File name: Pandora156s1_HamptonVA-HU_20220916_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T162926.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220916_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220916T112920.1Z 8294.478705 229 1 46.65 2 82.66 92.36 26.27 246.12 0.00 1 0.00 1 0 25 7.898e-01 5.308e-02 4.665e-01 3.573e-02 7.275587e-01 2.164138e-02 1.172779e-02 -6.000000e+00 4.774573e-01 229.29 -2.00 3.43 -2.00 322.16 0.00e+00 4.231022e-02 1.358333e-02 2.714720e-03 -6.000000e+00 3.026511e-02 290.18 -2.00 20.00 -2.00 321.62 0.00e+00 7.227 0.006 302.00 328.00 3 1.6060e+00 9.3473e-02 1.0499e-01 -6.0000e+00 1.2117e+00 1.2707e+00 1.1191e-01 1.1813e-01 -6.0000e+00 1.3326e+00 -1.8373e+00 6.3650e-02 1.8749e-02 -6.0000e+00 7.6706e-01 7.7901e-01 3.2994e-02 4.0385e-02 -6.0000e+00 3.2849e-01 3.2689e-05 -3.1355e-03 1.1637e-03 5.7779e-04 -6.0000e+00 2.5629e-02 4.0103e-03 4.5070e-05 12 8 8 10 0 0 74.28 24.21 1.56 0.00401 -0.01955 26 7 1 5 0 1793.920 26.94 19.99 24.21 26.08 10.2 963.34 900000 125867 900000 900000 95190 900000 19709 900000 900000 900000 900000 900000 -14097 900000 900000 -85015 4292 109121 900000 900000 900000 900000 92883 900000 107670 73014 164908 900000 900000 57007 140063 900000 900000 119009 74127 -11721 900000 900000 26134 87685 368412 370502 165754 -13054 125468 115165 60333 185561 92435 900000 900000 78920 279002 59730 77581 61894 4711 -27522 207056 38593 22593 12035 96769 39025 66032 61441 40267 16762 61655 54257 26627 13515 11504 62725 29886 -17198 -77 -5357 6044 7322 -8130 25016 20842 3435 2494 -1904 -5305 -9068 18514 5078 9605 3502 -5946 11558 305 -7923 -5218 855 -8825 2987 -6935 2180 -8171 -6440 1721 -2233 -12264 -7821 -7682 898 1762 -5257 2523 -4113 3844 -1198 -2944 -2426 1892 755 1970 5689 795 -8716 4172 7610 3007 8959 4793 4243 790 1176 4592 -1052 -237 -280 -777 367 155 -1024 -1059 2362 -678 -4306 900000 5333 900000 900000 4033 900000 1063 900000 900000 900000 900000 900000 -690 900000 900000 -18175 446 4228 900000 900000 900000 900000 3220 900000 3733 2531 5717 900000 900000 1976 4856 900000 900000 4126 2872 -956 900000 900000 1586 3040 12772 12845 5746 -1414 4350 3993 3530 6433 4206 900000 900000 4788 9673 4789 5211 4694 602 -4592 7178 3094 2203 1434 5661 4651 6582 6523 5148 2688 6546 6819 4846 2928 2517 7747 4662 -3838 -13 -952 1048 1491 -2325 5962 5780 1213 935 -788 -2391 -4421 6980 2168 3746 1358 -2396 3882 124 -4086 -3132 572 -7476 2414 -6116 1625 -6073 -4395 1104 -1592 -10310 -6778 -7307 885 1958 -6948 3253 -5686 4764 -1503 -3713 -3149 2501 1071 2838 7779 1099 -12804 5216 8887 3570 10663 6024 6132 1344 2200 8895 -2286 -544 -684 -1988 948 404 -2675 -2645 5337 -1482 -9506 SS 20220916T114016.3Z 8294.486300 232 1 46.67 2 80.49 94.02 28.24 249.34 0.00 1 0.00 1 0 17 5.312e-01 1.849e-02 3.582e-01 1.048e-02 7.014247e-01 5.893434e-03 7.614179e-03 -6.000000e+00 3.150100e-01 229.29 -2.00 3.43 -2.00 321.85 0.00e+00 3.646625e-03 3.612597e-03 2.234859e-03 -6.000000e+00 1.512612e-02 290.18 -2.00 20.00 -2.00 321.25 0.00e+00 5.759 0.003 302.00 328.00 3 1.4366e+00 2.4127e-02 6.8441e-02 -6.0000e+00 7.8591e-01 2.5503e-01 3.3596e-02 3.8222e-02 -6.0000e+00 8.5519e-01 -3.6605e-01 3.0773e-02 1.9845e-02 -6.0000e+00 5.0730e-01 1.4492e-01 1.4002e-02 6.2500e-03 -6.0000e+00 2.1152e-01 2.0015e-04 -1.2300e-03 3.2242e-04 1.0508e-04 -6.0000e+00 1.5690e-02 4.4472e-03 4.2181e-05 12 8 8 10 0 0 57.01 24.20 0.52 0.00445 -0.00480 73 20 1 5 0 639.140 26.94 20.00 24.20 26.82 10.1 968.63 -90911 -253424 -44380 900000 -192960 -249643 900000 -99648 105698 900000 -89332 -153555 900000 38037 900000 900000 -93018 -13460 -70704 -20994 2180 10036 -9895 900000 -8213 31815 18255 -8876 -95190 284176 -9404 -34093 900000 13646 71814 76316 -9478 56353 -7018 -27928 48047 25239 8404 35926 7188 9030 28789 -8545 15070 52303 -8337 346 15233 4150 31818 -17237 -2025 45392 5055 -789 8634 10139 8153 17735 2202 10321 11399 4691 1757 15319 5434 3972 6130 -1740 3614 6578 -2538 6549 -1575 -399 5940 -1723 -3082 918 -2387 -2652 2354 -3040 841 2152 -2002 4195 3131 -4545 1371 -236 -421 3074 -1407 -1249 468 -2769 -2660 -252 -2788 -6115 -520 -963 -926 -48 -1242 -21 177 -2255 592 657 -783 43 -331 267 3241 -488 1100 1627 -446 1709 1453 -249 1383 1286 -1056 688 511 -400 314 46 -178 728 -868 -161 768 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1.501221e-03 1.268017e-03 -6.000000e+00 1.120076e-02 290.18 -2.00 20.00 -2.00 320.79 0.00e+00 4.972 0.002 302.00 328.00 3 1.2513e+00 1.0443e-02 5.9835e-02 -6.0000e+00 5.7701e-01 3.1515e-02 1.4491e-02 3.5340e-02 -6.0000e+00 6.2674e-01 -5.4579e-02 1.3765e-02 1.6334e-02 -6.0000e+00 3.7095e-01 1.6053e-02 6.4249e-03 6.1853e-03 -6.0000e+00 1.5484e-01 5.6746e-04 -6.1034e-04 1.5664e-04 6.5753e-05 -6.0000e+00 1.1604e-02 3.7682e-03 2.9782e-05 11 8 0 10 0 0 4.35 24.20 0.55 0.00377 -0.00082 135 36 1 5 0 345.930 26.94 20.00 24.20 27.49 10.2 975.27 -132881 -137797 -106708 -152863 900000 -192272 900000 -178754 900000 -122070 900000 -113151 22368 -98582 -6242 -63108 -36145 24464 -29756 18831 -36385 3242 -16339 19992 -25072 40056 -45119 -1448 -72163 49744 -7344 21745 8203 -14392 -10445 -30099 4083 -18430 2939 -14094 13500 -7845 13472 -5190 13622 -5490 3493 -5882 872 2522 2966 6504 2031 6980 -2467 4660 -3655 3601 -1236 2612 580 5173 5409 4767 2861 1991 1780 128 1423 -387 2356 -170 3053 734 2129 -1209 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