File name: Pandora156s1_HamptonVA-HU_20221021_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T164937.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20221021_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20221021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221021T115947.4Z 8329.499854 177 1 47.31 2 82.97 109.23 37.15 125.03 0.00 1 0.00 1 0 25 6.429e-01 3.866e-02 4.574e-01 2.959e-02 8.574537e-01 1.846334e-02 8.864846e-03 -6.000000e+00 3.989935e-01 226.06 -2.00 3.43 -2.00 322.32 0.00e+00 -4.511599e-03 1.184802e-02 1.933009e-03 -6.000000e+00 2.256515e-02 286.34 -2.00 20.00 -2.00 321.82 0.00e+00 7.495 0.007 302.00 328.00 3 1.0796e+00 8.0279e-02 8.8054e-02 -6.0000e+00 9.9226e-01 9.2512e-01 1.0717e-01 4.9009e-02 -6.0000e+00 1.0999e+00 -1.3158e+00 8.5805e-02 2.3418e-02 -6.0000e+00 6.4034e-01 5.3560e-01 3.8749e-02 7.0349e-03 -6.0000e+00 2.6158e-01 4.4963e-05 -5.5018e-04 9.3344e-04 9.6262e-05 -6.0000e+00 2.0122e-02 1.3817e-02 -3.6293e-05 12 8 8 10 0 0 -6.99 22.96 0.91 0.01382 0.00968 42 11 1 5 0 1126.090 25.90 20.00 22.96 17.43 11.0 929.75 900000 -97152 -141554 -120416 900000 900000 900000 -142797 900000 -74907 -125592 900000 -11896 900000 900000 900000 83839 900000 900000 900000 126253 900000 900000 900000 900000 900000 900000 8681 900000 -76102 112992 900000 900000 -36765 900000 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843 3549 5459 2744 1744 4174 5778 4703 6912 3335 -5432 1781 3871 1241 1678 781 2428 1121 -1309 -1989 -321 4224 -797 1657 -703 619 1725 -1639 2905 4046 3084 1531 4058 -3164 -667 -738 790 -4209 149 -1286 -1381 -1087 -3834 4703 -798 -98 -13196 -9363 3667 -3502 -3985 766 -5203 -2554 4677 1805 -480 3784 2242 1141 2140 2429 6681 9970 -5394 2465 3415 4210 1961 -5405 -3739 4187 3146 3363 -1750 -1523 964 184 -3641 15 -1004 -2617 SS 20221021T121034.9Z 8329.507348 180 1 46.93 2 80.95 110.96 35.48 128.38 0.00 1 0.00 1 0 25 5.292e-01 1.244e-02 3.791e-01 8.782e-03 7.235219e-01 5.068851e-03 7.694195e-03 -6.000000e+00 3.110462e-01 226.06 -2.00 3.43 -2.00 321.89 0.00e+00 -1.264283e-03 3.063686e-03 2.019228e-03 -6.000000e+00 1.479883e-02 286.34 -2.00 20.00 -2.00 321.34 0.00e+00 6.023 0.004 302.00 328.00 3 8.9703e-01 2.0333e-02 7.1671e-02 -6.0000e+00 7.7260e-01 1.1491e-01 3.0449e-02 4.2011e-02 -6.0000e+00 8.4515e-01 -1.7386e-01 3.0979e-02 2.1078e-02 -6.0000e+00 4.9848e-01 5.9423e-02 1.3868e-02 6.0029e-03 -6.0000e+00 2.0979e-01 2.7688e-04 -8.3977e-04 2.7317e-04 8.3420e-05 -6.0000e+00 1.6011e-02 1.3015e-02 -5.1785e-05 12 8 8 10 0 0 -44.22 22.96 0.51 0.01301 0.00670 118 32 1 5 0 397.640 25.90 20.00 22.96 18.00 10.9 934.02 900000 -193107 900000 -186213 900000 -248578 -154205 900000 900000 -174076 -105036 -225383 -50030 900000 900000 -40653 -1470 -95283 -126846 900000 -60329 30192 51443 33438 -11679 51871 -86960 150992 -121061 -38349 900000 18547 900000 1233 -64331 43066 57481 30118 33320 6065 5125 -6546 25520 6591 31728 19258 21853 -5492 40069 -13855 29233 12552 10338 19105 864 7419 3840 -3478 -2658 18964 6046 9238 18089 5757 11755 1495 -650 534 8621 3995 2456 4355 -7306 -771 1119 -5429 6628 4056 939 -2600 1343 -1333 -1877 9 -2564 2259 -21 2777 -694 -680 -725 1916 -4884 -477 1408 -329 4456 41 -590 -84 -333 -1224 -1383 -429 -2038 -1576 -864 -648 576 -489 -967 -360 -81 -390 1535 484 11 -132 -916 90 -741 236 -21 1547 276 786 1693 1 724 498 -114 256 697 -409 -178 -208 -384 391 193 -43 524 -700 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-6.000000e+00 1.009717e-02 286.34 -2.00 20.00 -2.00 320.80 0.00e+00 5.019 0.002 302.00 328.00 3 5.7846e-01 7.0235e-03 5.9728e-02 -6.0000e+00 5.4261e-01 5.2084e-02 9.6997e-03 3.4465e-02 -6.0000e+00 5.9084e-01 -4.6993e-02 9.4832e-03 1.6371e-02 -6.0000e+00 3.5239e-01 6.2942e-03 4.4468e-03 6.8375e-03 -6.0000e+00 1.4841e-01 1.0592e-03 -9.0625e-04 1.0992e-04 7.3783e-05 -6.0000e+00 1.1011e-02 1.2161e-02 -8.4324e-05 11 8 0 10 0 0 12.67 22.95 0.33 0.01216 0.00535 254 68 1 5 0 181.780 25.90 20.00 22.95 18.91 11.0 942.88 900000 -144944 -213930 -39336 -199726 900000 -166769 -106823 -34477 -90325 -43159 -66169 -96898 -32389 -13209 5759 53815 -61523 62328 13359 -34016 -3276 -74320 -20346 -22296 -22435 -13428 3262 756 -18236 -10028 -1173 -3498 -5023 -2714 -11251 4106 7335 2189 -1699 -3301 396 -1410 255 5633 3984 -2914 8993 -596 7504 -7033 9557 2515 6097 2009 5047 -420 2085 -780 4321 2503 -1416 3796 4155 1803 2060 2265 3087 1938 1883 488 224 1138 735 -915 -604 -137 -418 -1105 251 -1274 -306 -2039 -1350 -1270 -632 68 -357 -225 149 680 -246 110 21 760 506 937 192 158 821 -1252 658 -1435 412 -636 -921 -1090 -648 -392 -305 -395 20 46 -196 502 -113 376 459 -337 604 -1428 362 89 256 459 728 839 551 439 517 184 205 100 -184 -96 -34 -109 75 -256 85 -150 24 -25 -201 900000 -1095 -3501 -136 -2640 900000 -1679 -740 -131 -657 -209 -458 -1140 -258 -110 48 317 -1278 410 153 -648 -46 -2238 -387 -471 -505 -284 58 14 -423 -250 -32 -114 -181 -95 -425 144 292 112 -109 -246 31 -119 22 470 346 -278 788 -60 743 -886 1141 356 908 333 851 -77 378 -143 740 446 -284 816 1001 478 546 587 806 551 609 179 88 446 279 -327 -195 -40 -121 -348 90 -547 -149 -1128 -797 -798 -422 48 -261 -167 107 462 -157 66 13 489 371 790 187 170 916 -1380 654 -1327 360 -586 -908 -1136 -715 -466 -401 -576 31 74 -311 754 -161 525 656 -511 956 -2351 576 137 381 655 997 1107 727 622 821 325 392 202 -393 -218 -82 -273 193 -664 217 -368 57 -54 -441 SS 20221021T122717.1Z 8329.518948 188 1 45.76 2 77.87 113.71 33.06 134.09 0.00 1 0.00 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