File name: Pandora156s1_HamptonVA-HU_20220707_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T154330.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220707_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220707T112640.6Z 8223.476859 92 1 46.82 2 73.53 73.86 148.85 2.33 0.00 1 0.00 1 0 25 1.455e-01 7.326e-03 1.547e-01 5.408e-03 4.588226e-01 2.879816e-03 5.133131e-03 -6.000000e+00 8.680921e-02 232.63 -2.00 3.43 -2.00 320.47 0.00e+00 -6.872706e-04 1.096420e-03 4.560821e-04 -6.000000e+00 3.890400e-03 290.81 -2.00 20.00 -2.00 319.67 0.00e+00 3.470 0.001 302.00 328.00 3 3.1760e+00 9.0938e-03 4.2202e-02 -6.0000e+00 2.1744e-01 8.2262e-03 1.1328e-02 2.4072e-02 -6.0000e+00 2.3519e-01 -1.0785e-03 9.2850e-03 1.1559e-02 -6.0000e+00 1.3989e-01 -5.5069e-03 4.6366e-03 3.0795e-03 -6.0000e+00 5.8057e-02 4.0405e-04 -2.9506e-04 1.7087e-04 3.8887e-05 -6.0000e+00 4.2392e-03 2.2640e-03 1.2802e-05 11 8 0 10 0 0 80.64 24.41 0.33 0.00226 0.00005 52 14 1 5 0 899.760 27.15 20.00 24.41 32.48 8.2 1024.52 40443 -25573 -61639 -43927 6382 -26925 900000 -55395 40998 -7913 43516 -84525 34724 -16972 35186 -15203 4869 -9457 3113 18076 -12839 -6824 -22909 12999 5114 17805 3827 8001 -1570 -12375 -18336 21065 -475 1266 -4399 -469 8807 -1014 3487 -14503 3431 -3288 649 -418 -1570 -2038 -2186 -2011 2026 1603 1150 3311 2527 -223 1330 421 -47 -249 6324 396 -2130 1010 3161 2460 1502 1398 -979 1552 1801 1403 849 577 866 149 274 -1201 515 -598 549 -596 -9 -995 -1310 -920 -1887 -430 -1218 820 524 469 310 1060 -194 497 43 961 791 1640 -801 191 -981 -724 -369 -959 -620 -332 -893 -707 -66 -253 -148 -275 -392 22 904 295 120 -161 -191 68 30 -115 -468 180 275 723 756 1064 261 868 -152 599 394 27 5 -478 77 -110 -31 142 -270 -272 17 -258 226 -317 -1166 -681 55 -317 900000 -1065 365 -118 430 -3042 469 -437 644 -533 154 -373 116 611 -613 -311 -1272 544 252 823 208 405 -84 -741 -1274 1124 -35 99 -360 -36 664 -98 394 -2348 528 -584 116 -78 -297 -391 -422 -389 381 313 242 747 626 -61 380 127 -15 -79 1848 121 -677 331 1119 963 625 571 -391 633 727 639 435 316 482 81 140 -603 231 -258 242 -299 -5 -653 -951 -711 -1567 -355 -1143 740 481 423 282 887 -153 376 34 835 780 1808 -936 229 -1223 -834 -390 -991 -668 -382 -1089 -907 -90 -371 -222 -438 -633 34 1399 431 170 -234 -291 109 49 -192 -763 283 414 1035 1037 1425 369 1335 -258 1071 737 53 10 -1050 164 -258 -70 313 -615 -590 36 -534 SS 20220707T113258.9Z 8223.481238 96 1 40.70 2 72.32 74.70 148.80 5.23 0.00 1 0.00 1 0 17 2.124e-01 7.928e-03 1.407e-01 4.822e-03 4.290201e-01 2.552096e-03 4.823047e-03 -6.000000e+00 1.258291e-01 232.63 -2.00 3.43 -2.00 320.12 0.00e+00 1.714664e-03 8.559360e-04 4.005421e-04 -6.000000e+00 5.655707e-03 290.81 -2.00 20.00 -2.00 319.29 0.00e+00 3.246 0.001 302.00 328.00 3 3.4458e+00 7.7395e-03 3.9541e-02 -6.0000e+00 3.1520e-01 3.9336e-02 9.3521e-03 2.2791e-02 -6.0000e+00 3.4083e-01 -1.3404e-02 7.3030e-03 1.0761e-02 -6.0000e+00 2.0335e-01 -1.0716e-03 3.7282e-03 3.6643e-03 -6.0000e+00 8.4712e-02 3.8726e-04 -7.9260e-04 1.5311e-04 3.9260e-05 -6.0000e+00 6.1380e-03 2.0154e-03 1.4875e-05 12 9 1 12 1 1 76.60 24.41 0.45 0.00202 -0.00394 24 8 1 5 0 1620.670 27.15 20.00 24.41 32.75 8.2 1026.64 94164 4275 16844 -25191 46981 -15870 -39577 -33242 -25279 -28615 -5127 41727 20386 6324 -13999 200968 -12568 -23350 13292 -14929 -5946 -2197 1750 563 5714 15195 8696 4177 -8132 -2548 -1251 -8432 -21860 -10442 10106 6271 -978 7062 -1368 5136 -2754 -3949 936 -1881 -1170 1008 -1641 -526 2208 193 62 -1430 1068 -1017 2455 168 -1002 632 2141 -1365 1614 674 3335 2537 2235 5896 -809 -1998 582 60 251 966 339 780 1484 -547 712 -2208 -342 -517 317 -1084 926 -2004 -419 -1042 322 -692 240 63 55 -131 -282 777 1280 312 90 671 -565 446 -233 -311 -557 -546 -1719 700 -1019 -445 178 -212 -938 -128 247 -1703 750 790 355 293 198 -331 -119 110 314 -622 270 996 300 790 447 1067 457 1060 165 178 -165 20 -512 -159 -264 153 142 -237 -174 -454 471 60 223 -496 414 -252 -838 -743 -587 -740 -109 589 414 178 -580 1197 -654 -1455 613 -961 -362 -130 102 35 365 929 578 282 -598 -178 -94 -773 -2570 -1173 909 571 -102 785 -199 835 -548 -857 203 -430 -269 229 -385 -122 502 46 16 -402 318 -331 814 59 -366 229 755 -492 574 257 1366 1149 1066 2657 -370 -905 269 31 145 592 213 475 844 -309 360 -1088 -170 -287 201 -738 679 -1616 -353 -946 306 -694 242 63 52 -114 -244 639 1083 294 90 750 -703 569 -291 -359 -593 -565 -1881 800 -1250 -571 241 -310 -1496 -215 417 -2833 1144 1129 491 414 294 -525 -195 180 501 -968 400 1398 433 1108 655 1589 743 1821 297 334 -327 42 -1124 -357 -602 345 309 -496 -348 -904 SS 20220707T113839.5Z 8223.485180 99 1 43.05 2 71.23 75.46 148.70 7.82 0.00 1 0.00 1 0 25 5.417e-02 5.212e-03 4.767e-02 3.080e-03 4.089984e-01 1.615934e-03 4.616079e-03 -6.000000e+00 3.208981e-02 232.63 -2.00 3.43 -2.00 319.94 0.00e+00 -5.285184e-04 5.096708e-04 2.178296e-04 -6.000000e+00 1.442360e-03 290.81 -2.00 20.00 -2.00 319.10 0.00e+00 3.069 0.000 302.00 328.00 3 2.9070e+00 4.8230e-03 3.7378e-02 -6.0000e+00 8.0384e-02 1.4172e-02 5.7919e-03 2.1269e-02 -6.0000e+00 8.6920e-02 5.9005e-03 4.3954e-03 1.0235e-02 -6.0000e+00 5.1858e-02 -1.0002e-02 2.2454e-03 2.7540e-03 -6.0000e+00 2.1604e-02 8.2120e-04 -4.5617e-04 9.7881e-05 3.4466e-05 -6.0000e+00 1.5653e-03 2.0909e-03 2.0521e-05 12 1 1 12 1 1 99.15 24.42 0.42 0.00209 -0.00134 53 16 1 5 0 793.890 27.15 20.00 24.42 32.90 8.2 1027.59 -13321 6567 -35843 -3975 -15882 -24100 -8312 -10616 -18406 -3014 -11138 -11091 -16270 -10659 4432 -2362 -796 -1703 -4020 -5228 -6278 -4861 -4481 2807 5210 -1614 -5687 272 -1078 9726 -7210 894 -1131 796 -3898 -3575 -5211 2013 -2573 1517 -156 657 -753 234 -785 -1856 1685 -804 240 -2331 1104 1586 826 1327 887 -465 57 -686 612 -1107 1474 2745 1769 1872 765 1540 -622 305 -527 837 1353 810 268 300 612 -351 123 -885 -410 -557 -644 -1216 -918 -1531 -618 -1246 130 65 286 219 143 38 572 756 440 964 571 899 234 41 -406 -390 -812 -260 -768 -387 -1238 -697 -417 -199 138 -51 20 -194 497 -103 62 -121 350 -169 -33 -399 15 284 474 464 510 646 843 551 131 557 27 50 -361 -9 -417 224 -19 167 -1 -440 202 -500 -231 106 -869 -73 -305 -484 -152 -226 -481 -73 -304 -320 -568 -419 177 -116 -42 -97 -249 -344 -432 -334 -316 197 386 -136 -507 22 -85 683 -646 83 -119 88 -443 -396 -625 261 -423 285 -34 152 -184 58 -198 -476 417 -203 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