File name: Pandora156s1_HamptonVA-HU_20221205_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T171101.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20221205_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20221205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221205T124650.8Z 8374.532532 216 1 47.50 2 83.46 124.53 120.31 325.07 0.00 1 0.00 1 0 25 6.011e-01 4.382e-02 5.004e-01 4.372e-02 9.388296e-01 2.615902e-02 1.070667e-02 -6.000000e+00 3.618442e-01 223.70 -2.00 3.43 -2.00 322.31 0.00e+00 -2.301777e-02 1.392002e-02 1.164319e-03 -6.000000e+00 1.938413e-02 281.43 -2.00 20.00 -2.00 321.83 0.00e+00 7.970 0.008 302.00 328.00 3 1.0845e+00 1.0086e-01 9.4007e-02 -6.0000e+00 8.9777e-01 1.1757e+00 1.2051e-01 5.8764e-02 -6.0000e+00 9.9147e-01 -1.6550e+00 8.1575e-02 2.3319e-02 -6.0000e+00 5.7895e-01 6.8341e-01 4.1635e-02 1.7035e-02 -6.0000e+00 2.3794e-01 2.6687e-05 -1.2574e-03 1.2754e-03 3.0429e-04 -6.0000e+00 1.8452e-02 1.2200e-02 -1.3012e-05 12 8 8 10 0 0 64.88 22.62 0.31 0.01220 0.00275 32 9 1 5 0 1484.030 25.68 19.98 22.62 9.20 11.3 939.23 228827 49774 82983 -149089 27509 71351 900000 900000 -45340 900000 35548 900000 -29018 10547 900000 900000 900000 130908 73751 195359 -93178 900000 900000 -22331 900000 900000 900000 -93888 900000 -88786 900000 900000 900000 900000 -36146 900000 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1607 4278 3295 5185 1910 5664 3804 -500 44 5755 -72 1433 1880 5852 2474 -815 252 -4474 2724 -557 5841 -1507 6474 -1908 143 -4837 960 -3826 -108 -1847 319 3213 -6479 3586 -7636 25 1402 -7053 -5458 7577 -6719 1127 -3991 -6799 -986 -5351 3030 4055 -1766 2424 3080 -829 3554 -2943 6770 446 3161 1904 3579 2488 5529 -94 -3741 -353 3164 2931 -5946 7523 -3396 1781 -4214 4824 -4192 -1515 -2804 985 SS 20221205T125732.0Z 8374.539953 219 1 47.36 2 81.73 126.30 121.42 327.64 0.00 1 0.00 1 0 25 6.331e-01 2.084e-02 4.149e-01 1.149e-02 8.017961e-01 6.555043e-03 8.442859e-03 -6.000000e+00 3.676971e-01 223.70 -2.00 3.43 -2.00 322.13 0.00e+00 -2.755504e-03 4.049380e-03 1.391535e-03 -6.000000e+00 1.724432e-02 281.42 -2.00 20.00 -2.00 321.65 0.00e+00 6.524 0.005 302.00 328.00 3 7.8205e-01 2.6619e-02 7.7575e-02 -6.0000e+00 9.1017e-01 4.7190e-01 3.8091e-02 4.4162e-02 -6.0000e+00 9.9523e-01 -6.9151e-01 3.7257e-02 2.3316e-02 -6.0000e+00 5.8733e-01 2.9496e-01 1.6807e-02 7.0897e-03 -6.0000e+00 2.4514e-01 1.6876e-04 -1.6486e-03 3.4161e-04 1.0765e-04 -6.0000e+00 1.8603e-02 1.2445e-02 -5.9210e-05 12 8 8 10 0 0 44.87 22.62 0.61 0.01244 0.00006 83 22 1 5 0 570.490 25.68 20.02 22.62 9.97 11.2 945.65 -211345 -181489 -61336 -113607 -95395 -204101 900000 -173840 900000 900000 -72803 -61628 152868 -107834 57732 74568 63768 25149 -31726 900000 62992 900000 -60466 900000 -84614 106525 -127184 55507 -23843 900000 -147429 -12048 -10125 250292 -43327 205068 -15932 87504 12509 48688 54682 26922 50215 32122 78415 26550 35213 -3205 72896 21873 53647 7540 255155 24439 35782 14026 69045 27581 31230 6173 11772 -5981 45020 23183 13131 17969 6636 14761 14337 10837 9206 6708 4603 9824 7659 3390 3846 2718 484 -3821 -939 1894 -2141 917 -3663 2834 -1217 7231 -6288 2043 -1206 -1731 -4706 683 -2720 1666 -3061 -545 -2036 -911 -1551 -786 -2426 -2619 -2915 -2223 549 -1691 -471 -1347 710 -1444 998 7 -354 -2246 930 -40 885 -438 1110 -334 1762 358 1396 1290 1480 629 935 555 535 727 154 214 -387 200 130 198 -642 -469 1371 -79 -1026 -1206 -4086 -2954 -686 -1271 -1068 -3530 900000 -2653 900000 900000 -815 -690 1711 -1865 646 835 714 281 -484 900000 705 900000 -1292 900000 -2755 1192 -6729 621 -412 900000 -10650 -270 -258 2801 -1631 2295 -470 1175 395 1417 1714 1096 1855 1438 2194 1248 1537 -192 2366 1273 2522 575 2856 2106 2963 1384 4482 2716 2866 698 1252 -736 4132 3010 2057 2735 1129 2395 2551 2073 2004 1590 1119 2375 1731 717 745 529 106 -1026 -292 607 -806 363 -1617 1249 -588 3325 -3333 973 -618 -839 -2265 318 -1446 985 -2024 -408 -1740 -809 -1350 -685 -1936 -1985 -2287 -1846 469 -1584 -478 -1556 913 -1904 1350 10 -520 -3228 1273 -56 1304 -684 1723 -511 2523 501 1872 1675 1862 803 1300 888 971 1449 331 490 -953 522 353 547 -1790 -1277 3473 -190 -2329 -2709 SS 20221205T131410.4Z 8374.551509 224 1 47.19 2 79.10 129.15 122.97 331.79 0.00 1 0.00 1 0 25 3.698e-01 4.425e-03 2.102e-01 3.175e-03 6.555068e-01 1.726476e-03 7.103360e-03 -6.000000e+00 2.115627e-01 223.70 -2.00 3.43 -2.00 321.48 0.00e+00 1.287654e-03 9.014078e-04 2.220227e-03 -6.000000e+00 9.459913e-03 281.42 -2.00 20.00 -2.00 320.93 0.00e+00 5.096 0.002 302.00 328.00 3 3.5518e-01 6.0988e-03 6.2189e-02 -6.0000e+00 5.2053e-01 6.1163e-02 8.6544e-03 3.8852e-02 -6.0000e+00 5.6784e-01 -3.1240e-02 9.0575e-03 1.8142e-02 -6.0000e+00 3.3924e-01 -1.3334e-03 4.2419e-03 5.8486e-03 -6.0000e+00 1.4232e-01 1.1744e-03 -1.0454e-03 9.6166e-05 7.3213e-05 -6.0000e+00 1.0662e-02 1.2159e-02 -5.8747e-05 10 0 0 10 0 0 97.25 22.62 0.34 0.01216 0.00430 267 72 1 5 0 176.690 25.58 19.98 22.62 11.65 11.4 961.96 -96605 -112829 -88662 -97034 -155513 -146730 -109450 -128748 -99418 -118088 -86996 -122542 -86046 -56588 -56612 -58823 -47126 -25914 -40092 834 -48645 -7173 -28954 24032 -17312 21652 -14140 -6501 -14405 -8052 2694 -1878 422 -5182 -5349 -4079 -6604 -6558 -2652 -6957 -6229 -4878 -3397 -2601 -376 -3051 -1846 -1540 -1418 630 3370 2332 1463 4655 1480 1859 1029 2002 2674 858 2323 231 3179 1438 3281 659 505 468 707 1701 72 888 975 479 454 27 548 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