800 1215 2600 1189 1462 -1769 -1214 -1587 -269 -368 168 -600 -682 -1228 -781 -1006 -730 -723 -1351 -745 -1023 489 536 1161 894 942 322 1009 462 415 454 950 1163 1597 1188 944 437 -243 -139 19 963 376 282 29 243 19 317 88 106 471 124 -129 -964 -1098 -1563 -1173 -1267 -424 -429 -30 -221 127 99 370 309 326 874 638 727 76 12 -393 -417 -601 -199 -624 -228 -573 -517 -358 -174 -9 88 -52 11 -20 -13 355 222 262 20 -7 -236 -175 323 414 859 799 980 749 733 262 399 -25 125 -23 -10 -81 134 -207 -214 -225 -170 -315 -467 -343 -159 -731 -252 -431 -292 -90 60 277 -50 -200 -165 -99 -18 51 -113 52 -81 218 48 28 114 156 104 186 75 95 -96 -70 204 314 707 351 446 -536 -352 -486 -93 -151 80 -322 -387 -655 -463 -596 -429 -418 -763 -406 -553 268 312 710 575 627 220 698 323 286 309 654 842 1241 986 800 354 -182 -98 14 755 329 262 27 227 17 256 64 71 312 89 -104 -866 -1068 -1612 -1275 -1477 -521 -551 -39 -283 154 110 372 290 307 875 705 885 101 17 -517 -511 -688 -224 -745 -291 -770 -727 -524 -268 -13 133 -78 17 -29 -18 452 286 355 29 -11 -369 -268 479 586 1149 1016 1201 937 972 369 584 -37 192 -37 -16 -143 244 -384 -396 -405 -296 -533 -784 SS 20220626T133223.3Z 8212.564158 230 1 15.78 2 47.95 90.68 25.19 118.23 0.00 1 0.00 1 0 17 8.306e-03 5.153e-03 3.706e-03 1.434e-03 2.100554e-01 7.453981e-04 2.448651e-03 -6.000000e+00 4.924282e-03 232.72 -2.00 3.43 -2.00 316.97 0.00e+00 8.594091e-05 9.865544e-05 4.472397e-05 -6.000000e+00 2.203182e-04 289.84 -2.00 20.00 -2.00 316.08 0.00e+00 1.490 0.000 302.00 328.00 3 2.8863e+00 1.9792e-03 1.8488e-02 -6.0000e+00 1.2342e-02 2.1378e-02 2.2198e-03 1.0800e-02 -6.0000e+00 1.3344e-02 7.9643e-03 1.2854e-03 5.2030e-03 -6.0000e+00 7.9567e-03 -7.2911e-03 5.9822e-04 1.4131e-03 -6.0000e+00 3.3127e-03 5.2107e-03 2.2115e-04 4.4408e-05 1.8155e-05 -6.0000e+00 2.3995e-04 6.3104e-04 1.1702e-04 12 1 1 12 1 1 99.99 24.57 0.23 0.00063 0.00229 78 63 1 5 0 197.470 27.26 20.00 24.57 32.52 7.8 1036.95 -1022 -1439 -1417 -1371 -3732 -1763 -1161 2242 1018 -278 -943 -1294 -422 270 -324 397 -527 -1557 735 -559 680 -141 1199 -129 509 365 -311 -274 -260 1307 914 2191 1350 1644 -1530 -615 -1602 -74 218 -42 -747 -508 -1060 -1115 -750 -918 -455 -672 -875 -639 328 783 926 1156 793 499 1191 429 174 485 1115 814 1523 1022 534 116 -476 -29 -295 1126 342 297 -68 208 -177 224 187 -74 141 -42 -363 -1029 -1038 -1616 -1116 -1269 -473 -437 -21 -130 235 320 205 407 506 789 633 594 61 114 -378 -221 -498 -81 -525 -151 -652 -399 -370 -247 -21 -84 41 -10 33 -123 239 -42 369 123 -74 -369 -119 211 585 731 726 1031 885 715 385 497 -106 271 -164 173 -140 20 -206 -202 -155 -249 -294 -481 -147 -227 -229 -209 -524 -228 -154 319 163 -48 -162 -224 -78 56 -76 101 -142 -434 207 -164 202 -42 357 -40 167 124 -107 -90 -79 375 268 675 448 563 -520 -199 -551 -29 100 -23 -448 -321 -630 -672 -495 -603 -292 -419 -531 -382 200 503 628 819 584 376 907 330 133 364 846 652 1186 850 455 94 -391 -22 -233 963 297 275 -65 193 -156 198 149 -54 102 -33 -319 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